Modified weather-resistant high-density polyethylene sheathing compound for bridge cables and method for preparing modified weather-resistant high-density polyethylene sheathing compound

A technology of high-density polyethylene and low-density polyethylene, which is applied in the field of modified weather-resistant high-density polyethylene sheathing materials for bridge cables and its preparation, can solve the problems of high cable replacement costs, economic losses, bridge collapse, etc., and achieve durable Excellent environmental stress cracking performance and uniform color effect

Active Publication Date: 2015-11-25
HUBEI YANGTIAN PLASTIC PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The cable sheath material is the first line of defense to protect the cables. Once the sheath material is cracked and damaged, the corrosive medium will directly enter the exposed steel wires, corrode the steel wires, and the corrosion of the stay cables will directly endanger the safety of the bridge. At this time, the cables must be replaced. , the cost of cable replacement is extremely high, which will cause major economic losses, and serious bridge collapse may occur, causing major safety disasters
[0003] At present, the sheath materials used by domestic cable manufacturers are all imported from abroad, and there is no qualified cable sheath material produced in China.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Embodiment 1: a kind of modified weather-resistant high-density polyethylene sheath material and preparation method thereof for bridge cable, this preparation method comprises the following steps in sequence:

[0037] The first step: modification of high-density polyethylene:

[0038] Take 30kg of ultra-high molecular weight polyethylene UHMWPE, 40kg of high-density polyethylene 6098, 10kg of linear low-density polyethylene 7042, 3kg of low-density polyethylene Q200, 0.3kg of antioxidant 300#, and 0.5kg of polyethylene wax into the high-speed mixer, Mix at room temperature for 3-5 minutes, then discharge into the parallel twin-screw granulator, melt extrude, pelletize under water, dry the particles after dehydration, and obtain modified high-density polyethylene particles; the working temperature of the extruder is: The first zone is 180±5°C, the second zone is 200±5°C, the third zone is 220±5°C, the fourth zone is 230±5°C, the fifth zone is 240±5°C, the sixth zone is 2...

Embodiment 2

[0049] With embodiment 1, difference is:

[0050] The first step: modification of high-density polyethylene:

[0051] Take 50kg of ultra-high molecular weight polyethylene UHMWPE, 50kg of high-density polyethylene 6098, 15kg of linear low-density polyethylene 7042, 5kg of low-density polyethylene Q200, 0.5kg of antioxidant 300#, and 0.8kg of polyethylene wax.

[0052] The second step: the preparation of black sheath material:

[0053] Get the modified high-density polyethylene particle that 30kg first step makes, 70kg high-density polyethylene 6098, 6kg carbon black masterbatch, 0.8kg antioxidant 300#, 5kg silicone masterbatch.

[0054] The third step: preparation of color sheath material

[0055] Take 30kg of modified high-density polyethylene particles prepared in the first step, 70kg of high-density polyethylene 6098, 3kg of color masterbatch (pearl white, red, silver gray, orange, blue), 0.8kg of antioxidant 1010, 0.8kg Antioxidant 168, 0.5kg UV absorber, 3kg silicone m...

Embodiment 3

[0062] With embodiment 1, difference is:

[0063] Step 1: Take 40kg of high-density polyethylene 2480, 10kg of linear low-density polyethylene 218W, and 3kg of low-density polyethylene 2426H.

[0064] Step 2: Take 50kg of high-density polyethylene 2480.

[0065] The third step: take 50kg high-density polyethylene 2480

[0066] Effect data of this example

[0067] black sheath

[0068] 1. Density 0.960g / cm 3 ;2. Melt flow rate 0.22g / 10min; 3. Tensile fracture stress 38MPa; 4. Tensile yield stress 27MPa; 5. Nominal strain at fracture 740%; 6. Hardness 63; 7. Tensile modulus of elasticity 800MPa ;8. Flexural modulus of elasticity 800MPa; 9. Impact strength 45KJ / m 2 ; 10. Softening temperature 120°C; 11. Resistance to environmental stress cracking F 0 >5000h; 12. Impact embrittlement temperature, qualified; 13. Heat stress cracking resistance F 0 >96h; 14. Heat aging resistance 100℃×168h, tensile fracture stress change rate is 4%, crack nominal strain change rate -10%; 15. ...

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Abstract

The invention discloses a modified weather-resistant high-density polyethylene sheathing compound for bridge cables. A method for preparing the modified weather-resistant high-density polyethylene sheathing compound includes mixing ultrahigh-molecular-weight polyethylene, high-density polyethylene, linear low-density polyethylene, low-density polyethylene, antioxidants and polyethylene wax with one another in high-speed mixers at normal temperatures to obtain mixtures, discharging the mixtures into parallel double-screw granulation units, melting and extruding the mixtures, granulating the mixtures under underwater conditions to obtain particles, dehydrating the particles, and then drying the particles to obtain modified high-density polyethylene particles; mixing the obtained modified high-density polyethylene particles, high-density polyethylene, carbon black parent materials, antioxidants and silicone parent materials with one another in the high-speed mixers at normal temperatures to obtain mixtures, discharging the mixtures into the parallel double-screw granulation units, melting and extruding the mixtures, granulating the mixtures under underwater conditions to obtain particles, dehydrating the particles, and drying the particles to obtain the modified weather-resistant high-density polyethylene black sheathing compound for the bridge cables. The modified weather-resistant high-density polyethylene sheathing compound and the method have the advantages that the sheathing compound is excellent in physical and mechanical properties, in particular, the ultraviolet resistance property and the environmental stress cracking resistance property, and various indexes of manufactured products conform to requirements of standards CJ / T297-2008 of housing construction departments.

Description

technical field [0001] The invention relates to a modified weather-resistant high-density polyethylene sheath material for bridge cables and a preparation method thereof, belonging to the field of new materials. Background technique [0002] The cables of large-scale bridges are the main load-bearing structure of the bridge. The cables of large-span bridges are divided into stay cables and suspension cables. The outer layers of the cables are extruded with two layers of high-density polyethylene sheath materials. The vinyl double-layer sheath structure, the outermost colored sheath material is to meet the special landscape requirements of the bridge. The cable sheath material is the first line of defense to protect the cables. Once the sheath material is cracked and damaged, the corrosive medium will directly enter the exposed steel wires, corrode the steel wires, and the corrosion of the stay cables will directly endanger the safety of the bridge. At this time, the cables m...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L23/08C08L83/04C08K3/04C08K5/134C08K5/526C08K5/375B29C47/92B29C48/92
CPCB29C48/92B29C2948/92704C08L23/06C08L2201/08C08L2205/025C08L2205/035C08L2207/062C08L2207/066C08L2207/068C08L23/0815C08L83/04C08K3/04C08K5/375C08K5/1345C08K5/526
Inventor 胡晓红
Owner HUBEI YANGTIAN PLASTIC PROD CO LTD
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