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Perovskite solar cell integrated device and preparation method thereof

A technology for solar cells and integrated devices, applied in the field of perovskite solar cell integrated devices and their preparation, can solve problems such as being unsuitable for large-scale practical applications, simple integration methods, complex processes, etc. Scope, easy to prepare effects

Inactive Publication Date: 2017-02-22
HUAZHONG UNIV OF SCI & TECH
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  • Abstract
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  • Claims
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Problems solved by technology

[0007] At present, there are relatively many related studies on the integration of solar cells and supercapacitors, but the research on the integration of perovskite solar cells with supercapacitors and thermoelectric devices is still blank, and the existing integration methods are simple, the process is complicated, and most of them need to go through high temperature. It is not suitable for large-scale practical applications, especially in the field of flexible electronics manufacturing that is currently widely concerned.
[0008] In view of the above technical problems, there is no perovskite solar cell micro-integrated device with excellent light absorption performance, rapid and stable charge and discharge, and simple structure. Spectral absorption, as well as the effective storage and stable output of energy in micro-integrated devices, the manufacture of highly integrated high-efficiency perovskite solar cell integrated devices, and further application to flexible electronic products are the problems to be solved by the present invention

Method used

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  • Perovskite solar cell integrated device and preparation method thereof

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preparation example Construction

[0045] The present invention also provides a method for preparing the perovskite solar cell integrated device as described above, which is characterized in that it comprises the following steps:

[0046] (a) pretreating the conductive substrate 1 of the perovskite solar cell;

[0047] (b) preparing a photoanode 2 on the conductive substrate 1 of the perovskite solar cell;

[0048] (c) preparing a perovskite photosensitive layer 3 on the photoanode 2;

[0049] (d) preparing a carbon counter electrode 4 on the perovskite photosensitive layer 3 to obtain a perovskite solar cell;

[0050] (e) The carbon counter electrode 4 is physically connected to the thermoelectric generation sheet through thermal conductive silicone grease, and at the same time, the perovskite solar cell and the thermoelectric generation sheet are electrically connected in series to obtain a Integrated devices for power generation chips;

[0051] (f) Prepare a first carbon electrode 8 on the cold surface la...

Embodiment 1

[0058] see figure 1 A method for preparing a perovskite solar cell integrated device with a thermoelectric power generation sheet and a supercapacitor comprises the following steps:

[0059] In the first step, the conductive substrate is pretreated. Specifically, first, a conductive substrate 1 is provided, and the conductive substrate 1 is ultrasonically cleaned with acetone and ethanol for 15 minutes respectively; afterward, the conductive substrate 1 is dried and then treated with an ultraviolet ozone cleaning machine for 30 minutes to carry out surface modification . The electrical resistivity of the conductive substrate 1 can reach 7Ω·cm, the light transmittance is greater than 90%, and the temperature resistance can reach 500°C. In this embodiment, the conductive substrate 1 includes conductive glass and an FTO / ITO conductive film layer formed on the conductive glass.

[0060] The second step is to prepare the photoanode. Specifically, the spin coating method was use...

Embodiment 2

[0066] A method for preparing a perovskite solar cell integrated device with a thermoelectric power generation sheet and a supercapacitor comprises the following steps:

[0067]In the first step, the conductive substrate is pretreated. Specifically, first, a conductive substrate 1 is provided, and the conductive substrate 1 is ultrasonically cleaned with acetone and ethanol for 15 minutes respectively; afterward, the conductive substrate 1 is dried and then treated with an ultraviolet ozone cleaning machine for 30 minutes to carry out surface modification . The electrical resistivity of the conductive substrate 1 can reach 7Ω·cm, the light transmittance is greater than 90%, and the temperature resistance can reach 500°C. In this embodiment, the conductive substrate 1 includes conductive glass and an FTO / ITO conductive film layer formed on the conductive glass.

[0068] The second step is to prepare the photoanode. Specifically, the spin coating method was used to prepare Ti...

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Abstract

The invention belongs to the technical field of miniature energy conversion and storage devices and particularly discloses a perovskite solar cell integrated device and a preparation method thereof. The integrated device comprises a perovskite solar cell, a thermoelectric power generation piece and a supercapacitor which are sequentially arranged from top to bottom. The perovskite solar cell comprises a conductive substrate, a solar electrode, a perovskite photosensitive layer and a carbon counter electrode which are sequentially arranged from top to bottom. The thermoelectric power generation piece is arranged between the perovskite solar cell and the supercapacitor, and the thermoelectric power generation piece and the perovskite solar cell are electrically connected in a serial connection mode. The supercapacitor is arranged on the cold surface layer of the thermoelectric power generation piece. The invention further discloses a preparation method of the perovskite solar cell integrated device. The integrated device is simple in structure, high in photoelectric conversion efficiency, large in electric energy storage capacity and very stable in storage and output and further has the advantages of being convenient to manufacture, low in cost and suitable for large-area industrial production.

Description

technical field [0001] The invention belongs to the technical field of miniature energy conversion and storage devices, and specifically relates to a perovskite solar cell integrated device and a preparation method thereof, which can improve photoelectric conversion efficiency, increase the storage capacity of electric energy, and improve the stability of electric energy storage and output. Background technique [0002] With the development of the current world industry and the continuous growth of population, the demand for global energy is also increasing rapidly, especially for non-renewable resources such as oil, coal, and natural gas. Due to the over-exploitation and utilization of fossil energy by human beings, such energy reserves are on the verge of exhaustion. At the same time, with the continuous consumption of fossil energy, a large amount of pollutants are discharged into nature, and the environmental problems brought about are becoming more and more severe. The...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L25/16H01L35/32H01L51/48H01L51/44H01G11/08H01G11/32H01G11/86B82Y40/00H10N10/17
CPCH01L25/167H01G11/08H01G11/32H01G11/86B82Y40/00H10N19/101H10K71/60H10K30/81Y02E10/549Y02E60/13Y02P70/50
Inventor 廖广兰韩京辉刘智勇史铁林刘星月孙博吴悠妮
Owner HUAZHONG UNIV OF SCI & TECH
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