Polyester film and transparent electrode film using the same
A technology of polyester film and polyurethane, applied in the field of polyester film, can solve the problems of reducing the visibility of the screen, difficult to eliminate light interference, and visual fatigue
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preparation example 1
[0125] Preparation of the first water dispersion composition for the primer layer
[0126] An adhesive (P3208, Rohm & Haas Company) prepared from 40% by weight methyl methacrylate, 40% by weight ethyl acrylate and 20% by weight melamine was used. 4% by weight of the adhesive, 0.3% by weight of a silicone-based wetting agent (polyester siloxane copolymer, Q2-5212, Dow Corning Corporation), 0.3% by weight of glue with an average particle diameter of 140nm After adding 0.3% by weight of the solid silica particles to water, the mixture was stirred for 2 hours to prepare a first water-dispersed composition. The primer layer prepared by using the first water dispersion composition had a glass transition temperature of 42.4°C, a swelling degree of 29.6%, and a gel ratio of 90.0%.
preparation example 2
[0128] Preparation of the second water dispersion composition for the primer layer
[0129]Add 40 moles (26 mole%) of 2,6-naphthalene dicarboxylic acid (2,6-Naphtalene dicarboxylic acid), 5 moles (3.3 mole%) of sodium 2,5-dicarboxybenzenesulfonate (sodium 2,5- dicarboxylbenzene sulfonate), 5 moles (3.3 mole%) of dimethyl terephthalic acid, 20 moles (13.3 mole%) of bis[(4-(2-hydroxyethoxy)phenyl]fluorene (Bis[4( 2-hydroxyethoxy)phenyl]fluorene), 10 mol (6.6 mol%) of triglyceride (Triglyceride, product of Kao Corporation (trade name: 85P)), 70 mol (46.6 mol%) of ethylene glycol in a solvent-free state After mixing at low temperature, add it into the reactor, raise the temperature by 1°C per minute from 170°C to 250°C and react, remove water or methanol as a by-product, and carry out esterification reaction, while raising the temperature to 260°C, the reaction The pressure in the vessel was reduced to 1 mm Hg, the diol was recovered as a by-product, and the polycondensation re...
preparation example 3
[0132] Preparation of the third water dispersion composition for the primer layer
[0133] A water-dispersible polyurethane having a theoretical branched polyol content of 50% by weight was prepared. By making 40% by weight of polyol (Polyethyleneadipate Diol: polyethylene adipate diol), 0.6% by weight of trimethylol propane (Trimethylol Propane), 55.9% by weight of hexamethylene diisocyanate (hexamethylenediisocyanate) ) reaction, after preparing the prepolymer (Prepolymer) with the isocyanate functional group as the terminal group, as an ionic group, 3.5% by weight of sodium hydrogen sulfate (Sodium Hydrogen Sulfate) is reacted with the isocyanate as the terminal functional group of the prepolymer to prepare Polyurethane with ionic groups and a weight-average molecular weight of 14400 g / mol.
[0134] The prepared 20% by weight polyurethane was dispersed in 80% by weight water to prepare a polyurethane adhesive with a solid content of 20% by weight. The 4% by weight of th...
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