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Low-VOC low-density glass fiber reinforced polypropylene composite material and application thereof

A composite material and polypropylene technology, which is applied in the field of low VOC and low density glass fiber reinforced polypropylene composite materials, can solve the problems of VOC, adsorption and degradation ability discount, limited effect, etc., to achieve lasting and effective secondary pollution, no The effect of secondary pollution and density reduction

Inactive Publication Date: 2016-11-16
SUZHOU RONGCHANG COMPOUND MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, reducing VOC by controlling the source of raw materials only solves one factor of VOC generation, and cannot solve the newly generated VOC substances in the process
The adsorption method, whether it is physical adsorption or chemical adsorption, has the problem of selectivity and balance of adsorption.
Chinese patent CN105001525A by adding at least one of activated carbon, molecular sieve, zeolite powder and nano inorganic powder (TiO 2 or ZnO) to reduce odor and VOC, the former is mainly used for adsorption, and the latter is mainly used for adsorption and degradation of VOC, but the 20-80nm nano-inorganic powder is easy to agglomerate, and its ability to absorb and degrade is greatly reduced. And without any modification, it needs to be excited by ultraviolet light to play a role, so the effect is very limited
However, the low-molecular organic repellant used in this method has compatibility problems with the polypropylene resin and the carbonates and their decomposition products, and water and fatty alcohols with a boiling point lower than 200°C, due to their low boiling point and And the premix is ​​added to the extruder in the main feed, then there are problems with the durability and uniformity of the melt of the modified polypropylene material
The above invention only improves a certain factor that generates VOC, and cannot solve the problem of VOC generated in both raw materials and production processes at the same time

Method used

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  • Low-VOC low-density glass fiber reinforced polypropylene composite material and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0023] This embodiment provides a low-VOC low-density glass fiber reinforced polypropylene composite material, which comprises the following components in parts by weight:

[0024] 65 parts of polypropylene, 4.5 parts of hollow glass microspheres, wherein the particle diameter of the hollow glass microspheres is 1-3mm, and the surface of the hollow glass microspheres is repeatedly dipped and coated with PP-g-MAH (grafting ratio of 2.5-3.0wt %, melt index is 120-200g / 10min) 2 parts, 5-25mm long glass fiber 21.5 parts, talcum powder 3.5 parts, antioxidant 1010 0.2 part, anti-ultraviolet additive CYASORB UV-V680 0.3 part, VOC inhibitor 3 Parts, wherein the VOC inhibitor includes titanium dioxide quantum dots, attapulgite, sepiolite, diatomite and tourmaline with 10-20nm surface doped with silver nanoclusters, wherein nano photocatalyst, attapulgite, sepiolite, silicon The mass ratio of algae earth and tourmaline is 12:45:30:12:1.

[0025] After the above raw materials are ball m...

Embodiment 2

[0027] A low-VOC low-density glass fiber reinforced polypropylene composite material, the composite material includes the following components in parts by weight:

[0028] 35 parts of polypropylene, 6 parts of hollow glass microspheres, wherein the particle diameter of the hollow glass microspheres is 1-3mm, and the surface of the hollow glass microspheres is repeatedly dipped and coated with PP-g-MAH (grafting ratio of 2.5-3.0wt %, melt index is 120-200g / 10min) 4 parts, 5-25mm long glass fiber 45 parts, talcum powder 5 parts, antioxidant 0.5 part, this antioxidant is made of antioxidant 1010 and antioxidant 168 according to mass ratio 2 : 1 compound, 0.3 parts of anti-ultraviolet additive CYASORB UV-3808PP5, 3 parts of VOC inhibitor, wherein the VOC inhibitor includes 10-20nm surface doped titanium dioxide quantum dots of silver nanoclusters, attapulgite, sea foam Stone and diatomite, tourmaline and 4A molecular sieve, wherein the mass ratio of nano photocatalyst, attapulgite...

Embodiment 3

[0031] A low-VOC low-density glass fiber reinforced polypropylene composite material, the composite material includes the following components in parts by weight:

[0032]75 parts of polypropylene, 4.5 parts of hollow glass microspheres, wherein the particle diameter of the hollow glass microspheres is 1-3mm, and the surface of the hollow glass microspheres is repeatedly dipped and coated with PP-g-MAH (grafting ratio of 2.5-3.0wt %, melt index is 120-200g / 10min) 2 parts, 5-25mm long glass fiber 15 parts, antioxidant 168 0.2 part, anti-ultraviolet additive CYASORB UV-V6800.5 part, VOC inhibitor 4 parts, wherein the VOC inhibitors include titanium dioxide quantum dots, attapulgite, sepiolite, and diatomite doped with silver nanoclusters on the surface of 10-20nm, wherein the mass ratio of nano photocatalyst, attapulgite, sepiolite, and diatomite is 15 :30:40:15.

[0033] Above-mentioned raw material is produced according to the processing method of embodiment 1, obtains produc...

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Abstract

The invention discloses a low-VOC low-density glass fiber reinforced polypropylene composite material and the application thereof. The material is prepared from, by weight, 35-75 parts of polypropylene, 4.5-6 parts of hollow glass beads, 15-45 parts of glass fiber, 0-5 parts of talcum powder, 0.2-0.5 part of antioxidant, 0.3-0.5 part of uvioresistant assistant, 2-4 parts of compatilizer and 3-4 parts of VOC inhibitor. The VOC inhibitor comprises nano-photocatalyst, attapulgite, sepiolite and kieselguhr. VOC in vehicles can be catalyzed and degraded efficiently in an energy-efficient and environment-friendly mode by means of the composition material without using an external ultraviolet light source or device; meanwhile, by adding the hollow glass beads coated with the compatilizer, compatibility with glass fiber reinforced polypropylene is high on the premise that the strength of the composite material is not reduced, and density can be reduced effectively. The low-VOC low-density glass fiber reinforced polypropylene composite material can be applied to cars and household appliances.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a low-VOC and low-density glass fiber reinforced polypropylene composite material and its application. Background technique [0002] With the rapid development of social economy, cars have become indispensable in people's lives. Since modern people stay in the car for a long time every day, the air quality inside the car is closely related to human health. There are two main factors that affect the air quality in the car: one is the release of harmful gases from the interior of the car itself; the other is the release of harmful gases from the car decorations selected by the car owner. In the final analysis, these two aspects are the volatilization of harmful gases in automobile interior decoration parts. The harmful gases are mainly volatile organic compounds (volatile organic compounds), that is, VOC. WHO defines VOC as volatile compounds with a boiling point betwe...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08K13/06C08K9/04C08K7/28C08K7/14C08K3/34C08K5/134C08K3/22C08K3/38
CPCC08K13/06C08K3/22C08K3/34C08K3/346C08K3/38C08K5/1345C08K7/14C08K7/28C08K9/08C08K2003/2237C08K2003/387C08K2201/011C08K2201/014C08L2205/08C08L23/12
Inventor 黄仁军资玉明朱正华
Owner SUZHOU RONGCHANG COMPOUND MATERIAL