Bulletproof material introduced with thermosetting epoxy resin and preparation method thereof

An epoxy resin and thermosetting technology, which is applied in the field of bulletproof fiber composite materials, bulletproof materials and their preparation, can solve the problems of insufficient fiber adhesion, unfavorable wearing, insufficient rigidity, etc., and achieves low hygroscopicity, high reactivity, The effect of high curing temperature

Active Publication Date: 2018-09-25
CHINA BLUESTAR CHENGRAND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Soft body armor is easy to loose without restraint
The third type is soft and hard composite body armor. Its base is soft body armor. In the reserved interlayer, ceramic plates or metal material composite plates are added as internal reinforcement materials, which are bulky and not conducive to wearing.
Generally, thermoplastic resins such as polyurethane elastomer TPU or polyvinyl butyral PVB are used in bulletproof materials, which have the advantages of good flexibility and good mechanical relaxation, but they show insufficient rigidity in bulletproof materials with special armor structures. Disadvantages of insufficient fiber adhesion
The present invention introduces thermosetting epoxy resin into the bulletproof material, which not only endows the material with the characteristics of light weight, softness, good flexibility, and high strength, but also has no relevant reports at home and abroad.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The bulletproof material with thermosetting epoxy resin is introduced, which is a composite material made of matrix resin and fiber;

[0042] The base resin is made of the following raw materials in parts by weight: 10 parts of polyvinyl butyral, 2 parts of epoxy resin, 50 parts of diluent, 1 part of curing agent, and 0.6 parts of auxiliary agent; the base resin, Composite with fibers at a weight ratio of 80:100.

[0043] The molecular weight of described polyvinyl butyral is 100,000;

[0044] Described epoxy resin is bisphenol A type epoxy resin E-51;

[0045] Described diluent is made up of the methanol of 60wt% and the ethanol of 40wt%;

[0046] Described curing agent is dicyandiamide slurry, specifically the mixture that is made up of the epoxy resin of 70wt%, the dicyandiamide of 25wt% and the accelerator of 5wt%;

[0047] The dicyandiamide is an ultrafine powder with a particle size of <10 μm;

[0048] Described accelerator is phenyl dimethyl urea;

[0049] D...

Embodiment 2

[0052] The bulletproof material with thermosetting epoxy resin is introduced, which is a composite material made of matrix resin and fiber;

[0053] The base resin is made of the following raw materials in parts by weight: 13 parts of polyvinyl butyral, 10 parts of epoxy resin, 85 parts of diluent, 8 parts of curing agent, and 0.6 parts of auxiliary agent; the base resin, Composite with fibers at a weight ratio of 70:100.

[0054] The molecular weight of described polyvinyl butyral is 100,000;

[0055] Described epoxy resin is made up of novolac type epoxy resin F-44 and F-51 by equal weight ratio;

[0056] Described diluent is made up of n-butanol, Virahol, toluene in equal weight ratio;

[0057] The curing agent is a phenolic resin with a molecular weight of 500-1000;

[0058] Described auxiliary agent is selected from Corning auxiliary agent Perenol S43;

[0059] The fibers are ultra-high molecular weight polyethylene fibers.

Embodiment 3

[0061] The bulletproof material with thermosetting epoxy resin is introduced, which is a composite material made of matrix resin and fiber;

[0062] The base resin is made of the following raw materials in parts by weight: 18 parts of polyvinyl butyral, 5 parts of epoxy resin, 75 parts of diluent, 6 parts of curing agent, and 0.6 parts of auxiliary agent; the base resin, Composite with fibers at a weight ratio of 60:100.

[0063] The molecular weight of described polyvinyl butyral is 100,000;

[0064] Described epoxy resin is made up of bisphenol A type epoxy resin E-20 and novolak type epoxy resin F-51 by the weight ratio of 1:2;

[0065] Described diluent is made up of acetone, butanone, cyclohexanone, ethyl acetate, propylene glycol methyl ether acetate in equal weight ratio;

[0066] The curing agent is a phenolic resin with a molecular weight of 500-1000;

[0067] Described auxiliary agent is selected from Corning auxiliary agent Texaphor P63;

[0068] The said fiber ...

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Abstract

The invention provides a bulletproofing material with thermoset epoxy resin and a preparation method thereof and belongs to the fields of polymer composites and armor protection. The bulletproofing material is a composite formed by combining matrix resin and fiber. The matrix resin is prepared from, by weight, 10-20 parts of polyvinyl butyral, 1-10 parts of epoxy resin, 50-85 parts of diluents, 1-10 parts of a curing agent and 0.6 part of auxiliaries. The epoxy resin is selected from one or any combination of two or more of bisphenol A type epoxy resin E-51, E-44 and E-20, bisphenol F type epoxy resin NPEF170, phenolic aldehyde type epoxy resin F-44 and F51 and polyfunctional group epoxy AG-80. The bulletproofing material can ensure the bearing strength and the bulletproofing performance and has the advantages of being light, good in softness and comfortable to wear when the bulletproofing material is used for body armors; when the bulletproofing material is used for bulletproofing armors, rigidity can be improved, and the weight of the bulletproofing armors can be reduced, and therefore the bulletproofing material has wide application value.

Description

technical field [0001] The invention relates to a bulletproof material and a preparation method thereof, in particular to a composition resin of polyvinyl butyral and epoxy resin, which is applied to fiber composite materials for bulletproof, and belongs to polymer composite materials and armor protection field. Background technique [0002] Since World War II, the development of bulletproof materials has been changing with each passing day. Especially in recent years, the world's anti-terrorism situation is severe, and human beings have strengthened their own safety protection awareness. The development of bulletproof materials is particularly important. It can be divided into three types according to different materials. The first type is hard body armor, which is made of steel plates or ceramic plates. Or shrapnel, it is inconvenient to wear and move, it is cumbersome and cannot protect the whole body, and has irreparable shortcomings. The second type is soft bulletproo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/10C08L23/06C08L29/14C08L63/00C08L63/04C08G59/40C08G59/62
CPCC08G59/4021C08G59/62C08L23/06C08L77/10C08L2201/02C08L2201/08C08L2205/02C08L2205/025C08L2205/03C08L2205/035C08L2205/16C08L2207/068C08L29/14C08L63/00C08L63/04
Inventor 王洪李晓娟杨旭明
Owner CHINA BLUESTAR CHENGRAND CO LTD
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