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A Composite Membrane Separation Method Applicable to Sewage Desalination and Reuse

A separation method and composite membrane technology, applied in separation methods, dispersed particle separation, permeation/dialysis water/sewage treatment, etc., can solve the problem of increasing the selective permeability of cations and anions, unable to solve the damage of particle pollutants, and ion exchange membranes High cost and other issues, to achieve the effect of prolonging the membrane cleaning cycle, reducing energy consumption, and improving desalination effect

Active Publication Date: 2018-02-09
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing research results and literature reports mainly focus on the optimization of the electro-adsorption process, and the results related to desalination in the domestic patents are also concentrated on the operating conditions of membrane separation and electro-adsorption alone, such as Takafumi Kiuchi (membrane separation device and Membrane separation method invention patent publication number 103052437), Chang Zheng (a kind of selective removal of Fe from industrial wastewater by electro-adsorption technology 2+ and / or Fe 3+ method (invention patent publication number 104609518), but there are few reports on the coupling process of membrane separation and electrosorption
One of the few processes that combines the two, such as Zhang Hongtao (a membrane-electroadsorption device for desalination system invention patent publication number 103693718) uses ion-exchange membranes combined with electro-adsorption processes to desalinate wastewater, which adds cation exchange membranes and The purpose of the anion-exchange membrane is to increase the selective permeability of cations and anions respectively, and the ion-exchange membrane cannot filter sewage; secondly, the system still cannot solve the damage of particle pollutants to the device itself, and the cost of the ion-exchange membrane is high, and the operation Maintenance is more troublesome

Method used

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  • A Composite Membrane Separation Method Applicable to Sewage Desalination and Reuse
  • A Composite Membrane Separation Method Applicable to Sewage Desalination and Reuse

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] use figure 1 In the process device shown in , the water inlet system 1 is composed of an inlet pool and an inlet water flow regulating device, and the brackish water mainly composed of NaCl that has been pretreated and meets the process requirements is connected to the inlet pool, and the salt content of the inlet water is 1200 mg / L (calculated as TDS), adjust the influent flow, and control the flux to 10 L / m 2 h. The water outlet of the water inlet tank is connected to the membrane reactor through a pipeline, and the outlet water of the water inlet tank enters the membrane reactor. The membrane reactor is composed of a reaction tank, a composite membrane module 6 and a stirring system. figure 2The composite membrane module shown in , in which the anode composite membrane is bonded by titanium mesh and carbon cloth through PVDF, the cathode composite membrane is bonded by stainless steel mesh and carbon cloth through PVDF, and the separation layer is non-woven fabric...

Embodiment 2

[0029] use figure 1 The process device shown in , the water inlet system 1 is composed of the water inlet tank and the water inlet flow adjustment device, and the biologically treated effluent of the cold rolling wastewater that has been pretreated and meets the process requirements is connected to the water inlet tank, and the salt content of the water inlet is 1000 mg / L (calculated as TDS), the concentration of suspended solids is 50 mg / L, adjust the influent flow, and the control flux is 40 L / m 2 h. The water outlet of the water inlet tank is connected to the membrane reactor through a pipeline, and the outlet water of the water inlet tank enters the membrane reactor. The membrane reactor is composed of a reaction tank, a composite membrane module 6 and a stirring system. figure 2 The composite membrane module shown in , in which both the anode composite membrane and the cathode composite membrane are bonded by titanium mesh and carbon cloth through PAN, and the separat...

Embodiment 3

[0031] use figure 1 The process device shown in , the water inlet system 1 is composed of the water inlet tank and the water inlet flow adjustment device, and the industrial wastewater mainly composed of nitrates that has been pretreated and met the process requirements is connected to the water inlet tank, and the water contains salt The amount is 900 mg / L (calculated as TDS), adjust the influent flow, and control the flux to 10 L / m 2 h. The water outlet of the water inlet tank is connected to the membrane reactor through a pipeline, and the outlet water of the water inlet tank enters the membrane reactor. The membrane reactor is composed of a reaction tank, a composite membrane module 6 and a stirring system. figure 2 The composite membrane assembly shown in , wherein both the anode composite membrane and the cathode composite membrane are composed of titanium mesh and carbon nanotubes, the separation layer is nylon mesh, and the cathode composite membrane assembly is con...

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PUM

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Abstract

Disclosed is a composite membrane separation method applicable to desalting and recycling of sewage. The method achieves desalting of the sewage through a filtering and adsorbing effect of a conductive composite membrane reactor. The conductive composite membrane reactor consists of a water inlet system (1), a power source system (2), a membrane reactor (3), a water outlet control system (4) and a clean water tank (5). The membrane reactor (3) consists of a reaction tank, a composite membrane module (6) and a stirring system. The composite membrane module (6) has a flat sheet membrane configuration and consists of a cathode composite membrane (8), an anode composite membrane (9) and a separation layer (10), wherein the cathode composite membrane (8) is formed by adhering, using a polymeric material, a cathode electrode (12) with a cathode current collector (11) and the anode composite membrane (9) is formed by adhering, using a polymeric material, an anode electrode (13) with an anode current collector (14). The cathode composite membrane (8) and the anode composite membrane (9) are separated by the separation layer (10) to avoid a short circuit. The cathode current collector (11) is disposed on the same side as a water inlet, the anode current collector (14) is disposed on the same side as a water outlet. Influent water first flows through the cathode current collector (11) and the cathode electrode (12), then the separation layer (10), and then the anode electrode (13) and the anode current collector (14), and is discharged from the conductive composite membrane reactor in the form of membrane effluent water.

Description

technical field [0001] The invention relates to a composite membrane separation method suitable for sewage desalination and reuse, which uses the coupling principle of membrane filtration and electric adsorption to remove ions in sewage and improve the quality of effluent, belonging to the field of sewage (waste) water treatment. Background technique [0002] With the rapid development of social economy, the environmental situation is becoming more and more severe. Among many environmental problems, the shortage of water resources is becoming more and more serious, which has become a major bottleneck restricting the sustainable development of social economy. Under such circumstances, simply advocating water conservation is not enough to meet the current water demand. It is urgent to develop and utilize unconventional water sources, such as desalination of brackish water, recycling of industrial wastewater, and advanced treatment and reuse of municipal wastewater. Groundwater...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/469C02F1/44
Inventor 王志伟李子梦于鸿光马金星吴志超郑君健王雪野潘辰
Owner TONGJI UNIV
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