Combined foaming agent, hard polyurethane foam and manufacturing method of hard polyurethane foam

A technology of rigid foam and foaming agent, applied in the manufacture of rigid polyurethane foam and the field of rigid polyurethane foam, can solve the problems of high thermal conductivity of foam, increase in energy consumption of the whole machine, and reduce thermal conductivity, so as to reduce thermal conductivity. , The effect of reducing the amount of injection and reducing pollution

Inactive Publication Date: 2016-12-07
QINGDAO HAIER SPECIAL ICEBOX
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although the manufacturing of some of the above-mentioned refrigerators uses a multi-component physical foaming agent process, which can reduce the thermal conductivity and reduce the amount of injection materials, the overall thermal conductivity of the foam is still high, the energy consumption of the whole machine increases, and the product competitiveness is low.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The mass part formula of polyurethane rigid foam:

[0030] White material: 100 parts of combined polyether, 9 parts of cyclopentane, 5 parts of isopentane, 2 parts of HFC-245fa;

[0031] Black material: 139 parts of isocyanate (PMDI).

[0032] The manufacturing steps of polyurethane rigid foam are as follows:

[0033] The S1 combined polyether is delivered to the static mixer through the delivery pump;

[0034] S2 Send cyclopentane and isopentane to the static mixer with a circulation pump, and send HFC-245fa to the static mixer with a circulation pump. The above mixture is uniformly mixed in the static mixer, and the temperature is controlled at 22°C and the pressure is 2bar. ;

[0035] S3 Mix the mixture and isocyanate in the static mixer evenly, and then use a high-pressure foaming machine to inject into the refrigerator for foaming reaction at a temperature of 20° C. and a pressure of 130 bar to obtain rigid polyurethane foam.

[0036] In the actual operation st...

Embodiment 2

[0039] The mass part formula of polyurethane rigid foam:

[0040] White material: 100 parts of combined polyether, 8.5 parts of cyclopentane, 4.5 parts of isopentane, 3.5 parts of HFC-245fa;

[0041] Black material: 145 parts of isocyanate (PMDI).

[0042] The manufacture step of present embodiment is the same as embodiment 1, and the average core density of the polyurethane rigid foam that makes is 30.0kg / m 3 , The average compressive strength is 184kpa, the minimum compressive strength is 161kpa, the average shrinkage rate is 1.1%, the maximum shrinkage rate is 3.5%, and the thermal conductivity is 19.0mW / m·k.

Embodiment 3

[0044] The mass part formula of polyurethane rigid foam:

[0045] White material: 100 parts of combined polyether, 8.5 parts of cyclopentane, 4.5 parts of isopentane, 5.5 parts of HFC-245fa;

[0046] Black material: 148 parts of isocyanate (PMDI).

[0047] The manufacture step of present embodiment is the same as embodiment 1, and the average core density of the polyurethane rigid foam that makes is 29.7kg / m 3 , The average compressive strength is 173kpa, the minimum compressive strength is 158kpa, the average shrinkage rate is 1.3%, the maximum shrinkage rate is 3.9%, and the thermal conductivity is 18.8mW / m·k.

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Abstract

The invention provides a combined foaming agent. The combined foaming agent comprises, by mass, 1-9 parts of cyclopentane, 1-5 parts of isopentane and 2-30 parts of HFC-245fa. The hard polyurethane foam prepared by adopting the combined foaming agent comprises, by mass, 100 parts of combined polyether, 10-26 parts of the combined foaming agent and 120-150 parts of isocyanate. The invention also provides a manufacturing method of the hard polyurethane foam. The above foaming technology effectively reduces the heat conduction coefficient of the polyurethane foam, and reduces the energy consumption of a freezer; the strength of the foam with same density is enhanced, and the density of the foam required by the freezer is reduced, so the injection amount of the whole freezer is reduced, the raw material waste is reduced when the demand of the freezer is a certain amount, production of the hard polyurethane foam difficult to treat is reduced, and pollution to environment is reduced; and the solidification time of the foam is shortened by 10-15%, and the production efficiency is improved.

Description

Technical field [0001] The present invention is the field of foam insulation material technology. Specifically, it involves a combination of foaming agent, a polyurethane hard foam made of this combination foaming agent, and the manufacturing method of the polyurethane hard foam. Background technique [0002] Traditional electric balcony uses a single component alkane physical foaming agent. After foaming, the polyurethane hard foam is formed after the reaction of isocyanate and polyether polyol.The amount is large, the production festival is slow, resulting in a higher manufacturing cost. [0003] At present, the manufacturing of some electric freezers adopts multiple groups of physical foaming agents, such as other alkanes for mixing proportions, thereby achieving the purpose of reducing foam thermal conductivity and product irrigation. [0004] Although the manufacturing of some of the above -mentioned electric freezers adopts multiple component physical foaming processes, whi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/14C08L75/08C08G18/48C08G101/00
Inventor 韩照华杨洪光吴悠赵风阳孙科
Owner QINGDAO HAIER SPECIAL ICEBOX
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