Preparation method of cage-shaped organic silicon hybridized star-shaped polyester soft PVC plasticizer

An organosilicon and plasticizer technology, applied in the field of functional polymer material preparation and modification, can solve problems such as increasing low temperature impact resistance, achieve enhanced low temperature impact resistance, good compatibility, and prevent plasticizer migration Effect

Active Publication Date: 2016-01-13
GUANGDONG DAHUA WATER SAVING TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to solve the problems of increasing the compatibility between the soft PVC plasticizer and the matrix, preventing the migration of the plasticizer, and enhancing its low-temperature impact resistance. The raw materials are organically combined through chemical modification to prepare a A cage-type silicone hybrid star-shaped polyester soft PVC plasticizer

Method used

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  • Preparation method of cage-shaped organic silicon hybridized star-shaped polyester soft PVC plasticizer
  • Preparation method of cage-shaped organic silicon hybridized star-shaped polyester soft PVC plasticizer
  • Preparation method of cage-shaped organic silicon hybridized star-shaped polyester soft PVC plasticizer

Examples

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Effect test

Embodiment 1

[0032] A kind of preparation method of cage silicone hybrid star polyester soft PVC plasticizer, its preparation steps are as follows:

[0033] S1, ricinoleic acid is subjected to cracking and oxidation through ozone oxidation, and Renay-Ni catalytic hydrogenation reaction to obtain nonanol acid and 1,3-dihydroxynonanediol;

[0034] S2. The vertex group of octamethacryloyloxypropyl cage silsesquioxane undergoes an ester hydrolysis reaction in aqueous sulfuric acid, and stirs and refluxes for 4 hours to obtain octapropanol cage silsesquioxane;

[0035] S3, the nonanol acid obtained in step S1 and 1,3-dihydroxynonanediol and the octapropanol-based cage silsesquioxane obtained in step S2 are 70:10:20 in mass ratio with dimer acid Mix to obtain a mixed solution;

[0036] S4, adding esterification reaction catalyst heteropolyacid PW to the mixed solution prepared in step S3 12 / SiO 2 And dehydrating agent DCC, reflux reaction for 2~6h, to obtain cage silicone hybrid star polyest...

Embodiment 2

[0039] A kind of preparation method of cage silicone hybrid star polyester soft PVC plasticizer, its preparation steps are as follows:

[0040] S1, ricinoleic acid is subjected to cracking and oxidation through ozone oxidation, and Pd / C catalytic hydrogenation reaction to obtain nonanol acid and 1,3-dihydroxynonanediol;

[0041] S2. The vertex group of octamethacryloxypropyl cage silsesquioxane undergoes an ester hydrolysis reaction in aqueous sodium hydroxide solution, and stirs and refluxes for 2 hours to obtain octapropanol cage silsesquioxane ;

[0042] S3, the nonanol acid obtained in step S1 and 1,3-dihydroxynonanediol and the octapropanol-based cage silsesquioxane obtained in step S2 are 70:20:10 in mass ratio with dimer acid Mix to obtain a mixed solution;

[0043] S4, adding esterification reaction catalyst heteropolyacid PW to the mixed solution prepared in step S3 12 / SiO 2 And dehydrating agent DCC, reflux reaction for 2~6h, to obtain cage silicone hybrid star ...

Embodiment 3

[0045] A kind of preparation method of cage silicone hybrid star polyester soft PVC plasticizer, its preparation steps are as follows:

[0046] S1, ricinoleic acid is subjected to cracking and oxidation through ozone oxidation, and Pd / C catalytic hydrogenation reaction to obtain nonanol acid and 1,3-dihydroxynonanediol;

[0047] S2. The vertex group of octamethacryloyloxypropyl cage silsesquioxane undergoes an ester hydrolysis reaction in aqueous sulfuric acid, and stirs and refluxes for 4 hours to obtain octapropanol cage silsesquioxane;

[0048] S3, the nonanol acid obtained in step S1 and 1,3-dihydroxynonanediol and the octapropanol-based cage silsesquioxane obtained in step S2 are 80:10:10 in mass ratio with dimer acid Mix to obtain a mixed solution;

[0049] S4, adding esterification reaction catalyst heteropolyacid PW to the mixed solution prepared in step S3 12 / SiO 2 And dehydrating agent DCC, reflux reaction for 2~6h, to obtain cage silicone hybrid star polyester sof...

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Abstract

The invention relates to the technical fields of the preparation and modification of functional macro-molecular materials, and particularly relates to a preparation method of a cage-shaped organic silicon hybridized star-shaped polyester soft PVC plasticizer. The preparation method comprises the following steps: (1) sequentially cracking oxidizing and hydrogenating ricinoleic acid to obtain a mixed product of dihydric alcohol and nonanol acid; (2) facilitating esterolysis reaction of an apex group of 8-methacryloxypropyl cage-shaped silsesquioxane to obtain 8-propanol cage-shaped silsesquioxane; (3) mixing the mixed product obtained in the step (1) and the 8-methacryloxypropyl cage-shaped silsesquioxane obtained in the step (2) with a dimer acid according to a mass ratio to obtain a mixed solution; and (4) adding an esterification catalyst and a dehydration agent into the mixed solution prepared in the step (3), and refluxing to obtain the cage-shaped organic silicon hybridized star-shaped polyester soft PVC plasticizer. The plasticizer has excellent application performance and is high in migration resistance, solvent resistant effect, weather resistance and the like.

Description

technical field [0001] The invention relates to the technical field of preparation and modification of functional polymer materials, in particular to a method for preparing a cage-type organosilicon hybrid star-type polyester soft PVC plasticizer. Background technique [0002] Polyvinyl chloride (PVC) is one of the largest synthetic resin products in the world. Adding an appropriate amount of plasticizer to polyvinyl chloride resin can make a variety of hard and soft products. Among them, soft PVC products account for 30% of the PVC market share, and it is widely used in the manufacture of artificial leather, food packaging materials, wires and cables, and children's toys. The plasticizer used in soft PVC is mainly di(2-ethyl)hexyl phthalate (DEHP), which has good compatibility with PVC, high plasticizing efficiency, low price, and does not affect the safety of the product. It has many advantages such as sex and electrical insulation. However, since DEHP is a small molecu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G63/695C08L27/06C08L67/02
Inventor 潘怀聪潘家瑞许凯彭军魏新
Owner GUANGDONG DAHUA WATER SAVING TECH CO LTD
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