Method for inhibiting chloroform acidifying during separation of N-methylpyrolidone and chloroform by adding stabilizing agent
A separation process and stabilizer technology, applied in the field of chemical reaction, can solve the problems of complex separation and achieve high process safety, improved recycling efficiency, and low raw material cost
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0021] Experiments were carried out according to this method, using p-nitrophenol as a stabilizer, adding 2.0% of the stabilizer to the NMP / chloroform solution with a mass fraction of NMP of 80%, and stirring to dissolve the stabilizer. Let NMP / chloroform enter vacuum distillation and separation, the separation process temperature is 120° C., and the vacuum degree is 0.90 atmospheric pressure. When detecting the degree of acidification, the volume ratio of NMP / chloroform sample to deionized water is 1:1. After three hours of stable separation process, the pH of the aqueous phase was found to be stable around 4.8, and the acidification phenomenon was suppressed.
Embodiment 2
[0023] Experiments were carried out according to this method, and 1-naphthol was used as a stabilizer. In an NMP / chloroform solution with a mass fraction of NMP of 10%, a stabilizer with a mass fraction of 10.0% was added and stirred to dissolve the stabilizer. Let the NMP / chloroform enter the vacuum distillation separation, the temperature of the separation process is 150° C., and the vacuum degree is 0. When detecting the degree of acidification, the volume ratio of NMP / chloroform sample to deionized water is 1:5. After three hours of stable separation process, the pH of the aqueous phase was found to be stable around 5.2, and the acidification phenomenon was suppressed.
Embodiment 3
[0025] Experiments were carried out according to this method, using glycerol as a stabilizer, adding a 20.0% stabilizer in a NMP / chloroform solution with a mass fraction of 1%, and stirring to dissolve the stabilizer. Let NMP / chloroform enter vacuum distillation and separation, the separation process temperature is 70° C., and the vacuum degree is 0.95 atmospheric pressure. When detecting the degree of acidification, the volume ratio of NMP / chloroform sample to deionized water is 1:10. After three hours of stable separation process, the pH of the aqueous phase was found to be stable around 7.0, and the acidification phenomenon was suppressed.
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com