Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Silver salt doped silver conductive adhesive, as well as preparation method and application thereof

A technology of conductive silver glue and silver salt, applied in the direction of conductive adhesives, adhesives, epoxy resin glue, etc., can solve the problems of low conductivity, weak adhesion, high cost, etc.

Active Publication Date: 2016-11-09
SHENZHEN INST OF ADVANCED TECH
View PDF2 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] Therefore, in view of the relatively low electrical conductivity, poor cohesiveness, and high cost of the current conductive silver glue, it has become a priority to develop a relatively high electrical conductivity, strong cohesive and low-cost conductive silver glue. Technical problems that need to be solved urgently

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Silver salt doped silver conductive adhesive, as well as preparation method and application thereof
  • Silver salt doped silver conductive adhesive, as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0099] This embodiment provides a conductive silver glue doped with silver salt, which is prepared from the following raw materials:

[0100] 0.6 parts by weight of silver salt (silver nitrate);

[0101] 80 parts by weight of micron silver powder (mixing flaky rod-shaped silver powder, 5 microns of average particle diameter);

[0102] Epoxy resin (Shell bisphenol A type epoxy resin 828E) 17 parts by weight;

[0103] 1 part by weight of curing agent (dicyandiamide);

[0104] Accelerator (1-cyanoethyl-2-ethyl-4-methylimidazole) 0.1 parts by weight;

[0105] 0.1 parts by weight of coupling agent (KH-560);

[0106] Diluent (1,4-butanediol diglycidyl ether) 1.15 parts by weight;

[0107] Anti-precipitation agent (fumed silica) 0.05 parts by weight;

[0108] The preparation method of the above-mentioned conductive silver glue doped with silver salt comprises the following steps:

[0109] (1) Silver nitrate is filled in the epoxy resin according to the ratio, stirred and ground...

Embodiment 2

[0113] This embodiment provides a conductive silver glue doped with silver salt, which is prepared from the following raw materials:

[0114] 0.6 parts by weight of silver salt (silver nitrate);

[0115] 70 parts by weight of micron silver powder (mixing flaky rod-shaped silver powder, 5 microns of average particle diameter);

[0116] Epoxy resin (Shell bisphenol A type epoxy resin 828E) 25.0 parts by weight;

[0117] 1.4 parts by weight of curing agent (dicyandiamide);

[0118] Accelerator (1-cyanoethyl-2-ethyl-4-methylimidazole) 0.15 parts by weight;

[0119] 0.15 parts by weight of coupling agent (KH-560);

[0120] Diluent (1,4-butanediol diglycidyl ether) 2.63 parts by weight;

[0121] Anti-precipitation agent (fumed silica) 0.075 parts by weight;

[0122] The preparation method of the above-mentioned conductive silver glue doped with silver salt comprises the following steps:

[0123] (1) Silver nitrate is filled in the epoxy resin according to the ratio, stirred an...

Embodiment 3

[0127] This embodiment provides a conductive silver glue doped with silver salt, which is prepared from the following raw materials:

[0128] 0.6 parts by weight of silver salt (silver nitrate);

[0129] Micron silver powder (mixed flake rod-shaped silver powder, average particle diameter 5 microns) 60 parts by weight;

[0130] Epoxy resin (Shell bisphenol A type epoxy resin 828E) 34 parts by weight;

[0131] 2 parts by weight of curing agent (dicyandiamide);

[0132]Accelerator (1-cyanoethyl-2-ethyl-4-methylimidazole) 0.2 parts by weight;

[0133] 0.2 parts by weight of coupling agent (KH-560);

[0134] Diluent (1,4-butanediol diglycidyl ether) 2.9 parts by weight;

[0135] 0.1 parts by weight of anti-precipitation agent (fumed silica);

[0136] The preparation method of the above-mentioned conductive silver glue doped with silver salt comprises the following steps:

[0137] (1) Silver nitrate is filled in the epoxy resin according to the ratio, stirred and ground, so t...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Shear strengthaaaaaaaaaa
Login to View More

Abstract

The invention provides a silver salt doped silver conductive adhesive, as well as a preparation method and application thereof. The silver salt doped silver conductive adhesive is prepared from the following raw materials in parts by weight: 0.01 to 5 parts of silver salt, 50 to 85 parts of micron silver powder, 10 to 50 parts of epoxy resin, 0.5 to 60 parts of a curing agent, 0.05 to 5 parts of an accelerator, 0.05 to 5 parts of a coupling agent, 1 to 10 parts of a diluent and 0.05 to 2 parts of an anti-precipitant. According to the preparation method, the silver salt is introduced into the formula of the silver conductive adhesive in a doping manner, so that the using amount of the silver powder can be reduced by 15 to 20 percent on the premise of ensuring the conductivity of the silver conductive adhesive; under the same addition of the silver powder, the electrical conductivity of the silver conductive adhesive is greatly improved, and moreover, the silver conductive adhesive has strong shear strength and high aging resistance; the prepared silver salt doped silver conductive adhesive can be widely applied to the fields of solar cell, IC (integrated circuit) and LED (light-emitting diode) packaging and the like.

Description

technical field [0001] The invention relates to a conductive silver glue doped with silver salt, a preparation method and application thereof, and belongs to the technical field of semiconductor materials and preparation thereof. Background technique [0002] As a substitute for traditional packaging materials in the field of electronic packaging—solder, conductive adhesive has many advantages, such as: environmental friendliness, no toxic metals, no need for pre-cleaning and post-soldering cleaning in the process; mild curing temperature, greatly reducing the impact on electronic devices Thermal damage and internal stress, especially suitable for heat-sensitive materials and non-solderable materials; high line resolution, and its line resolution below 200μm is more suitable for fine-pitch manufacturing. The many advantages of conductive adhesives adapt to the development trend of miniaturization, lightness and integration of electronic devices today, so it is widely used in...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C09J9/02C09J163/00
CPCC09J9/02C08K3/08C08K3/16C08K3/28C08K5/098C08K7/00C08K7/18C08K13/02C08K2003/0806C08K2201/014C09J163/00
Inventor 孙蓉韩延康张保坦朱朋莉李刚
Owner SHENZHEN INST OF ADVANCED TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products