Carbon fiber modified non-solvent polyurethane surface layer resin for sports shoe leather, as well as preparation method and application of carbon fiber modified non-solvent polyurethane surface layer resin
A technology of solvent-free polyurethane and surface layer resin, which is applied in the field of synthetic leather, can solve the problems of DMF residue and organic solvent N,N-dimethylformamide, etc., so as to ensure environmental protection, solve difficult peeling, and improve compatibility effect
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[0037] Example 1:
[0038] A carbon fiber modified solvent-free surface layer polyurethane resin for sports shoe leather. The resin is composed of hydroxyl component A and isocyanate component B:
[0039] The composition of the component A is as follows in proportion to parts by mass:
[0040]
[0041] The composition of the B component is as follows in proportion to mass parts:
[0042]
[0043] Wherein, the A component and the B component are mixed at a mass ratio of 1:1.4.
[0044] IPDI in component A is isophorone diisocyanate produced by German Bayer, T5652 is a polycarbonate diol with a number average molecular weight of 2000 produced by Japan’s Asahi Kasei Chemical Co., Ltd., and SP-2013 is Hefei Amway Polyurethane New Material Polyester diol with a number average molecular weight of 2000 produced by Co., Ltd., EG and glycerin are all commercially available products. OFOH702E is a hydroxy silicone oil with a hydroxyl value of 50mgKOH / g produced by Momentive Advanced Materials Gr...
Example Embodiment
[0051] Example 2
[0052] A carbon fiber modified solvent-free surface layer polyurethane resin for sports shoe leather. The resin is composed of hydroxyl component A and isocyanate component B:
[0053] According to the proportion of parts by mass, the component A is composed as follows:
[0054]
[0055] The composition of the B component is as follows in proportion to mass parts:
[0056]
[0057] Wherein, the A component and the B component are mixed at a mass ratio of 1:1.
[0058] H in component A 12 MDI is hydrogenated MDI produced by Yantai Wanhua Company, T5652 is a polycarbonate diol with a number average molecular weight of 2000 produced by Japan’s Asahi Kasei Chemical Co., Ltd., and SP-2313 is a number average molecular weight of 2000 produced by Hefei Anli Polyurethane New Material Co., Ltd. OFX-0930 is a hydroxy silicone oil with a hydroxyl value of 130mgKOH / g produced by Dow Corning, 1,4-BG and trimethylolpropane TMP are commercially available products, and BiCAT 8108 is...
Example Embodiment
[0065] Example 3:
[0066] A carbon fiber modified solvent-free surface layer polyurethane resin for sports shoe leather. The resin is composed of hydroxyl component A and isocyanate component B:
[0067] The composition of the component A is as follows in proportion to parts by mass:
[0068]
[0069] The composition of the B component is as follows in proportion to mass parts:
[0070]
[0071] Wherein, the A component and the B component are mixed at a mass ratio of 2:1.
[0072] IPDI in component A is isophorone diisocyanate produced by German Bayer, T5652 is a polycarbonate diol with a number average molecular weight of 2000 produced by Japan’s Asahi Kasei Chemical Co., Ltd., and SP-2013 is Hefei Amway Polyurethane New Material Polyester diol with a number average molecular weight of 2000 produced by Co., Ltd., EG and glycerin are all commercially available products. OFOH702E is a hydroxy silicone oil with a hydroxyl value of 50mgKOH / g produced by Momentive Advanced Materials Grou...
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