Treatment method for reverse osmosis concentrated water

The technology of reverse osmosis concentrated water and treatment method is applied in the field of sewage treatment, which can solve the problems of poor biodegradability, high economic cost and high salt content, and achieve the effects of difficult adsorption, high treatment efficiency and simple operation.

Inactive Publication Date: 2016-01-06
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] ② Poor biodegradability, the main pollutants are some high-level aliphatic hydrocarbons, polycyclic aromatic hydrocarbons, polycyclic aromatic compounds and other refractory organic substances;
[0007] ④High salt content
[0013] Patents CN102139984A and CN103373786A adopt membrane distillation process, and use temperature difference to treat reverse osmosis concentrated water under normal pressure to obtain pure water, but the required economic cost is relatively high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A reverse osmosis concentrated water, the water quality is shown in Table 1. Concentrated water enters the nanofiltration (NF200-270) system through a high-pressure pump. The operating pressure of the nanofiltration system is 0.6MPa, and the system recovery rate is 60%. The concentrated water and nanofiltration product water of the nanofiltration system are obtained; The pump enters the reverse osmosis system for further concentration treatment to obtain reverse osmosis concentrate and reverse osmosis product water. Among them, the reverse osmosis membrane is BW30-400FR, the operating pressure of the reverse osmosis system is 1.3MPa, and the system recovery rate is 60%. The produced water is reused, and the reverse osmosis concentrate enters the membrane distillation (S6-2 type) system for distillation treatment. The vacuum degree of the membrane distillation system is -0.085MPa, the temperature is 80°C, and the membrane distillation produced water is reused; the nanofil...

Embodiment 2

[0058] Take another reverse osmosis concentrated water, the water quality is shown in Table 2. The concentrated water enters the nanofiltration (NF200-270) system through the security filter. The operating pressure of the nanofiltration system is 0.5MPa, and the system recovery rate is 65%. The concentrated water and nanofiltration product water of the nanofiltration system are obtained; The high-pressure pump enters the reverse osmosis system for further concentration treatment to obtain reverse osmosis concentrate and reverse osmosis product water. Among them, the reverse osmosis membrane is BW30-400FR, the operating pressure of the reverse osmosis system is 1.2MPa, and the system recovery rate is 70%. The osmotic product water is reused, and the reverse osmosis concentrated solution enters the membrane distillation (S6-2 type) system for distillation treatment. The vacuum degree of the membrane distillation system is -0.09MPa, the temperature is 75°C, and the membrane distil...

Embodiment 3

[0063] Take another reverse osmosis concentrated water, the water quality is shown in Table 3. The concentrated water enters the nanofiltration (NF90) system through the security filter. The operating pressure of the nanofiltration system is 0.9MPa, and the system recovery rate is 50%. The concentrated water and nanofiltration product water of the nanofiltration system are obtained; the nanofiltration product water passes through the high-pressure pump Enter the reverse osmosis system for further concentration treatment to obtain reverse osmosis concentrate and reverse osmosis product water, wherein the reverse osmosis membrane is BW30-400FR, the operating pressure of the reverse osmosis system is 1.5MPa, the system recovery rate is 60%, and the reverse osmosis product For water reuse, the reverse osmosis concentrate enters the membrane distillation (S6-2 type) system for distillation treatment. The vacuum degree of the membrane distillation system is -0.085MPa, the temperature...

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Abstract

The invention relates to a treatment method for reverse osmosis concentrated water. Aiming at reverse osmosis concentrated water generated by a reverse osmosis process of a double-membrane process, the method comprises: firstly removing organic matters and scaling ions such as calcium, magnesium and the like in the reverse osmosis concentrated water by using a nanofiltration membrane, then feeding the nanfiltration contributing water into the reverse osmosis system to be further concentrated, and then feeding the concentrated nanfiltration contributing water into a membrane distillation system for treatment and recycling; and adding alkali into the concentrated water generated by the nanfiltration system to remove scaling ions such as calcium, magnesium and the like and part of organic matters and adsorbing the substances through powdery active carbon to discharge the up-to-standard concentrated water. According to the treatment method for reverse osmosis concentrated water provided by the invention, the organic matters and scaling ions such as calcium, magnesium and the like which cause pollution to a subsequent reverse osmosis membrane are removed by virtue of a nanofiltration technology firstly, so that the stable operation of the reverse osmosis system is ensured; then the nanofiltration contributing water is further concentrated by virtue of the reverse osmosis system, so that the water inflow of membrane distillation is greatly reduced, the recovery rate of the reverse osmosis concentrated water is improved, and the treatment cost for the reverse osmosis concentrated water is lowered. The treatment method has good economical and social benefits.

Description

technical field [0001] The invention relates to a method for treating sewage, in particular to a method for treating reverse osmosis concentrated water, especially a method for treating reverse osmosis concentrated water for reuse. The reverse osmosis concentrated water is the reverse osmosis concentrated water produced by the reverse osmosis process in the double-membrane process. Background technique [0002] Due to its simple process, convenient operation, and small footprint, the double-membrane process is widely used in the advanced treatment and reuse of industrial wastewater. However, while the reverse osmosis process in the double-membrane process produces pure recycled water, it also produces concentrated water with a high concentration of pollutants (that is, reverse osmosis concentrated water), and the amount of reverse osmosis concentrated water usually accounts for 50% of the recycled water. One-third, therefore, the treatment and discharge of reverse osmosis c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/10C02F1/44
CPCY02A20/131
Inventor 平春霞张新妙王玉杰
Owner CHINA PETROLEUM & CHEM CORP
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