All-solid UV bright light anti-scratch coating for bopp precoating film and preparation method thereof
A scratch-resistant, pre-coated film technology, applied in polyurea/polyurethane coatings, coatings, etc., can solve problems such as poor scratch resistance, achieve good scratch resistance, high hardness, and improve conversion efficiency.
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Embodiment 1
[0039] Put 37.5 parts of nanocomposite polyurethane acrylate oligomer, 17.5 parts of aliphatic urethane acrylate oligomer, 25 parts of reactive diluting monomer No. 1, and 15 parts of reactive diluting monomer No. 2 into the high-speed mixer at 500r / min Stir for 3min at a speed of 1°C.
[0040] Add 1.5 parts defoamer, 1 part wetting agent, and 2 parts leveling agent to the mixed system obtained by stirring, adjust the mixer speed to 1200r / min at a uniform speed, and disperse at high speed for 10 minutes.
[0041] Finally, add 2 parts of photoinitiator No. 1 and 1 part of photoinitiator No. 2 to the mixed system obtained by stirring, and stir at 800r / min for 5 minutes, and then fill the obtained transparent paint into a can.
[0042] The reactive diluent monomer No. 1 is a difunctional acrylate monomer; the reactive diluent monomer No. 2 is a difunctional acrylate monomer; the photoinitiator No. 1 is 2-hydroxy-2- One of methyl-1-phenyl-1-acetone or 1-hydroxycyclohexyl phenyl ketone o...
Embodiment 2
[0044] Put 30 parts of nanocomposite polyurethane acrylate oligomer, 25 parts of aliphatic urethane acrylate oligomer, 25 parts of reactive diluent monomer No. 1 and 15 parts of reactive diluent monomer No. 2 into the high-speed mixer at 500r / min Stir for 3min at a speed of 1°C.
[0045] Add 1.5 parts defoamer, 1 part wetting agent, and 2 parts leveling agent to the mixed system obtained by stirring, adjust the mixer speed to 1200r / min at a uniform speed, and disperse at high speed for 10 minutes.
[0046] Finally, add 2 parts of photoinitiator No. 1 and 1 part of photoinitiator No. 2 to the mixed system obtained by stirring, and stir at 800r / min for 5 minutes, and then fill the obtained transparent paint into a can.
[0047] The reactive diluent monomer No. 1 is a difunctional acrylate monomer; the reactive diluent monomer No. 2 is a difunctional acrylate monomer; the photoinitiator No. 1 is 2-hydroxy-2- One of methyl-1-phenyl-1-acetone or 1-hydroxycyclohexyl phenyl ketone or a com...
Embodiment 3
[0057] The full-solid UV bright anti-scratch coating for BOPP pre-coating film is composed of the following components based on parts by weight: nanocomposite polyurethane acrylate oligomer: 15-50 parts; aliphatic polyurethane acrylate oligomer: 9-32 parts ; Reactive diluent monomer No. 1: 15-65 parts; Reactive diluent monomer No. 2: 10-40 parts; Photoinitiator No. 1: 1-6 parts; Photoinitiator No. 2: 0.3-1.8 parts; Foaming agent: 0.3-2.5 parts; wetting agent: 0.3-2.5 parts; leveling agent: 0.3-2.5 parts; the reactive diluent monomer No. 1 is a difunctional acrylate monomer; the reactive diluent single Body No. 2 is a difunctional acrylate monomer; The photoinitiator No. 1 is one of 2-hydroxy-2-methyl-1-phenyl-1-acetone or 1-hydroxycyclohexyl phenyl ketone , Or a mixed compound of 2-hydroxy-2-methyl-1-phenyl-1-acetone and 1-hydroxycyclohexyl phenyl ketone; the photoinitiator No. 2 is 2,4,6-trimethyl Ethyl acyl phenyl phosphonate; the nano-composite polyurethane acrylate oligome...
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