A colloidal slow-release material for in-situ restoration of groundwater and its preparation method

An in-situ repair and slow-release material technology, applied in the field of environmental pollution control and repair, can solve the problems of reducing the use efficiency of active repair agents, the influence of morphology, structure and particle size, and the short half-life of active repair agents, so as to improve the groundwater quality. In-situ remediation efficiency of chlorinated olefin pollution, easy-to-operate preparation method, and low operating condition requirements

Active Publication Date: 2018-10-23
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The applied in-situ remediation technology still has the following defects in actual site remediation: (1) The commonly used active remediation agents have short half-life, poor stability, and are easily consumed by natural organic matter in the aquifer, thereby reducing the use efficiency of active remediation agents; ( 2) The active remediation agent is mostly injected into the underground aquifer in the form of liquid or gas, which is easy to migrate out of the polluted area under the action of convection, and cannot contact the pollutants in the low-permeability area due to the preferential channel effect. Reduce remediation efficiency; (3) The by-products and permanent impact on the underground environment caused by excessive injection of remediation agents will also limit their use
However, in actual site applications, since the reported slow-release materials are mostly solid, affected by their morphology and particle size, the on-site construction technology is cumbersome, the cost is relatively high, and the scope of applicable sites is limited.

Method used

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  • A colloidal slow-release material for in-situ restoration of groundwater and its preparation method
  • A colloidal slow-release material for in-situ restoration of groundwater and its preparation method
  • A colloidal slow-release material for in-situ restoration of groundwater and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Slow release and effect of embodiment 1 permanganate oxidant

[0053] A permanganate solution with a concentration of 10g / L was prepared as the restorative solution, and then fumed silicon dioxide was added to make the mass fraction of the colloidal particles in the suspension be 7%, and mixed evenly to obtain the colloidal slow-release material.

[0054] Place the prepared slow-release material at the bottom of a 250ml Erlenmeyer flask, and slowly inject 200ml of ultrapure water to avoid disturbing the surface morphology of the colloidal slow-release material. Keep the water in the Erlenmeyer flask at room temperature in a still state. Observing MnO through Visibility Observation 4 - Sustained release process, such as figure 1 As shown, the colloidal sustained-release material always maintains its original shape and size, and there is a clear interface between the colloid and the water phase. The color of the colloidal sustained-release material gradually changes fr...

Embodiment 2

[0057] Embodiment 2 Colloid slow-release material oxidized trichlorethylene effect

[0058] A permanganate solution with a concentration of 4g / L was prepared, and fumed silica was added to make the mass fraction of the colloidal particles in the suspension to be 7%, and the mixture was evenly mixed. The suspension was stirred on a stirrer at a speed of 600 rpm for 1 h, and the viscosity was reduced by 95% compared with before.

[0059] 10ml of permanganate solution or permanganate colloid slow-release material (containing MnO 4 - The same quantity) was injected into the bottom of the water-saturated sand column through a syringe. The peristaltic pump controls the flow rate to 2.56m / d, rinses the entire packed column with 10mg / L trichlorethylene (TCE) solution from bottom to top, and begins to collect effluent samples. The sample taken was injected directly via needle into a 20ml headspace vial already filled with 10ml of methylene chloride. The headspace bottle was placed ...

Embodiment 3

[0063] The sustained release of embodiment 3 sodium persulfate oxidant

[0064] Prepare a sodium persulfate solution with a mass concentration of 10%, and then add silicon dioxide aerosol to make the mass fraction of colloidal particles in the suspension be 5%, and mix evenly. The suspension was stirred on a stirrer at a speed of 600rpm for 1 hour, and the viscosity was reduced by 95% compared with before to obtain a sodium persulfate colloid slow-release material.

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Abstract

The invention discloses a colloid sustained-release material for underground water in-situ remediation and a preparation method of the colloid sustained-release material for underground water in-situ remediation. The colloid sustained-release material is colloidal suspension formed by sufficient mixing of an active remediation agent and colloidal silicon dioxide, wherein a mass ratio of the active remediation agent to the colloidal silicon dioxide is 93-99:1-7, initial viscosity of the colloidal suspension is less than 60cP, and after the colloidal suspension is injected into an underground aquifer, viscosity is increased gradually, semisolid gel is formed finally, and the active remediation agent is released into the aquifer gradually. The colloid sustained-release material for underground water in-situ remediation and the preparation method of the colloid sustained-release material have the advantages that initial injection viscosity of the colloid sustained-release material can be less than 60cP, difficulty in injection into the ground is reduced and accordingly the colloid sustained-release material and the preparation method can be popularized in various types of contaminated sites; after the colloid sustained-release material forms the gel gradually, active remediation agent release time is prolonged by 5-7 times, fluid remediation agent loss and repeated construction defects are avoided, cost saving is achieved and underground water remediation efficiency is improved.

Description

technical field [0001] The invention belongs to the technical field of environmental pollution control and restoration, and relates to a colloidal slow-release material for in-situ restoration of groundwater and a preparation method thereof. Background technique [0002] With the rapid development of my country's national economy and industry, the problem of environmental pollution has become increasingly prominent. Toxic and harmful pollutants enter the underground environmental system through various channels, causing groundwater pollution. In recent years, groundwater pollution around cities and industrial enterprises has become increasingly serious, threatening drinking water safety and human health. Chlorinated olefins are widely used as solvents in metal processing, electronics, dry cleaning and other industries, thus becoming one of the types of pollutants widely distributed in the underground environment [ 1 ] . At the same time, chlorinated olefins were also d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/00C02F1/72C02F1/70C02F3/00C02F103/06
CPCC02F1/00C02F1/70C02F1/72C02F3/00C02F2103/06C02F2305/06
Inventor 李广贺杨硕
Owner TSINGHUA UNIV
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