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Ca-Zn composite stabilizer for PVC (polyvinyl chloride) cables and preparation method of Ca-Zn composite stabilizer

A calcium-zinc composite and stabilizer technology, used in circuits, electrical components, plastic/resin/wax insulators, etc., which can solve the problems of large dielectric loss of PVC, increased maintenance costs, and less auxiliary heat stabilizer used alone.

Inactive Publication Date: 2016-05-04
ZHUCHENG POWER SUPPLY CO STATE GRID SHANDONG ELECTRIC POWER CO +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, PVC stabilizers are developing in the direction of high efficiency, non-toxicity, environmental protection and low cost. However, the progress of metal stabilizers is relatively slow, and the research and development of auxiliary heat stabilizers are unprecedentedly active, but auxiliary heat stabilizers are rarely alone. Use, often used in conjunction with the main agent, is the main direction of current development
[0004] The applicant combined the existing technology and long-term work practice, after many times of production use and follow-up observation, and found that although the performance of the existing PVC cables is good, there are still some defects, such as: thermal stability needs to be improved. Further improvement, due to the large dielectric loss of PVC, the heat generated during the use of medium and low voltage cables below 15kv will easily degrade PVC itself, shorten the service life of the cable, increase the cost of maintenance, and further improve Limit the use environment of PVC cables and narrow the scope of use

Method used

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  • Ca-Zn composite stabilizer for PVC (polyvinyl chloride) cables and preparation method of Ca-Zn composite stabilizer
  • Ca-Zn composite stabilizer for PVC (polyvinyl chloride) cables and preparation method of Ca-Zn composite stabilizer

Examples

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Embodiment 1

[0038] A calcium-zinc composite stabilizer for PVC cables, made of the following raw materials in parts by weight: 45 parts of calcium stearate, 15 parts of zinc stearate, 10 parts of dibutyl tin maleate, 10 parts of hydrotalcite, 5 parts of polyethylene wax, 25 parts of composite calcium carbonate, 3 parts of pentaerythritol diester, 10 parts of epoxy rubber tree oil;

[0039] Described composite calcium carbonate is 1:1 by weight ratio by micron calcium carbonate and nanometer calcium carbonate

[0040] The above-mentioned production method comprises the following steps:

[0041] (1) Purchasing each raw material by weight for use;

[0042] (2) Synthesis of hydrotalcite: Add a certain amount of magnesium nitrate and aluminum nitrate into water to prepare a salt solution, in which the concentration of magnesium nitrate is 0.85mol / L, and the concentration of aluminum nitrate is 0.4mol / L. Add a certain amount of sodium carbonate and sodium hydroxide to water at 40°C to prepare...

Embodiment 2

[0047]A calcium-zinc composite stabilizer for PVC cables, made of the following raw materials in parts by weight: 50 parts of calcium stearate, 20 parts of zinc stearate, 11 parts of dibutyltin maleate, 12 parts of hydrotalcite, oxidized polystyrene 7 parts of ethylene wax, 12 parts of micron calcium carbonate, 15.5 parts of nano calcium carbonate, 4 parts of pentaerythritol diester, 13 parts of epoxy rubber tree oil.

[0048] The preparation method is the same as in Example 1.

Embodiment 3

[0050] A calcium-zinc composite stabilizer for PVC cables is made of the following raw materials in parts by weight: 65 parts of calcium stearate, 25 parts of zinc stearate, 12 parts of dibutyl tin maleate, 15 parts of hydrotalcite, oxidized polystyrene 10 parts of ethylene wax, 30 parts of complex calcium carbonate, 6 parts of pentaerythritol diester, 15 parts of epoxy rubber tree oil;

[0051] The composite calcium carbonate consists of micron calcium carbonate and nano calcium carbonate in a weight ratio of 1:1.5.

[0052] The preparation method is the same as in Example 1.

[0053] The vibration-milling equipment used in the present invention is common equipment in the field, and will not be repeated here.

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Abstract

The invention discloses a Ca-Zn composite stabilizer for PVC (polyvinyl chloride) cables and a preparation method of the Ca-Zn composite stabilizer. The Ca-Zn composite stabilizer is prepared from raw materials in parts by weight as follows: 45-65 parts of calcium stearate, 15-25 parts of zinc stearate, 10-12 parts of dibutyltin maleate, 10-15 parts of hydrotalcite, 5-10 parts of oxidized polyethlene wax, 25-30 parts of compound calcium carbonate, 3-6 parts of pentaerythritol dimer ester and 10-15 parts of epoxy rubber seed oil, wherein compound calcium carbonate comprises micron-calcium carbonate and nano-scale calcium carbonate in the weight ratio of 1:(1-1.5). The invention further discloses the preparation method of the Ca-Zn composite stabilizer. The Ca-Zn composite stabilizer and the preparation method have the following benefits: through regulation of the ratio of the raw materials, the quality of the stabilizer is improved, the quality of the cables is improved, self-degradation of PVC is retarded, the service life of the cables is prolonged, and the maintenance cost is reduced.

Description

technical field [0001] The invention relates to a stabilizer and a preparation method thereof, in particular to a calcium-zinc composite stabilizer for PVC cables and a preparation method thereof. Background technique [0002] Heat stabilizers are a class of additives that can prevent or reduce self-degradation or crosslinking of polymers due to heat during processing and use, and prolong the service life of materials. They mainly include bases, metal soaps, composites and pure organics. Different types of stabilizers can inhibit the discoloration or deterioration of PVC during processing or use to varying degrees. The principle is mainly to use different components in the stabilizer to inhibit the thermal degradation of PVC by replacing unstable chlorine atoms, neutralizing hydrogen chloride and reacting with unsaturated parts. The demand and output of heat stabilizers increase with the demand and output of PVC cables, and are continuously improved according to the use env...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L91/00C08L23/30C08L67/00C08K13/02C08K5/098C08K5/57C08K3/26H01B3/44
CPCC08L91/00C08K2201/011C08K2201/014C08L27/06C08L2201/08C08L2203/202C08L2205/03C08L2205/035H01B3/443C08L23/30C08L67/00C08K13/02C08K5/098C08K5/57C08K3/26C08K2003/265
Inventor 隋东阳
Owner ZHUCHENG POWER SUPPLY CO STATE GRID SHANDONG ELECTRIC POWER CO
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