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High-quality and high-volume phosphorous slag cement produced through phosphorus slag and production method of cement

A high-dosage, phosphorus slag technology, applied in clinker production, cement production, etc., can solve the problems of wasting natural resources, high production costs, and high energy consumption for calcination, so as to reduce energy consumption for sintering, improve utilization rate, Improves the effect of hydration activity

Inactive Publication Date: 2016-11-09
GEZHOUBA SONGZI CEMENT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It not only wastes a lot of natural resources, but also consumes a lot of energy for calcination, and the production cost is high

Method used

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  • High-quality and high-volume phosphorous slag cement produced through phosphorus slag and production method of cement
  • High-quality and high-volume phosphorous slag cement produced through phosphorus slag and production method of cement
  • High-quality and high-volume phosphorous slag cement produced through phosphorus slag and production method of cement

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The specific operation of using phosphorus slag to produce high-quality and high-volume phosphorus slag cement is as follows:

[0035] The incoming raw materials should be as stable as possible, and the main raw materials should be made from a single ore as much as possible. Shale, phosphorus slag, sandstone, limestone, and iron ore should be used as five-component ingredients, and sandstone should be used as siliceous correction material to adjust SiO in the raw meal. 2 . Make a batching plan according to the chemical composition of each raw material, put it into the raw material mill for grinding according to the ratio of the batching plan, and finally mix. Wherein the chemical composition of the raw material in implementation is shown in Table 1:

[0036] The chemical composition of table 1 raw material

[0037] raw material

Loss on ignition

SiO 2

Al 2 o 3

Fe 2 o 3

CaO

MgO

K 2 o

Na 2 o

R 2 o

Cl -

...

Embodiment 2

[0062] A kind of cement that utilizes phosphorus slag to produce high-quality and high-volume phosphorus slag, the cement includes the following ingredients in parts by weight:

[0063] 55 parts of clinker;

[0064] Mixed materials: 26 parts of phosphorus slag, 5 parts of limestone, 2 parts of gypsum, 0.01 part of grinding aid.

[0065] The raw meal for producing the clinker is prepared with shale, phosphorus slag, sandstone, limestone and iron ore, and the SiO in the raw meal is adjusted with sandstone as the siliceous correcting raw material. 2 .

[0066] The raw meal contains phosphorus slag with a weight ratio of 3%, and the lime saturation coefficient of the clinker is 0.92; the silicon rate is 2.5; the tricalcium aluminate content is 8%, the free calcium oxide content is 1250g / L.

[0067] The grinding aid is triethanolamine and triisopropanolamine mixed in a weight ratio of 1:1.

[0068] The gypsum is natural dihydrate gypsum.

[0069] Described phosphorus slag com...

Embodiment 3

[0072] A kind of cement that utilizes phosphorus slag to produce high-quality and high-volume phosphorus slag, the cement includes the following ingredients in parts by weight:

[0073] 68 parts of clinker;

[0074] Mixed materials: 39 parts of phosphorus slag, 6 parts of limestone, 4 parts of gypsum, 0.04 parts of grinding aid.

[0075] The raw meal for producing the clinker is prepared with shale, phosphorus slag, sandstone, limestone and iron ore, and the SiO in the raw meal is adjusted with sandstone as the siliceous correcting raw material. 2 .

[0076] The raw meal contains phosphorus slag with a weight ratio of 5%, and the lime saturation coefficient of the clinker is 0.96; the silicon rate is 2.7; the tricalcium aluminate content is 9%, the free calcium oxide content is 1250g / L.

[0077] The grinding aid is triethanolamine and triisopropanolamine mixed in a weight ratio of 1:1.

[0078] The gypsum is natural dihydrate gypsum.

[0079] Described phosphorus slag co...

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Abstract

The invention relates to the field of cement production, in particular to high-quality and high-volume phosphorous slag cement produced through phosphorus slag and a production method of the cement. The production method specifically comprises the following steps that shale, the phosphorous slag, sandstone, limestone and iron ores are used as ingredients, the sandstone serves as a siliceous calibration raw material to be ground to obtain a raw material, the raw material is preheated, decomposed, calcined at high temperature and then cooled to obtain phosphorus slag cement clinker, gypsum, the limestone, the phosphorus slag and the like are ground separately to be mixed with the phosphorus slag cement clinker, and then the phosphorus slag cement is prepared. According to the method, the firing temperature can be lowered in the clinker calcination process, therefore, a liquid phase is generated in advance, the clinker yield is increased, CO2 emission is reduced, and energy conversation and emission reduction are achieved.

Description

technical field [0001] The invention relates to the field of cement production, in particular to a method for producing high-quality and high-volume phosphorus slag cement by using phosphorus slag. Background technique [0002] Phosphorus slag is a kind of industrial waste. Long-term stacking not only wastes a lot of land resources, but also seriously pollutes the surrounding air and soil under the action of wind and rain. With the country's emphasis on environmental protection, more and more companies are beginning to seek efficient utilization of phosphorus slag. Cement plants generally use raw materials such as limestone and shale to calcinate clinker. It not only wastes a lot of natural resources, but also consumes a lot of energy for calcination, and the production cost is relatively high. [0003] Phosphorus slag is an industrial by-product produced during the production of yellow phosphorus, and its main components are CaO and SiO 2 . Contents of the invention ...

Claims

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Application Information

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IPC IPC(8): C04B7/24C04B7/52C04B7/44
CPCC04B7/24C04B7/44C04B7/52Y02P40/10Y02P40/121
Inventor 邹兴芳王银吴振华刘生超程龙杨华杨莉荣
Owner GEZHOUBA SONGZI CEMENT
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