Alkylation reaction method for isoparaffin and alkene with liquid acid for catalysis

A technology of alkylation reaction and isoparaffin, applied in chemical instruments and methods, organic chemistry, hydrocarbons, etc., can solve the problems of unsatisfactory mixing, bulky equipment, and insufficient compact structure, etc., and achieve improved microscopic mixing The effect of high level, low equipment investment and easy processing

Inactive Publication Date: 2016-10-19
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the mixing of the acid hydrocarbon emulsion and other reactants in the riser is not satisfactory. In addition, the entire reactor system uses a riser, two horizontal tanks and a downcomer, and the equipment is huge and the structure is not compact enough.

Method used

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  • Alkylation reaction method for isoparaffin and alkene with liquid acid for catalysis

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] As shown in the figure, this embodiment provides a method and device using concentrated sulfuric acid as an alkylation catalyst.

[0043] Alkylation catalyst Concentrated sulfuric acid (98.5% concentration, the same below) and circulating acid are pumped into a set of static mixer 1 (Sulzer Construction Machinery Manufacturing Co., Ltd. SMV) through circulating acid pump 4 TM type, the same below), the circulating hydrocarbon is returned to the alkylation reaction raw material through the circulating hydrocarbon pump 5 through the pipeline 10 (the raw material line is divided into 2 routes), and mixed with the prepared fresh raw material with an alkene ratio of 8.3:1, Vertically enter the side part of the static mixer 1, and the acid hydrocarbon phase in the static mixer is strongly mixed, so that the olefins in the mixed material can reach a microscopic mixed state. The uniformly mixed mixed material reacts for a period of time and then enters the separator 2 under red...

Embodiment 2

[0046] As shown in the figure, this embodiment provides a method and device using concentrated sulfuric acid as an alkylation catalyst.

[0047] Alkylation catalyst Concentrated sulfuric acid (98.5% concentration, the same below) and circulating acid are pumped into a set of static mixer 1 (Sulzer Construction Machinery Manufacturing Co., Ltd. SMV) through circulating acid pump 4 TMtype, the same below), the circulating hydrocarbon is returned to the alkylation reaction raw material through the circulating hydrocarbon pump 5 through the pipeline 10 (the raw material line is divided into 4 routes), and mixed with the prepared fresh raw material with an alkene ratio of 9.5:1, Vertically enter the side part of the static mixer 1, and the acid hydrocarbon phase in the static mixer is strongly mixed, so that the olefins in the mixed material can reach a microscopic mixed state. The uniformly mixed mixed material reacts for a period of time and then enters the separator 2 under redu...

Embodiment 3

[0050] As shown in the figure, a kind of strongly acidic AlCl provided in this embodiment 3 A method and an apparatus for using an ionic liquid as an alkylation catalyst.

[0051] Alkylation Catalyst Strongly Acidic AlCl 3 Type ionic liquid (concentration is 95.0%, the same below) and circulating acid are injected into a group of static mixer 1 (Sulzer Engineering Machinery Manufacturing Co., Ltd. SMV) through circulating acid pump 4 TM type, the same below), the circulating hydrocarbon is returned to the alkylation reaction raw material through the circulating hydrocarbon pump 5 through the pipeline 10 (the raw material line is divided into 3 routes), and mixed with the prepared fresh raw material with alkene ratio of 7.5:1, Vertically enter the side part of the static mixer 1, and the acid hydrocarbon phase in the static mixer is strongly mixed, so that the olefins in the mixed material can reach a microscopic mixed state. The uniformly mixed mixed material reacts for a pe...

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Abstract

The invention provides an alkylation reaction method for isoparaffin and alkene with liquid acid for catalysis. The method is characterized in that the method comprises the following steps: alkylation reaction raw materials are fed from a side surface of a static mixer in one stream or several streams, the raw materials and an acid hydrocarbon emulsion which is in a main runner of the static mixer are mixed and contacted, after the mixture is reacted and contacted for 0.2-15 minutes, pressure reduction is carried out for the mixture, the mixture enters a separator, the pressure of the separator is controlled at 0.005-0.18MPa, butane is vaporized in order to take away reaction heat, the acid phase below the separator is supercharged by an acid circulation pump and recycled to the main runner of the static mixer; gas phase components which are separated from an upper part of the separator enter a compressor system, and the components are compressed and condensed by a compressor in order to cool the alkylation reaction raw materials; a hydrocarbon phase which is partially separated from the separator enters a coalescer, most of the hydrocarbon phase which is separated from the coalesce is supercharged by a hydrocarbon circulation pump and mixed with the raw materials, and the mixture enters the side surface of the static mixer for feeding; an acid phase which is separated from the lower part of the coalesce returns an inlet of the circulation pump; a small part of a hydrocarbon phase which is extracted from the upper part of the coalescer enters a deisobutanizer, isobutane which is obtained from the top of the deisobutanizer is circulated and returns to the static mixer, and alkylation products are obtained from the bottom of the deisobutanizer.

Description

technical field [0001] The invention relates to a liquid acid alkylation reaction method, in particular to a liquid acid-catalyzed alkylation reaction method of isoparaffins and olefins. Background technique [0002] The alkylation reaction of isoparaffins and olefins mainly refers to the alkylation reaction of isobutane and butene. The essence of the reaction is the organic addition of alkane molecules to olefin molecules in the presence of acidic catalysts. reaction. Alkylation is an important process in the petrochemical industry. The isomeric C produced by the reaction of isobutane and butene under the action of a strong acid catalyst 8 Alkanes, known as alkylated gasoline. Alkylated gasoline has high octane number (RON94-96) and low Reid vapor pressure, very low sulfur content and olefin content, no benzene and aromatics, and is an excellent gasoline blending component. The use of new formula gasoline as the fuel for gasoline engines will greatly alleviate the urban...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C9/16C07C2/62
Inventor 董明会温朗友宗保宁慕旭宏喻惠利俞芳郜亮夏玥穜
Owner CHINA PETROLEUM & CHEM CORP
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