Graphene electrolyte for lead-acid storage battery and preparation method of graphene electrolyte

A lead-acid battery and graphene technology, applied in the direction of lead-acid batteries, acid electrolytes, aqueous electrolytes, etc., can solve the problems of poor acid-fixing ability, large electrolyte internal resistance, short service life, etc., to increase the reaction capacity, increase Activation energy, effect of enhancing flow activity

Active Publication Date: 2016-06-15
江西力之奇新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a graphene electrolyte for lead-acid batteries that improves battery performance and improves battery c

Method used

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Examples

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Example Embodiment

[0028] Example 1

[0029] A graphene electrolyte for lead-acid batteries, consisting of the following components by mass percentage: 0.2% graphene aqueous solution, 0.8% sodium sulfate, 0.1% stannous sulfate, 5% silica sol, 0.5% sodium carboxymethyl cellulose, The remainder is sulfuric acid solution, and the graphene content of the graphene aqueous solution is 0.5×10 -3 g / ml; SiO in the silica sol 2 The mass percentage content is 10%.

[0030] The modification of graphene before being configured into a graphene aqueous solution includes the following steps:

[0031] 1) Mix graphene particles, 15% sodium dibutyl naphthalene sulfonate solution and acid solution at a material-to-liquid ratio of 1g:45mL:18mL, control the temperature at 95℃, stir and mix for 10min, filter, and use water and no Wash with water and ethanol, and vacuum dry at 180°C for 15 minutes to obtain primary modified graphene particles;

[0032] 2) Mix the primary modified graphene particles with the chemical shearing ...

Example Embodiment

[0038] Example 2

[0039] A graphene electrolyte for lead-acid batteries, consisting of the following components by mass percentage: 1.5% graphene aqueous solution, 1.5% potassium sulfate, 0.8% sodium sulfate, 0.3% stannous sulfate, 20% silica sol, 3% carboxymethyl Base cellulose sodium, the balance is sulfuric acid solution, the graphene content of the graphene aqueous solution is 7×10 -3 g / ml; SiO in the silica sol 2 The mass percentage of 15%.

[0040] The modification of graphene before being configured into a graphene aqueous solution includes the following steps:

[0041] 1) Mix graphene particles, 18% sodium dibutylnaphthalene sulfonate solution and acid solution at a material-to-liquid ratio of 1g:50mL:20mL, control the temperature at 110℃, stir and mix for 15min, filter, and use water and without Wash with water and ethanol, and vacuum dry at 200°C for 20 minutes to obtain primary modified graphene particles;

[0042] 2) Mix the primary modified graphene particles with the c...

Example Embodiment

[0048] Example 3

[0049] A graphene electrolyte for lead-acid batteries, consisting of the following components by mass percentage: 5% graphene aqueous solution, 1.5% sodium sulfate, 1.5% potassium sulfate, 0.8% zinc sulfate, 1.2% aluminum sulfate, 0.7% stannous sulfate , 30% silica sol, 6% sodium carboxymethyl cellulose, the balance is sulfuric acid solution, the graphene content of the graphene aqueous solution is 10×10 -3 g / ml; SiO in the silica sol 2 The mass percentage of 23%.

[0050] The modification of graphene before being configured into a graphene aqueous solution includes the following steps:

[0051] 1) Mix the graphene particles, 20% sodium dibutylnaphthalene sulfonate solution and acid solution at a material-to-liquid ratio of 1g:55mL:23mL, control the temperature at 120℃, stir and mix for 25min, filter, and use water and without Wash with water and ethanol, and vacuum dry at 220°C for 25 minutes to obtain primary modified graphene particles;

[0052] 2) Mix the prima...

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Abstract

The invention discloses a graphene electrolyte for a lead-acid storage battery. The graphene electrolyte comprises the following components: a graphene water solution, sulfate, stannous mono-sulphate, silica sol, sodium carboxymethylcellulose and the balance of a sulfuric acid solution. With the graphene water solution as an electrolyte additive, the flow activity of the electrolyte can be strengthened; the reaction capacity of the electrolyte and an active material is improved; the activation energy of the electrode surface is increased; the obstacle of a lead sulfate film on the lead surface to electron conduction is reduced; the oxygen cycle efficiency is improved; sulfation of particles are reduced; and the service lifetime of a deep cycle is prolonged.

Description

technical field [0001] The invention relates to the field of lead-acid batteries, in particular to a graphene electrolyte for lead-acid batteries and a preparation method thereof. Background technique [0002] Lead-acid batteries have the advantages of reliable performance, long storage life, low price, and easy availability of raw materials. They have been widely used in various fields, especially power applications, telecommunications fields, backup power supplies, and energy storage power supplies. The five major components of a lead-acid battery are the positive electrode, the negative electrode, the separator, the electrolyte, and the battery case, among which the electrolyte is one of the main factors affecting battery performance. Ordinary electrolytes have high internal resistance, poor acid-fixing ability, and short service life. Therefore, selecting and using appropriate electrolyte additives can greatly improve battery performance. [0003] As an important part o...

Claims

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Application Information

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IPC IPC(8): H01M10/08
CPCH01M10/08H01M2300/0011Y02E60/10
Inventor 吴秋菊杨新新周明明戴贵平吴亮柯娃石沫
Owner 江西力之奇新能源科技有限公司
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