A kind of sponge alumina and its preparation method and application
A technology of alumina and aluminum hydroxide, applied in the field of alumina refractories, can solve the problems of easy generation of large cracks, high temperature control requirements, difficult to mix evenly, etc., and achieves improved thermal shock resistance and high temperature toughness, excellent heat resistance. shock performance, and the effect of improving thermal shock resistance
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[0029] The invention provides a preparation method of sponge alumina, which comprises impregnating aluminum hydroxide agglomerates with alumina sol and calcining to obtain sponge alumina.
[0030] The preparation method of the sponge alumina of the present invention adopts the agglomerate of aluminum hydroxide impregnated with alumina sol as the raw material for calcination, and the surface of the agglomerate of aluminum hydroxide is coated with a layer of alumina sol containing alumina. During the calcination process, The aluminum hydroxide in the aluminum hydroxide aggregate will lose structural water and undergo crystal transformation, resulting in greater shrinkage, and the aluminum oxide colloid wrapped in the outer layer will also shrink, but the shrinkage ratio is small compared to the aluminum hydroxide aggregate , so that the final inner layer is porous alumina aggregates, and the outer layer forms a net-like alumina package, which constitutes a sponge alumina with a c...
Embodiment 1
[0055] A preparation method of sponge alumina, comprising the steps of:
[0056] (1) Get 240g aluminum hydroxide powder, form the spherical agglomerate that particle diameter is below 1mm through spray granulation;
[0057] (2) Dried the agglomerate obtained in step (1) and impregnated with 100g of alumina sol (manufactured by Qingdao Shanke Haitai New Material Co., Ltd.), and fully stirred so that the alumina sol was evenly coated on the agglomerate obtained in step (1) superior;
[0058] (3) drying the agglomerates coated with alumina sol obtained in step (2), and calcining them at 600° C. for 6 hours to obtain porous alumina agglomerates in the inner layer, and form a reticular alumina wrap in the outer layer, The whole constitutes a sponge alumina with a cladding structure.
Embodiment 2
[0060] A preparation method of sponge alumina, comprising the steps of:
[0061] (1) Get 237.6g aluminum hydroxide powder and 2.4g aluminum oxide powder, fully mix, form the spherical agglomerate that particle diameter is below 1mm through spray granulation;
[0062] (2) Dried the agglomerate obtained in step (1) and impregnated with 100g of alumina sol (manufactured by Qingdao Shanke Haitai New Material Co., Ltd.), and fully stirred so that the alumina sol was evenly coated on the agglomerate obtained in step (1) superior;
[0063] (3) drying the agglomerates coated with alumina sol obtained in step (2), and calcining them at 600° C. for 6 hours to obtain porous alumina agglomerates in the inner layer, and form a reticular alumina wrap in the outer layer, The whole constitutes a sponge alumina with a cladding structure.
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