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A kind of polybutylene succinate ionomer microporous foam material and preparation method thereof

A technology of polybutylene succinate and microcellular foaming materials, which is applied in the field of polymer materials, can solve the problems of difficult control of cell quality, high cell density, and low material density, and achieve small cell size , The effect of high cell density and low density

Active Publication Date: 2018-09-14
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method of the present invention effectively overcomes the difficulty that polybutylene succinate has low melt strength and is not easy to foam, and solves the problems of high open cell ratio, large and uneven cell size, and difficult control of cell quality in existing products The technical problems of the polybutylene butyrate foam material are improved, the cell size and cell density of the foam material are easy to control, and the material density is low, the expansion ratio is high, and the cell size is low. Foam material with small size and high cell density

Method used

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  • A kind of polybutylene succinate ionomer microporous foam material and preparation method thereof
  • A kind of polybutylene succinate ionomer microporous foam material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The polybutylene succinate ionomer with an amino ion content of 1mol% is packed into an autoclave and sealed, the autoclave is heated to 100°C, and the 2 The gas injection system injects CO 2 , purging for 1 to 2 minutes to remove the air in the autoclave, close the pressure relief valve, and control the CO 2 The pressure is 20MPa, keep at constant temperature for 2 hours, then quickly cool down to 80°C, keep at constant temperature for 20 minutes, then quickly release the pressure to normal pressure, and finally cool the autoclave to room temperature to prepare polybutylene succinate Ionomer foam material.

Embodiment 2

[0033] The polybutylene succinate ionomer with an amino ion content of 5 mol% is packed into an autoclave and sealed, and the autoclave is heated to 110° C. 2 The gas injection system injects CO 2 , purging for 1 to 2 minutes to remove the air in the autoclave, close the pressure relief valve, and control the CO 2 The pressure is 25MPa, keep at constant temperature for 2 hours, then quickly cool down to 80°C, keep at constant temperature for 20 minutes, then quickly release the pressure to normal pressure, and finally cool the autoclave to room temperature to prepare polybutylene succinate Ionomer foam material.

Embodiment 3

[0035] The polybutylene succinate ionomer with an amino ion content of 1mol% is packed into an autoclave and sealed, the autoclave is heated to 120°C, and the 2 The gas injection system injects CO 2 , purging for 1 to 2 minutes to remove the air in the autoclave, close the pressure relief valve, and control the CO 2 The pressure is 25MPa, keep at constant temperature for 2 hours, then quickly cool down to 80°C, keep at constant temperature for 20 minutes, then quickly release the pressure to normal pressure, and finally cool the autoclave to room temperature to prepare polybutylene succinate Ionomer foam material.

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Abstract

The invention belongs to the technical field of high polymer materials and discloses a poly(butylene succinate) ionomer microcellular foaming material and a preparation method thereof. According to the method, poly(butylene succinate) ionomer serves as a raw material, supercritical CO2 serves as a foaming agent, and the poly(butylene succinate) ionomer microcellular foaming material is achieved in a mode of intermittent foaming. According to the method, the shortcoming that poly(butylene succinate) ionomer melt is low in strength and difficult to foam is effectively overcome, the technical problems that existing products are high in opening percentage and large and uneven in cell size, and cell quality is difficult to regulate are solved, the cell quality of the poly(butylene succinate) foaming material is improved, the cell size and cell density of the foaming material are easy to regulate, and the foaming material which is small in material density, high in foaming ratio, small in cell size and high in cell density is manufactured. The supercritical CO2 serves as the foaming agent, and the poly(butylene succinate) ionomer microcellular foaming material has the advantages of low cost, easiness in operation control, no poison and no pollution and the like.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, in particular to a polybutylene succinate ionomer microporous foaming material and a preparation method thereof. Background technique [0002] Due to the large number of micron-sized cells inside the polymer microcellular foaming material, it can significantly reduce the quality of polymer products without significantly reducing the mechanical properties of the material, effectively reducing the amount of plastic used and reducing costs. It has high impact strength, With the advantages of light weight, low thermal conductivity and low dielectric constant, it is widely used in construction, packaging, automobile, military, aerospace and other fields. [0003] Supercritical CO 2 Because of its low price, easy operation, non-toxic and non-polluting, etc., it has become a hot spot in industrial production and scientific research in the field of foaming, and has become the most promising al...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J9/12C08L67/02
Inventor 张水洞汪鹏彭响方
Owner SOUTH CHINA UNIV OF TECH
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