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PE anti-aging functional master batch and preparation method thereof

A functional masterbatch and anti-aging technology, which is applied in the field of PE anti-aging functional masterbatch and its preparation, can solve the problems of easy aging of materials, abnormal products, and influence of resin performance, and achieve high content of anti-ultraviolet light agent and high dosage Less, good dispersion effect

Inactive Publication Date: 2016-11-09
OPTA POLYMER JIANGSU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. After adding anti-ultraviolet light agent to the resin, it is directly processed. This method will easily lead to uneven dispersion of anti-ultraviolet light agent in the product and cause abnormalities in the product. Fewer places where the material is more prone to aging
[0004] 2. After the resin is added with an anti-ultraviolet agent, it is extruded and pelletized by a single-screw extruder or a twin-screw extruder, and then processed into a finished product. This method is effective, but the cost is high. When the extruder is extruded, the resin needs to be processed at high temperature, and the new material becomes a secondary material, so it will affect the performance of the resin
[0005] 3. In the preparation process of the existing anti-aging functional masterbatch, adding a large amount of anti-ultraviolet light agent to the resin will easily cause the screw of the twin-screw extruder to not eat material during processing, and the broken strips cannot be pelletized, resulting in the machine not operating normally. Therefore, it is impossible to prepare an anti-aging functional masterbatch with a high content of anti-ultraviolet light agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Based on the total mass of 100 parts, weigh 25 parts of LLDPE resin with a model number of 6101RQ and a melt flow rate of 20 g / 10 min, 18 parts of UV531, 7 parts of antioxidant 1010, and 50 parts of calcium carbonate. After adding the high and low speed mixer and mixing for 3 minutes, add the mixed raw materials into the twin-screw extruder. The temperature of the feed inlet of the twin-screw extruder is set at 60-100°C, and the temperature of the rest of the sections is set at 100-100°C. 160°C, start extrusion, water-cooled and cut into pellets. The surface of the masterbatch is smooth, and the appearance is off-white opaque columnar shape. It is packaged after natural cooling to room temperature.

[0024] Use an injection molding machine to add 4 parts of this anti-aging masterbatch to 100 parts of PP30S for injection molding, and set the temperature of the injection molding machine to 200 ° C. Injection molded parts are translucent and foggy white, well dispersed, an...

Embodiment 2

[0026] Based on the total mass of 100 parts, weigh 75 parts of LLDPE resin with a model number of 6201RQ and a melt flow rate of 50 g / 10 min, 18 parts of UV531, and 7 parts of antioxidant 168. After adding the high and low speed mixer and mixing for 3 minutes, add the mixed raw materials into the twin-screw extruder. The temperature of the feed inlet of the twin-screw extruder is set at 60-100°C, and the temperature of the rest of the sections is set at 100-100°C. 160°C, start extrusion, after water cooling, cut into pellets, the surface is smooth, the appearance is translucent beige columnar shape, after natural cooling to room temperature, it will be packaged.

[0027] Use an injection molding machine to add 4 parts of this anti-aging masterbatch to 100 parts of PE2420 for injection molding, and set the temperature of the injection molding machine to 180 ° C. The injection molded parts are transparent and well dispersed, and meet the anti-aging requirements through accelerat...

Embodiment 3

[0029] Based on the total mass of 100 parts, weigh 25 parts of PE resin with a model number of HXM50100 and a melt flow rate of 30 g / 10 min, 25 parts of UV944, and 50 parts of talcum powder. After adding the high and low speed mixer and mixing for 5 minutes, add the mixed raw materials into the twin-screw extruder. The temperature of the feed inlet of the twin-screw extruder is set at 60-100°C, and the temperature of the rest of the sections is set at 100-100°C. 160°C, start extrusion, water-cooled and cut into pellets, the surface is smooth, the appearance is off-white opaque columnar, after natural cooling to room temperature, it will be packaged.

[0030] Use an injection molding machine to add 3 parts of this anti-aging masterbatch to 100 parts of PP30S for injection molding, and set the temperature of the injection molding machine to 200 ° C. Injection molded parts are translucent and foggy white, well dispersed, and meet anti-aging requirements through accelerated aging ...

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Abstract

The invention discloses a PE anti-aging functional master batch. Total 100 parts by mass of the PE anti-aging functional master batch is prepared from, by mass, 25-75 parts of PE resin, 15-25 parts of uvioresistant agent, 0-20 parts of antioxygen and 0-50 parts of filling powder. The invention further discloses a preparation method of the master batch. The method comprises the steps that 1, the PE resin, the uvioresistant agent, the antioxygen and the filling powder are weighed according to the ratio of the composition raw materials and mixed to be uniform in a high-low-speed mixer; 2, the mixed raw materials are added into a single screw extruder or a twin-screw extruder to be extruded and then diced; 3, natural cooling evaporation or low-temperature drying is selected according to the water content of the diced functional master batch. The PE anti-aging functional master batch has the advantages that the uvioresistant agent content of the anti-aging functional master batch is high, the use addition is small, the anti-aging effect equivalent to that of an existing product can be achieved simply by adding 2-4 parts of the master batch to every 100 parts of resin, and the performance of the resin is not influenced after adding.

Description

technical field [0001] The invention relates to an anti-aging functional master batch, in particular to a PE type anti-aging functional master batch and a preparation method thereof. Background technique [0002] Plastics are prone to aging due to external sunlight, oxygen, damp heat, etc. Plastic aging will cause plastics to lose their use value and cause huge economic losses. The existing production methods of anti-aging functional materials are as follows: [0003] 1. After adding anti-ultraviolet light agent to the resin, it is directly processed. This method will easily lead to uneven dispersion of anti-ultraviolet light agent in the product and cause abnormalities in the product. Fewer places where the material is more prone to aging. [0004] 2. After the resin is added with an anti-ultraviolet agent, it is extruded and pelletized by a single-screw extruder or a twin-screw extruder, and then processed into a finished product. This method is effective, but the cost i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/06C08L23/12C08K13/02C08K5/134C08K3/26C08K5/526C08K3/34C08K3/30C08J3/22
CPCC08K13/02C08J3/226C08J2323/12C08J2423/08C08K3/26C08K3/30C08K3/34C08K5/1345C08K5/526C08K2003/265C08K2003/3045C08L23/12C08L2201/08C08L23/0815C08L23/06
Inventor 刘家诚
Owner OPTA POLYMER JIANGSU