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Preparation method of titanium-zinc alloy and titanium-zinc alloy plate

A titanium-zinc and alloy technology is applied in the field of preparation of titanium-zinc alloys and titanium-zinc alloy sheets, which can solve the problems of complex smelting and casting, difficulty in controlling the proportion of copper and titanium, pollution of the surrounding environment, etc., so as to improve market competitiveness and simplify the casting process. , the effect of efficient use of energy

Active Publication Date: 2017-06-13
SHANGHAI JIAOTONG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there are no literature and patent reports on the casting and rolling process of zinc-copper-titanium alloys in China. Since the melting point of zinc is far lower than that of copper and titanium, and there is a certain burning rate of zinc and titanium, if directly using pure The smelting of zinc-copper-titanium alloys will have the problem of difficult or incomplete melting of copper, and it will also make it difficult for the copper and titanium components to be evenly distributed into the alloy, which will not achieve the desired effect. Repeated smelting will inevitably increase the production cost. improve
At present, two binary alloys of zinc-copper and zinc-titanium are often added to the zinc melt, but there is often a problem that it is difficult to control the ratio of copper and titanium, and the melting and casting are complicated, the melting and refining time is long, a large amount of smoke and dust are generated, and the pungent odor is released. Deteriorating the operating environment, while damaging the health of the workers, and causing pollution to the surrounding environment (Geng Haoran, Wang Shouren, Wang Yan, etc. Casting zinc and copper alloys [M]. Beijing: Chemical Industry Press, 2006: 65~73)

Method used

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  • Preparation method of titanium-zinc alloy and titanium-zinc alloy plate
  • Preparation method of titanium-zinc alloy and titanium-zinc alloy plate
  • Preparation method of titanium-zinc alloy and titanium-zinc alloy plate

Examples

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Embodiment 1

[0050] This embodiment relates to a titanium-zinc plate material obtained by non-vacuum casting, the mass percentage of zinc element is 98.78%, the mass percentage of copper element is 1.04%, the mass percentage of titanium element is 0.08%, and the weight of unavoidable impurities The percentage shall not exceed 0.1%. The raw material of casting zinc-copper-titanium alloy ingot is pure zinc and zinc-copper-titanium ternary master alloy (the composition of zinc-copper-titanium ternary master alloy includes: pure zinc is 90wt%, pure copper 9.29wt%, Pure titanium is 0.71wt%).

[0051] The preparation method is to grind pure zinc and zinc-copper-titanium ternary master alloy with 320 mesh sandpaper to remove the oxide layer, respectively put them into a blast drying oven (200°C) for drying and preheating; use a stainless steel crucible for alloying For casting, set the temperature of the resistance heating furnace to 430°C, melt a small amount of pure zinc accounting for about 10%...

Embodiment 2

[0055] A titanium-zinc plate material obtained by non-vacuum casting, the mass percentage of zinc element is 98.78%, the mass percentage of copper element is 1.04%, the mass percentage of titanium element is 0.08%, and the weight percentage of unavoidable impurities is not more than 0.1 %. The raw material of casting zinc-copper-titanium alloy ingot is pure zinc and zinc-copper-titanium ternary master alloy (the composition of zinc-copper-titanium ternary master alloy includes: pure zinc is 90wt%, pure copper 9.29wt%, Pure titanium is 0.71wt%).

[0056] The preparation method is to grind pure zinc and zinc-copper-titanium ternary master alloy with 320 mesh sandpaper to remove the oxide layer, respectively put them into a blast drying oven (200°C) for drying and preheating; use a stainless steel crucible for alloying For casting, set the temperature of the resistance heating furnace to 430°C, melt a small amount of pure zinc accounting for about 10% of the total pure zinc mass...

Embodiment 3

[0060] A titanium-zinc plate material obtained by non-vacuum casting, the mass percentage of zinc element is 98.78%, the mass percentage of copper element is 1.04%, the mass percentage of titanium element is 0.08%, and the weight percentage of unavoidable impurities is not more than 0.1 %. The raw material of casting zinc-copper-titanium alloy ingot is pure zinc and zinc-copper-titanium ternary master alloy (the components of zinc-copper-titanium ternary master alloy include: pure zinc is 88.8wt%, pure copper 10.4wt% , pure titanium is 0.8wt%).

[0061] The preparation method is to grind pure zinc and zinc-copper-titanium ternary master alloy with 320 mesh sandpaper to remove the oxide layer, respectively put them into a blast drying oven (200°C) for drying and preheating; use a stainless steel crucible for alloying For casting, set the temperature of the resistance heating furnace to 430°C, melt a small amount of pure zinc accounting for about 10% of the total pure zinc mass...

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Abstract

The invention provides a fabrication method of a titanium-zinc alloy. The fabrication method comprises the following steps that after a part of pure zinc is molten to form a molten pool, the balance pure zinc is added; after the whole pure zinc is molten, heating to 450 degrees is performed, and a zinc-copper-titanium ternary intermediate alloy is added; after the zinc-copper-titanium ternary intermediate alloy is added wholly, a covering agent is spread on the surface of a melt uniformly; after the whole zinc-copper-titanium ternary intermediate alloy is molten, a refining agent is added, and mixing refining is performed on the condition of the temperature not exceeding 450 degrees; and after dirt and dross are removed, casting is performed, and a titanium-zinc alloy ingot is obtained. With the adoption of the fabrication method, a casting process can be simplified, and the production efficiency can be improved; the fabrication method is simple, safe and reliable, and is convenient to operate; and the finally fabricated titanium-zinc alloy plate has no defect on the surface, has better mechanical property and higher market competitiveness, and is suitable for popularization in scale industrial production.

Description

technical field [0001] The invention relates to a preparation method of a titanium-zinc alloy and a titanium-zinc alloy plate, belonging to the technical field of metal smelting. Background technique [0002] As a new type of green building material, titanium-zinc plate building roofing materials have gradually entered the Chinese building material market. The domestic comparable products are limited to color-coated steel plates, while the products made of zinc in Europe and the United States have been used on roofs for nearly 200 years of history. For buildings with higher service life and quality requirements, the overall anti-corrosion and titanium-zinc panels with a service life of more than 100 years are the first choice of architects all over the world. Titanium-zinc plate is an alloy, which is smelted by adding titanium and copper to high-purity Z1-grade metal zinc (purity 99.995%) that meets the European quality standard EN1179. Copper adds to the mechanical streng...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/03C22C18/02C22C1/06C22F1/16
Inventor 叶兵蒋海燕丁文江鲍庆煌丁学明唐继勇陆永
Owner SHANGHAI JIAOTONG UNIV