Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of sponge alumina and its preparation method and application

A technology of alumina and aluminum hydroxide, applied in the field of alumina refractories, can solve the problems of easy generation of large cracks, high temperature control requirements, difficult to mix evenly, etc., and achieves improved thermal shock resistance and high temperature toughness, excellent heat resistance. shock performance, and the effect of improving thermal shock resistance

Active Publication Date: 2020-04-03
河南和成无机新材料股份有限公司
View PDF3 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The method of adding other materials to form a second phase or react to form tiny cracks is difficult to mix evenly during the production process, and the weighing process is also prone to deviations. The firing process requires high temperature control, and it is easy to produce large cracks, or temperature rise and fall If the speed is too fast, it is easy to form a glass phase, and the size of the product exceeds the requirement due to two times of mullitization and spinelization, and the reaction temperature may not have been reached in the castable. to improve toughness

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of sponge alumina and its preparation method and application
  • A kind of sponge alumina and its preparation method and application
  • A kind of sponge alumina and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0029] The invention provides a preparation method of sponge alumina, which comprises impregnating aluminum hydroxide agglomerates with alumina sol and calcining to obtain sponge alumina.

[0030] The preparation method of the sponge alumina of the present invention adopts the agglomerate of aluminum hydroxide impregnated with alumina sol as the raw material for calcination, and the surface of the agglomerate of aluminum hydroxide is coated with a layer of alumina sol containing alumina. During the calcination process, The aluminum hydroxide in the aluminum hydroxide aggregate will lose structural water and undergo crystal transformation, resulting in greater shrinkage, and the aluminum oxide colloid wrapped in the outer layer will also shrink, but the shrinkage ratio is small compared to the aluminum hydroxide aggregate , so that the final inner layer is porous alumina aggregates, and the outer layer forms a net-like alumina package, which constitutes a sponge alumina with a c...

Embodiment 1

[0055] A preparation method of sponge alumina, comprising the steps of:

[0056] (1) Get 240g aluminum hydroxide powder, form the spherical agglomerate that particle diameter is below 1mm through spray granulation;

[0057] (2) Dried the agglomerate obtained in step (1) and impregnated with 100g of alumina sol (manufactured by Qingdao Shanke Haitai New Material Co., Ltd.), and fully stirred so that the alumina sol was evenly coated on the agglomerate obtained in step (1) superior;

[0058] (3) drying the agglomerates coated with alumina sol obtained in step (2), and calcining them at 600° C. for 6 hours to obtain porous alumina agglomerates in the inner layer, and form a reticular alumina wrap in the outer layer, The whole constitutes a sponge alumina with a cladding structure.

Embodiment 2

[0060] A preparation method of sponge alumina, comprising the steps of:

[0061] (1) Get 237.6g aluminum hydroxide powder and 2.4g aluminum oxide powder, fully mix, form the spherical agglomerate that particle diameter is below 1mm through spray granulation;

[0062] (2) Dried the agglomerate obtained in step (1) and impregnated with 100g of alumina sol (manufactured by Qingdao Shanke Haitai New Material Co., Ltd.), and fully stirred so that the alumina sol was evenly coated on the agglomerate obtained in step (1) superior;

[0063] (3) drying the agglomerates coated with alumina sol obtained in step (2), and calcining them at 600° C. for 6 hours to obtain porous alumina agglomerates in the inner layer, and form a reticular alumina wrap in the outer layer, The whole constitutes a sponge alumina with a cladding structure.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention provides sponge aluminum oxide and a preparation method and application thereof. The preparation method of the sponge aluminum oxide comprises the following steps of using an aluminum oxide aggregate soaked by an aluminum oxide sol as a calcining raw material, wrapping the surface of the aluminum oxide aggregate by an aluminum oxide sol layer containing aluminum oxide, and calcining, so as to obtain the sponge aluminum oxide with a coating structure that the inner layer is a porous aluminum oxide aggregate and the outer layer is a latticed aluminum oxide wrapper. The special sponge structure body with the coating structure can greatly improve the anti-heat vibration property and high-temperature toughness of the aluminum oxide. The sponge aluminum oxide has the advantages that the anti-heat vibration property and high-temperature toughness are excellent; the sponge aluminum oxide can be directly applied to various fire-retardant or ceramic products to improve the anti-heat vibration property and high-temperature toughness of the product, the degrading of the high-temperature property caused by the production of other low-temperature phase or glass phase is avoided, and the influence to the size accuracy of the product due to the production of the second phase in the shaped products is also avoided.

Description

technical field [0001] The invention relates to the field of alumina refractory materials, in particular to a sponge alumina and its preparation method and application. Background technique [0002] The current refractories or ceramic corundum products are generally directly added ɑ-Al 2 o 3 , various corundum or other alumina raw materials to improve the high temperature performance of the product, the thermal shock resistance of the product is not very ideal, in order to improve the thermal shock performance or improve the toughness of the product, it is often formed by adding other materials to form the second phase or Is the reaction to form tiny cracks. [0003] The method of adding other materials to form a second phase or react to form tiny cracks is difficult to mix evenly during the production process, and the weighing process is also prone to deviations. The firing process requires high temperature control, and it is easy to produce large cracks, or temperature r...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/10C04B35/66C04B38/06
CPCC04B35/10C04B35/66C04B38/062C04B2235/3218C04B2235/96C04B38/0045
Inventor 肖继东孙志红冯钢军冯海军
Owner 河南和成无机新材料股份有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products