A kind of mesoporous zirconium phosphate loaded nano-silver antibacterial polyamide fiber and preparation method thereof

An antibacterial polyamide and mesoporous zirconium phosphate technology, applied in the direction of single-component polyamide rayon, etc., can solve the problems of uneven distribution of antibacterial components, difficult continuous production, large amount of addition, etc., and achieve filling preparation technology. Blank, performance does not change color, low cost effect

Active Publication Date: 2017-06-30
DONGHUA UNIV
View PDF1 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in this method, the addition amount is relatively large, and the distribution of antibacterial components is uneven, so it is difficult to realize continuous production

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A mesoporous zirconium phosphate-loaded nano-silver antibacterial polyamide fiber includes a polyamide matrix (polycaprolactam), and Ag@mesoporous zirconium phosphate antibacterial powder is dispersed in the polyamide matrix. The size of the Ag@mesoporous zirconium phosphate antibacterial powder is 200-400nm. The mass ratio of the Ag@mesoporous zirconium phosphate antibacterial powder to the polyamide matrix is ​​3:97.

[0026] The preparation method of above-mentioned mesoporous zirconium phosphate loaded nano-silver antibacterial polyamide fiber is:

[0027] (1) Mesoporous zirconium phosphate is treated with oleum to obtain mesoporous zirconium phosphate with sulfonic acid groups on the surface. The specific steps for treating mesoporous zirconium phosphate with oleum are: oleum with a mass fraction of 98% and mesoporous zirconium phosphate The mass ratio of pore zirconium phosphate is 10:1, the reaction temperature is 40°C, and the reaction is 20 minutes.

[0028] ...

Embodiment 2

[0031] A mesoporous zirconium phosphate-loaded nano-silver antibacterial polyamide fiber includes a polyamide matrix (polycaprolactam), and Ag@mesoporous zirconium phosphate antibacterial powder is dispersed in the polyamide matrix. The size of the Ag@mesoporous zirconium phosphate antibacterial powder is 400-700nm. The mass ratio of the Ag@mesoporous zirconium phosphate antibacterial powder to the polyamide matrix is ​​3:97.

[0032] The preparation method of above-mentioned mesoporous zirconium phosphate loaded nano-silver antibacterial polyamide fiber is:

[0033] (1) Treat mesoporous zirconium phosphate with oleum to obtain mesoporous zirconium phosphate with sulfonic acid groups on the surface. The specific steps for treating mesoporous zirconium phosphate with oleum are: 50% oleum and mesoporous The mass ratio of pore zirconium phosphate is 10:1, the reaction temperature is 40°C, and the reaction is 80 minutes.

[0034] (2) Take silver sulfate, propylene glycol, and me...

Embodiment 3

[0037] A mesoporous zirconium phosphate-loaded nano-silver antibacterial polyamide fiber, comprising a polyamide matrix (polyhexamethylene adipate), in which Ag@mesoporous zirconium phosphate antibacterial powder is dispersed. The size of the Ag@mesoporous zirconium phosphate antibacterial powder is 500-700nm. The mass ratio of the Ag@mesoporous zirconium phosphate antibacterial powder to the polyamide matrix is ​​0.5:99.5.

[0038] The preparation method of above-mentioned mesoporous zirconium phosphate loaded nano-silver antibacterial polyamide fiber is:

[0039] (1) Mesoporous zirconium phosphate is treated with oleum to obtain mesoporous zirconium phosphate with sulfonic acid groups on the surface. The specific steps for treating mesoporous zirconium phosphate with oleum are: oleum with a mass fraction of 80% and mesoporous zirconium phosphate The mass ratio of pore zirconium phosphate is 20:1, the reaction temperature is 50°C, and the reaction is 60 minutes.

[0040] (2...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
sizeaaaaaaaaaa
particle diameteraaaaaaaaaa
pore sizeaaaaaaaaaa
Login to view more

Abstract

The invention provides mesoporous zirconium phosphate-loaded nanosilver antibacterial polyamide fiber and a preparation method of the mesoporous zirconium phosphate-loaded nanosilver antibacterial polyamide fiber. The mesoporous zirconium phosphate-loaded nanosilver antibacterial polyamide fiber is characterized by being prepared from a polyamide substrate, wherein Ag-coated mesoporous zirconium phosphate antibacterial powder is dispersed in the polyamide substrate. The preparation method comprises the steps of preparing the Ag-coated mesoporous zirconium phosphate antibacterial powder; adding raw materials comprising the Ag-coated mesoporous zirconium phosphate antibacterial powder and a polyamide reactive monomer into a polyamide reactor for carrying out in-situ polymerization to prepare a mesoporous zirconium phosphate-nanosilver antibacterial composite material; drying; finally spinning the antibacterial polyamide fiber carrying nanosilver on mesoporous zirconium phosphate through a melt spinning method. The preparation method provided by the invention has the advantages that the operation is simple, effectiveness is realized, the cost is low, the effect is durable, and the application prospect is wide.

Description

technical field [0001] The invention belongs to the field of preparation of antibacterial fibers, in particular to a mesoporous zirconium phosphate-loaded nano-silver antibacterial polyamide fiber and a preparation method thereof. Background technique [0002] In today's society, the extreme environment, environmental pollution and other ecological environments have seriously deteriorated, and special living microenvironments such as confined spaces have led to an urgent need for functional protective textiles. At present, the fibers used to prepare textiles do not have antibacterial ability. Under certain conditions, they will provide an environment for bacteria to survive and reproduce, threatening human health. The main method to solve the antibacterial problem of fibers is to use antibacterial nanoparticles and polymer matrix for composite modification to prepare modified fibers with antibacterial effects. The fiber will gradually release antibacterial ingredients durin...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/90D01F1/10
CPCD01F1/103D01F6/90
Inventor 朱美芳周家良胡泽旭陈伟成艳华陈文萍
Owner DONGHUA UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap