Transparent anti-impact hard PVC particle composition and preparation method thereof

A composition and hard technology, which is applied in the field of transparent impact-resistant rigid PVC pellet composition and its preparation, can solve the problems of high transparency and high impact resistance, improve gloss and light transmittance, and improve The degree of gelation and the effect of achieving uniformity

Active Publication Date: 2017-06-20
XINJIANG CORPS MODERN GREEN CHLOR ALKALI CHEM ENG RES CENT LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The transparent PVC pellets produced by this method have certain transparency, good processability, weather resistance, stability and mechanical properties, and can meet the requirements of extrusion, calendering and other molding processes, but cannot meet the requirements of high-quality transparent impact-resistant rigid PVC. The products require high transparency and high impact resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Composition formula: 100 parts of PVC, 8 parts of impact modifier ACR, 0 parts of bridging agent vinyl chloride-vinyl acetate-butyl acrylate terpolymer resin, 2 parts of heat stabilizer organotin, plasticizer phthalic acid 2 parts of dioctyl ester, 0.5 part of lubricant stearic acid, 0.2 part of ultramarine blue toner.

[0024] Preparation method: Calculate the required weight of each component according to the weight ratio, and weigh the raw materials of each component according to the calculated result; put each component material into the high-speed mixer, start it for high-speed mixing, first turn on the low-speed mixing, and then start High-speed mixing, control the speed of the mixer to 1200-1400 rpm, and raise the temperature of the material in the machine to 105°C; cool and mature the uniformly mixed material for 12 hours, put it into the extruder for extrusion, and select the extruder screw The length-to-diameter ratio is 20-30, the screw speed is 20-30 rpm, an...

Embodiment 2

[0026] Composition formula: 100 parts of PVC, 10 parts of impact modifier ACR, 2 parts of bridging agent vinyl chloride-vinyl acetate-butyl acrylate terpolymer resin, 2 parts of heat stabilizer organotin, plasticizer phthalic acid 2 parts of dioctyl ester, 0.5 part of lubricant stearic acid, 0.2 part of ultramarine blue toner.

[0027]Preparation method: Calculate the required weight of each component according to the weight ratio, and weigh the raw materials of each component according to the calculated result; put each component material into the high-speed mixer, start it for high-speed mixing, first turn on the low-speed mixing, and then start High-speed mixing, control the speed of the mixer to 1200-1400 rpm, and raise the temperature of the material in the machine to 105°C; cool and mature the uniformly mixed material for 12 hours, put it into the extruder for extrusion, and select the extruder screw The length-to-diameter ratio is 20-30, the screw speed is 20-30 rpm, an...

Embodiment 3

[0029] Composition formula: 100 parts of PVC, 10 parts of impact modifier ACR, 4 parts of bridging agent vinyl chloride-vinyl acetate-butyl acrylate terpolymer resin, 2 parts of heat stabilizer organotin, plasticizer phthalic acid 2 parts of dioctyl ester, 0.5 part of lubricant stearic acid, 0.2 part of ultramarine blue toner.

[0030] Preparation method: Calculate the required weight of each component according to the weight ratio, and weigh the raw materials of each component according to the calculated result; put each component material into the high-speed mixer, start it for high-speed mixing, first turn on the low-speed mixing, and then start High-speed mixing, control the speed of the mixer to 1200-1400 rpm, and raise the temperature of the material in the machine to 105°C; cool and mature the uniformly mixed material for 12 hours, put it into the extruder for extrusion, and select the extruder screw The length-to-diameter ratio is 20-30, the screw speed is 20-30 rpm, a...

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Abstract

The invention discloses a transparent anti-impact hard PVC particle composition and a preparation method thereof. The transparent impact-resistant hard PVC particle composition is characterized in that vinyl chloride-vinyl acetate-butyl acrylate ternary copolymerized resin is used as a bridging agent and cooperates with other modifiers, then mixed granulation is performed to obtain the transparent anti-impact hard PVC particle composition; the composition comprises the following components in parts by weight with each 100 parts by weight of PVC as the benchmark: 100 parts of polyvinyl chloride, 8-15 parts of an anti-impact modifier, 0-4 parts of a bridging agent, 1-3 parts of a heat stabilizer, 2-3 parts of a plasticizer, 0.3-0.8 part of a lubricant, and 0.1-0.3 part of a color toner. By selection of the particle size of anti-impact modifier colloidal particles and introduction of the vinyl chloride-vinyl acetate-butyl acrylate ternary copolymerized resin as the bridging agent, the transparent anti-impact rigid PVC particle formula is improved, the purpose of improving the impact resistance and transparency of the material is finally reached, and the requirements of high-quality transparent anti-impact hard PVC products on high transparency and high impact resistance are met.

Description

technical field [0001] The invention relates to the field of transparent anti-impact rigid PVC granules, more specifically, it relates to a transparent anti-impact rigid PVC granule composition and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC for short) is one of the most widely used polymer materials, because it is non-toxic, transparent, easy to process and shape, especially the secondary molding has good air tightness and colorability, and has good physical properties etc., all aspects can meet the requirements as packaging materials, widely used in the field of packaging. However, PVC has poor toughness and is a brittle material. At the same time, its melt viscosity is high, and it is easy to decompose when heated, and the processing temperature is close to the decomposition temperature. , stabilizer, lubricant, toner and other second and third component processing aids to modify it. [0003] In the transparent impact-resistant ri...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L33/04C08L51/04C08K5/00C08K5/12C08K5/09
CPCC08L27/06C08L2201/10C08L2205/02C08L2205/03C08L33/04C08K5/00C08K5/12C08K5/09C08L51/04
Inventor 宋晓玲黄东沈姗姗贺盛喜彭兵
Owner XINJIANG CORPS MODERN GREEN CHLOR ALKALI CHEM ENG RES CENT LTD
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