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Epoxy resin composition and prepreg and copper clad laminate manufactured by using epoxy resin composition

A technology of epoxy resin and prepreg, which is applied in the field of resin composition, can solve problems such as high brittleness, low thermal decomposition temperature, and poor PCB processability, and achieve high glass transition temperature, good impact toughness, and excellent dielectric properties.

Active Publication Date: 2016-02-10
江苏生益特种材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional FR-4 boards mostly use dicyandiamide as the curing agent, which has high hygroscopicity and low thermal decomposition temperature, which cannot meet the heat resistance requirements of lead-free technology
After 2006, along with the large-scale implementation of lead-free technology, the industry began to adopt phenolic resin as the curing agent of epoxy resin, as patent CN1966572A discloses a kind of epoxy resin composition utilizing phenolic resin curing, the composition Tg High, excellent heat resistance, but high brittleness, insufficient toughness, poor PCB processability
Patents CN102443138A and CN102850722A proposed epoxy resin compositions containing dicyclopentadiene structure and naphthalene ring structure and cured with active esters. The composition has a higher glass transition temperature and excellent dielectric properties. performance, but no mention of its toughness and processability

Method used

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  • Epoxy resin composition and prepreg and copper clad laminate manufactured by using epoxy resin composition
  • Epoxy resin composition and prepreg and copper clad laminate manufactured by using epoxy resin composition
  • Epoxy resin composition and prepreg and copper clad laminate manufactured by using epoxy resin composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] 100 parts by weight of HP-7200HHH (dicyclopentadiene type novolac epoxy resin, epoxy equivalent: 286g / eq), then add 74.1 parts by weight of HPC-8000-65T (active ester compound, active ester equivalent: 223g / eq) , then add 5.4 parts by weight of ELASMER-1000P (poly-1,4-butanediol bis(4-aminobenzoate, active hydrogen equivalent is 309g / eq), mix and stir and add an appropriate amount of curing accelerator DMAP, and Solvent toluene, continue to stir evenly to form glue, control the solid content of glue to be 40-80%.Impregnate the above glue with glass fiber cloth (model is 2116, thickness is 0.08mm), and control to a suitable thickness, then dry Remove the solvent to make a prepreg. Use several prepared prepregs to stack each other, press a piece of copper foil on each side of the prepreg, put it into a hot press and solidify to make the copper-clad laminate. Physical data As shown in Table 1.

Embodiment 2

[0056] 100 parts by weight of HP-7200HHH (dicyclopentadiene type novolak epoxy resin, epoxy equivalent: 286g / eq), then add 70.2 parts by weight of HPC-8000-65T (active ester compound, active ester equivalent: 223g / eq) , then add 10.8 parts by weight of ELASMER-1000P (poly-1,4-butanediol bis(4-aminobenzoate active hydrogen equivalent is 309g / eq), mix and stir and add an appropriate amount of curing accelerator DMAP, and solvent Toluene, continue to stir evenly to form the glue, control the solid content of the glue to be 40-80%.Impregnate the above-mentioned glue with glass fiber cloth (the model is 2116, and the thickness is 0.08mm), and control to a suitable thickness, then dry and remove Solvent makes prepregs. Use several prepared prepregs to stack each other, press and cover a piece of copper foil on both sides, put it into a hot press and solidify to make the copper-clad laminate. The physical data is as follows: Table 1 shows.

Embodiment 3

[0058] 100 parts by weight of HP-7200HHH (dicyclopentadiene type novolac epoxy resin, epoxy equivalent: 286g / eq), then add 54.6 parts by weight of HPC-8000-65T (active ester compound, active ester equivalent: 223g / eq) , then add 32.4 parts by weight of ELASMER-1000P (poly-1,4-butanediol bis(4-aminobenzoate, active hydrogen equivalent is 309g / eq), mix and stir and add an appropriate amount of curing accelerator DMAP, and Solvent toluene, continue to stir evenly to form glue, control the solid content of glue to be 40-80%.Impregnate the above glue with glass fiber cloth (model is 2116, thickness is 0.08mm), and control to a suitable thickness, then dry Remove the solvent to make a prepreg. Use several prepared prepregs to stack each other, press a piece of copper foil on each side of the prepreg, put it into a hot press and solidify to make the copper-clad laminate. Physical data As shown in Table 1.

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Abstract

The invention relates to a resin composition, particularly an epoxy resin composition and a prepreg and a copper clad laminate manufactured by using the epoxy resin composition. The epoxy resin composition provided by the invention cures epoxy resin by using an ester compound and a flexible amine curing agent. The epoxy resin composition has a high glass-transition temperature and good toughness while maintains an excellent dielectric property of the resin composition. The epoxy resin composition provided by the invention applied to the prepreg and the copper clad laminate has the excellent dielectric property, high glass-transition temperature and good impact toughness.

Description

technical field [0001] The invention relates to a resin composition, in particular to an epoxy resin composition and a prepreg and a laminate made using the same. Background technique [0002] In recent years, with the development of high-performance, multi-functional and networked computers and information communication equipment, the amount of data to be processed is increasing, and the speed of signal propagation is also increasing. Therefore, the circuit substrate used is required to have low Excellent dielectric constant and low dielectric loss tangent, and can remain stable at a wide temperature and frequency. At the same time, electronic products are becoming lighter, thinner, shorter, and smaller. The assembly density and integration of components on printed circuit boards are getting higher and higher, which is manifested in smaller and smaller circuit layer spacing and narrower line width. New requirements are put forward for the drilling, punching, gong edge and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08G59/50B32B27/04B32B27/38
CPCC08L63/00C08L71/02C08G59/5033C08G59/504C08G59/686C08J2363/00B32B5/26B32B2264/10B32B2307/3065B32B2457/08C08K3/36C08K5/36C08L67/00B32B15/14B32B15/20B32B2260/021B32B2260/046B32B2262/101B32B2307/204C08J5/244C08J5/249B32B5/02B32B15/092B32B27/08B32B27/12B32B2457/04C08G59/08C08J2363/04C08L63/04H05K1/0306H05K1/0373
Inventor 辛玉军陈勇曾宪平许永静
Owner 江苏生益特种材料有限公司