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Silicone rubber foaming material and preparation method thereof

A technology of foaming materials and silicone rubber, applied in the field of materials, can solve problems such as the preparation of large-scale and precise-sized foamed silicone rubber materials that do not support three-dimensional structures, and the matching design research of heat treatment and shaping processes that have not been found, so as to achieve designability Strong, stable high and low temperature stiffness, and uniform cells

Inactive Publication Date: 2017-04-19
SHANDONG NON METALLIC MATERIAL RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the existing research reports on foamed silicone rubber materials, there is no research on the matching design of two vulcanizing agent compound formulas and two-stage molding vulcanization foaming, heat treatment and shaping processes, and the existing technology does not support large and precise dimensions of three-dimensional structures Preparation of foamed silicone rubber material products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Take 500g of 110-2 vinyl silicone rubber and 100g of precipitated silica, knead in a kneader for 30 minutes, then heat-treat in an oven at 190°C for 2 hours, take it out and cool it to room temperature; Add 1.0 g of benzoyl peroxide, 5.0 g of dicumyl peroxide, 25 g of azodicarbonamide and 12.5 g of urea. After the addition is complete, pass through 10 times and park for 24 hours. Use a flat vulcanizer to mold, vulcanize and foam. The first-stage vulcanization and foaming conditions are: mold size ф80×30mm, feed material 160g, vulcanization temperature 124°C, and vulcanization time 30 minutes; the second-stage vulcanization and foaming conditions are: mold size ф120×50mm, The vulcanization temperature is 140°C, and the vulcanization time is 35 minutes; heat treatment in an oven at 90°C for 6 hours to shape the foam material.

[0049] The density of the foam material is 0.26g / cm 3 , when the compressive strain is 15%, 38%, 50%, the load is 150N, 485N, 875N, and the compr...

Embodiment 2

[0051] Take 500g of 110-2 vinyl silicone rubber and 300g of fumed silica, knead in a kneader for 45 minutes, then heat-treat in an oven at 198°C for 2 hours, take it out and cool it to room temperature; And add 2.5g of 2,4-dichlorobenzoyl peroxide, 1.5g of 2,5-dimethyl-2,5-di-tert-butylperoxyhexane, 21g of azodicarbonamide and 13g of urea, and add After the completion, thin pass 10 times, add 30g of 201 methyl silicone oil, after the addition, thin pass 10 times to remove the film, and park for 24 hours. Use a flat vulcanizer to mold, vulcanize, foam and form. The mold and the amount of material added are the same as in Example 1. The conditions for the first-stage vulcanization and foaming are temperature 127°C, time 15 minutes, and the conditions for second-stage vulcanization and foaming are temperature 160°C, time 60 minutes, and oven 95°C. ℃ heat treatment for 5.5 hours to set the shape to obtain a foam material.

[0052] The density of embodiment 2 foaming material is 0...

Embodiment 3

[0054] Take 500g of 110-1 vinyl silicone rubber and 225g of precipitated silica, knead in a kneader for 30 minutes, then heat-treat in an oven at 200°C for 2.5 hours, take it out and cool it to room temperature; And add 1.7g of benzoyl peroxide, 2g of di-tert-butyl peroxide, 10g of azodicarbonamide and 17g of urea. Repeat the next film and park for 24 hours. Use a flat vulcanizer to mold, vulcanize, foam and form. The mold and the amount of material added are the same as in Example 1. The conditions for the first-stage vulcanization and foaming are temperature 123°C, time 25 minutes, and the conditions for second-stage vulcanization and foaming are temperature 148°C, time 40 minutes, and oven 100 ℃ heat treatment for 5 hours to set the shape to obtain a foam material.

[0055] The density of the foam material is 0.25g / cm 3 , when the compressive strain is 15%, 38%, 50%, the load is 95N, 355N, 634N, and the compression set rate of 40%×48 hours at room temperature is 13%.

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Abstract

The invention belongs to the technical field of materials, and relates to a silicone rubber foaming material. Two vulcanizing agent compounding technologies with different vulcanizing temperatures are adopted, vulcanizing foaming technological conditions suitable for a vulcanizing agent compounding system are adopted, a preparation method of two-stage high-temperature mold pressing vulcanizing foaming and thermal treatment shaping is adopted, and the silicone rubber foaming material is obtained. The silicone rubber foaming material is prepared through a two-stage mold pressing vulcanizing foaming process and is at least prepared from, by mass, 100 parts of silicone rubber, 20-60 parts of foaming agent, 20-60 parts of fortifier, 0.2-0.5 part of vulcanizing agent, 0.3-1.0 part of vulcanizing agent B, 2-7 parts of foaming agent, 2-4 parts of foaming promoter and 0-10 parts of modifier. The silicone rubber foaming material is high in designability, even in bubble, smooth in surface, precise in dimension, small in density, stable in high and low temperature rigidity and small in compression permanent deformation. The silicone rubber foaming material is suitable for buffering and damping materials, especially suitable for preparing large-sized products. The silicone rubber foaming material is simple in preparation process, easy to operate, good in stability and suitable for volume production.

Description

technical field [0001] The invention belongs to the technical field of materials, and relates to foam rubber material design and processing technology, in particular to silicone rubber foam material design and processing technology. Background technique [0002] Foamed silicone rubber material is a porous polymer elastic material prepared after vulcanization and foaming of silicone rubber. It has the characteristics of high and low temperature resistance, chemical stability, and aging resistance of silicone rubber and the low density of foam. Vibration, heat insulation, sealing and other high-performance materials are used in aerospace, defense industry, electronics industry and other fields. [0003] The key issue in the study of silicone rubber foam materials is the matching design of the vulcanization process and the foaming process. Whether the vulcanization process and the foaming process match determines the success of the foam material preparation. , strength, stiffn...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/04C08K13/06C08K9/06C08K3/36C08K5/14C08J9/10B29C35/02
CPCC08L83/04B29C35/02C08J9/103C08J9/107C08J2203/04C08J2383/07C08K3/36C08K5/14C08K9/06C08K13/06C08K2201/014C08L2203/14C08L2205/025
Inventor 李辉孙国华李斌肖勇孙志勇马卫东杜华太张春杰张鲲张颖异温家亮
Owner SHANDONG NON METALLIC MATERIAL RES INST