Degradable resin material for operation of oil and gas field and preparation method thereof

A technology for degrading resins, oil and gas fields, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of long contact time, insufficient, dissolution and release, etc.

Inactive Publication Date: 2015-11-25
CHINA UNIV OF PETROLEUM (BEIJING) +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, these temporary plugging materials have some shortcomings and deficiencies. For water-soluble temporary plugging materials, the carrier fluid needs to be organic hydrocarbons, and after the operation is completed, there needs to be a sufficient amount of water in the formation. During the subsequent liquid drainage process, The produced water in the formation dissolves it, removes its temporary blockage, and dredges the oil and gas channels. If there is not enough water in the formation, or the formation pressure is insufficient, and there is not enough water produced, it is necessary to squeeze water into the formation to dissolve these water solubles. Temporary plugging materials are often unable to be completely dissolved and removed, causing certain damage to the formation; acid-soluble temporary plugging materials, after completing the temporary plugging operation, need to inject acid to dissolve the temporary plugging materials and remove them. Clogging is not suitable for acid-sensitive reservoirs, even for non-acid-sensitive reservoirs, an additional operation is required, which increases operating costs. Since the acid solution cannot fully soak all the temporary blocking materials, it cannot be completely dissolved. Unblock the oil and gas channels; for oil-soluble temporary plugging materials, first of all, it is not suitable for gas wells, and second, it is oil wells. Since the formation crude oil only contacts the front edge of temporary plugging, when the dissolution reaches saturation, it is mainly achieved by diffusion and convection. Slow dissolution, which leads to long and insufficient contact time, and some damage to the formation

Method used

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  • Degradable resin material for operation of oil and gas field and preparation method thereof
  • Degradable resin material for operation of oil and gas field and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0040] This embodiment provides a degradable resin material for oil and gas field operations, such as figure 1 As shown, it is prepared by the following steps:

[0041] (1) Stir and dry polyglycolic acid slices with a weight average molecular weight (Mw) of 60,000 at 90-100°C and a vacuum of 90 kPa for 4 hours; Butylene glycol ester slices were stirred and dried for 9 hours at 70-75°C and a vacuum of 90 kPa; poly-3-hydroxybutyrate slices with a weight average molecular weight (Mw) of 50,000 were placed at Under the vacuum degree of 90 kPa, stir and dry for 4 hours, so that the moisture content is lower than 0.1wt%, preferably lower than 0.01wt%;

[0042] (2) Take 100 kilograms of polyglycolic acid slices, 500 kilograms of polybutylene succinate slices and 400 kilograms of poly-3-hydroxybutyrate slices after dewatering and add them to a stainless steel mixer with stirring device , heat up to 50°C, and mix for 10 minutes at a vacuum of 90 kPa;

[0043] (3) Add the mixture of ...

Embodiment 2

[0048] The PGA / PBS / PHA resin nano-alloy slices prepared in Example 1 are granulated through a screw granulator at 200°C, the particle diameter is Φ1-1.5 mm, and the temperature is reduced to 10°C / min at a cooling rate of At 20°C, molded Φ1-1.5 mm particles are obtained, and a granular degradable resin material is obtained.

[0049] The Φ1-1.5 mm granular degradable resin material is used in the B2 well (in the well section with a depth of 6417-6563m, the temperature of this well section is 150°C-153°C, and 5 layers are shot, 6417-6428m, 6461-6472m, 6493- 6506m, 6522-6533m and 6549-6563m) wells were temporarily plugged and diverted to fracturing operations, carried by guar jelly fracturing fluid, and temporarily blocked and diverted to fracturing in three times, using 128 kg of Φ1-1.5 mm particle temporary plugging materials for the three times , 150 kg and 280 kg, after 3 diversions, under the same pump injection displacement, the pressure increased by 5.8MPa, 7.2MPa and 13.5M...

Embodiment 3

[0051] This embodiment provides a degradable resin material for oil and gas field operations, such as figure 1 As shown, it is prepared by the following steps:

[0052] (1) Stir and dry polyglycolic acid slices with a weight average molecular weight (Mw) of 25,000 at 100-105°C and a vacuum of 90 kPa for 3.5 hours; Butylene glycol ester chips were stirred and dried for 7.5 hours at 70-75°C and a vacuum of 90 kPa, so that the moisture content was lower than 0.1wt%, preferably lower than 0.01wt%;

[0053] (2) Take 800 kilograms of polyglycolic acid slices and 200 kilograms of polybutylene succinate slices after removing water and add them to a stainless steel mixer with a stirring device, heat up to 50°C, Under kPa, mix for 10 minutes;

[0054] (3) the mixture of polyglycolic acid in the mixer and polybutylene succinate is added in the reciprocating single-screw mixing extruder, adding 6 kilograms of particle diameters is the silicon dioxide of 10-15nm, And add 1.2 kilograms o...

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Abstract

The invention provides a degradable resin material for operation of an oil and gas field and a preparation method thereof. The method comprises the step of performing a melt-mixing reaction on polymer of two or three of polyglycolic acid, butylene succinate and poly-3-hydroxybutyrate with a chain extender to prepare resin alloy, namely the degradable resin material for operation of the oil and gas field. The degradable resin material prepared by the method can be prepared into flakes, powder, particles, spheres and other shapes, or one of polyglycolic acid, butylene succinate and poly-3-hydroxybutyrate is prepared into flakes, powder, particles, spheres and other shapes. The degradable resin material can be used for temporarily plugging and reducing filtration to protect reservoirs, temporarily plugging blast-holes, constructed reservoirs and the like in various oil and gas field constructing operations, such as well drilling, completion and repairing and acid fracturing. The degradable resin material has the advantages of complete degradability and zero harm to stratum.

Description

technical field [0001] The invention relates to a degradable resin material for oil and gas field operations and a preparation method thereof, belonging to the technical field of oil and gas exploitation. Background technique [0002] In various construction operations in oil and gas fields, such as drilling, well completion, well workover or stimulation operations, fluid loss control materials are widely used to reduce the intrusion of working fluid into the reservoir and reduce its damage to the reservoir. The fluid loss control agent used can block the fractures and pores of the reservoir, thereby reducing the intrusion of working fluid, and plugging the pore throats and fractures of the reservoir. After the operation is completed, these plugging materials also block the flow of oil and gas from the reservoir. Flow into the wellbore and cause damage to the reservoir. [0003] In order to reduce the damage caused by the fluid loss control agent to the reservoir, temporary...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/50C09K8/74C09K8/03
CPCC09K8/50C09K8/03C09K8/725C09K8/74
Inventor 周福建王旻周志澎周翠红左洁
Owner CHINA UNIV OF PETROLEUM (BEIJING)
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