A kind of preparation method of enteromorpha carbon nanomaterial regenerated cellulose blend fiber

Abstract

The invention discloses a preparation method of an enteromorpha carbon nano material and regenerated cellulose blended fiber. The preparation method is characterized by comprising the following preparation steps of (1), preparing a high-performance enteromorpha carbon nano material by using enteromorpha as a raw material; (2), blending the enteromorpha carbon nano material with a regenerated cellulose spinning solution; (3), spinning the blended spinning solution through a wet-method spinning device, and shaping a fiber through a coagulating bath, so as to prepare the enteromorpha carbon nano material and regenerated cellulose blended fiber. According to the preparation method of the enteromorpha carbon nano material and regenerated cellulose blended fiber, the raw materials are rich in source and low in cost, the method is simple in preparation process, is free from pollution and can be used for quantitative production; the prepared enteromorpha carbon nano material and regenerated cellulose blended fiber is good in antibacterial, adsorptive and deodorant effects, and is higher in added value compared with ordinary regenerated cellulose.

Description

technical field

[0001] The invention belongs to the technical field of preparation of blended regenerated cellulose, and in particular relates to a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber. Background technique

[0002] Regenerated fibers are chemical fibers made from natural polymers by chemical methods, and have basically the same chemical composition as the original polymers. Due to the characteristics of softness, comfort, breathability and environmental protection of regenerated cellulose fiber, the clothes woven by it are favored by consumers all over the world. Due to the reduction of cultivated land and the depletion of oil resources, the output of natural fibers and synthetic fibers will be more and more restricted; while people pay attention to the environmental protection performance in the process of textile consumption, the value of regenerated cellulose fibers has been reconsidered. Know and discover.

[0003] ...

Examples

Embodiment 1

[0027] The invention provides a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber, comprising the following preparation steps:

[0028] (1) Use Enteromorpha as raw material to prepare high-performance Enteromorpha carbon nanomaterials: collect Enteromorpha, pick and remove impurities, wash, freeze-dry, crush and sieve to obtain 100 mesh Enteromorpha powder; take the Enteromorpha powder in Calcined to black in a nitrogen atmosphere at 200°C for 60 minutes to obtain a pre-carbonized product; add potassium permanganate to the pre-carbonized product according to a weight ratio of 1:1, at a temperature of 50°C and a stirring speed of Stirring under the condition of 50r / min for 4h to obtain a precursor; drying the precursor at 50°C for 6h to obtain an intermediate product; subjecting the intermediate product to heat treatment to obtain product I, the conditions of the heat treatment are, at 10 Heat up to 600°C at a heating rate of °C / min, and...

Embodiment 2

[0032] Different from Example 1, a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber comprises the following preparation steps:

[0033] (1) Use Enteromorpha as raw material to prepare high-performance Enteromorpha carbon nanomaterials: collect Enteromorpha, pick and remove impurities, wash, freeze-dry, crush and sieve to obtain 50 mesh Enteromorpha powder; take the Enteromorpha powder in Calcined to black under argon atmosphere at 800°C for 60 minutes to obtain a pre-carbonized product; add phosphorus pentoxide to the pre-carbonized product according to the weight ratio of 1:5, at a temperature of 50°C and a stirring speed of Stirring at 300r / min for 10h to obtain a precursor; drying the precursor at 100°C for 12h to obtain an intermediate product; subjecting the intermediate product to heat treatment to obtain product I, the heat treatment conditions being, Raise the temperature to 1400°C at a heating rate of 20°C / min, and then heat f...

Embodiment 3

[0037] Different from Example 1, a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber comprises the following preparation steps:

[0038] (1) Use Enteromorpha as raw material to prepare high-performance Enteromorpha carbon nanomaterials: collect Enteromorpha, pick and remove impurities, wash, freeze-dry, crush and sieve to obtain 70 mesh Enteromorpha powder; take the Enteromorpha powder in Calcined to black under argon atmosphere at 650°C for 30 minutes to obtain a pre-carbonized product; add phosphorus pentoxide to the pre-carbonized product according to the weight ratio of 1:3, at a temperature of 30°C and a stirring speed of Stirring at 250r / min for 8h to obtain a precursor; drying the precursor at 85°C for 10h to obtain an intermediate product; subjecting the intermediate product to heat treatment to obtain product I, the conditions of the heat treatment are as follows: The temperature was raised to 1000°C at a heating rate of 15°C / m...

technical field

[0001] The invention belongs to the technical field of preparation of blended regenerated cellulose, and in particular relates to a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber. Background technique

[0002] Regenerated fibers are chemical fibers made from natural polymers by chemical methods, and have basically the same chemical composition as the original polymers. Due to the characteristics of softness, comfort, breathability and environmental protection of regenerated cellulose fiber, the clothes woven by it are favored by consumers all over the world. Due to the reduction of cultivated land and the depletion of oil resources, the output of natural fibers and synthetic fibers will be more and more restricted; while people pay attention to the environmental protection performance in the process of textile consumption, the value of regenerated cellulose fibers has been reconsidered. Know and discover.

[0003] ...

Examples

Embodiment 1

[0027] The invention provides a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber, comprising the following preparation steps:

[0028] (1) Use Enteromorpha as raw material to prepare high-performance Enteromorpha carbon nanomaterials: collect Enteromorpha, pick and remove impurities, wash, freeze-dry, crush and sieve to obtain 100 mesh Enteromorpha powder; take the Enteromorpha powder in Calcined to black in a nitrogen atmosphere at 200°C for 60 minutes to obtain a pre-carbonized product; add potassium permanganate to the pre-carbonized product according to a weight ratio of 1:1, at a temperature of 50°C and a stirring speed of Stirring under the condition of 50r / min for 4h to obtain a precursor; drying the precursor at 50°C for 6h to obtain an intermediate product; subjecting the intermediate product to heat treatment to obtain product I, the conditions of the heat treatment are, at 10 Heat up to 600°C at a heating rate of °C / min, and...

Embodiment 2

[0032] Different from Example 1, a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber comprises the following preparation steps:

[0033] (1) Use Enteromorpha as raw material to prepare high-performance Enteromorpha carbon nanomaterials: collect Enteromorpha, pick and remove impurities, wash, freeze-dry, crush and sieve to obtain 50 mesh Enteromorpha powder; take the Enteromorpha powder in Calcined to black under argon atmosphere at 800°C for 60 minutes to obtain a pre-carbonized product; add phosphorus pentoxide to the pre-carbonized product according to the weight ratio of 1:5, at a temperature of 50°C and a stirring speed of Stirring at 300r / min for 10h to obtain a precursor; drying the precursor at 100°C for 12h to obtain an intermediate product; subjecting the intermediate product to heat treatment to obtain product I, the heat treatment conditions being, Raise the temperature to 1400°C at a heating rate of 20°C / min, and then heat f...

Embodiment 3

[0037] Different from Example 1, a preparation method of Enteromorpha carbon nanomaterial regenerated cellulose blended fiber comprises the following preparation steps:

[0038] (1) Use Enteromorpha as raw material to prepare high-performance Enteromorpha carbon nanomaterials: collect Enteromorpha, pick and remove impurities, wash, freeze-dry, crush and sieve to obtain 70 mesh Enteromorpha powder; take the Enteromorpha powder in Calcined to black under argon atmosphere at 650°C for 30 minutes to obtain a pre-carbonized product; add phosphorus pentoxide to the pre-carbonized product according to the weight ratio of 1:3, at a temperature of 30°C and a stirring speed of Stirring at 250r / min for 8h to obtain a precursor; drying the precursor at 85°C for 10h to obtain an intermediate product; subjecting the intermediate product to heat treatment to obtain product I, the conditions of the heat treatment are as follows: The temperature was raised to 1000°C at a heating rate of 15°C / m...