A nonylphenol-free epoxy thick paint and its preparation and use method

A technology of nonylphenol and epoxy, applied in the direction of epoxy resin coating, coating, etc., can solve the problem of easy deepening of color, achieve fast hardening speed, meet construction requirements, and shorten drying time

Active Publication Date: 2018-11-16
YANTAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the deficiencies in the prior art, the purpose of the present invention is to provide a nonylphenol-free epoxy thick paint, to solve the problem of harmful chemical substances such as nonylphenol and the like in the epoxy thick paint used by fishing rods or other sporting goods. The problem that the color of epoxy thick paint is easy to deepen

Method used

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  • A nonylphenol-free epoxy thick paint and its preparation and use method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] 1) Preparation of epoxy component of epoxy thick paint: 94 parts of low molecular weight bisphenol A epoxy resin, C 12 ~C 14 5 parts of alkyl glycidyl ether, 0.6 part of defoamer, 0.4 part of leveling agent, after mixing the above components, stir evenly.

[0038] 2) Preparation of epoxy thick paint curing agent components: 19 parts of low molecular weight bisphenol A epoxy resin (epoxy value 0.50~0.54eq / 100g), 7 parts of butyl glycidyl ether, 21 parts of diethylene triamine Parts, 9 parts of isophorone diamine, 36 parts of benzyl alcohol, 8 parts of carboxyl-terminated hyperbranched polyether with a molecular weight of 3000~7000 g / mol, the above components were mixed and reacted for 4 hours under stirring conditions to obtain the modified Hardener.

[0039] When in use, mix the above-mentioned epoxy components and curing agent components in equal proportions to obtain epoxy thick paint, which can be directly used for coating.

Embodiment 2

[0041] 1) Preparation of epoxy component of epoxy thick paint: 80 parts of low molecular weight bisphenol A type epoxy resin, 10 parts of low molecular weight bisphenol F type epoxy resin, 8.5 parts of benzyl glycidyl ether, 0.8 parts of defoamer , 0.7 parts of leveling agent, after mixing the above components, stir evenly.

[0042] 2) Preparation of epoxy thick paint curing agent components: 16 parts of bisphenol A epoxy resin, 7 parts of butyl glycidyl ether, 3 parts of 1,4-butanediol diglycidyl ether, 17 parts of diethylene triamine 4 parts, 4 parts of trivinyltetramine, 7 parts of N-(ß-aminoethyl) piperazine, 45 parts of benzyl alcohol, 1 part of carboxyl-terminated hyperbranched polyether with a molecular weight of 800~1700 g / mol, the above components are in Under the condition of stirring, the epoxy compound is dissolved in benzyl alcohol, and is added dropwise to the mixture of organic amines for 2 hours, and then stirred and reacted for 3 hours after the dropwise addit...

Embodiment 3

[0045] 1) Preparation of epoxy component of epoxy thick paint: 80 parts of low molecular weight bisphenol A epoxy resin (epoxy value 0.50-0.54eq / 100g), low molecular weight bisphenol A epoxy resin (epoxy value 0.42-0.45 eq / 100g) 12 parts, neopentyl glycol diglycidyl ether 7 parts, defoamer 0.7 parts, leveling agent 0.3 parts, after mixing the above components, stir evenly.

[0046] 2) Preparation of epoxy thick paint curing agent components: 16 parts of bisphenol A epoxy resin, 3 parts of low molecular weight bisphenol F epoxy resin, 7 parts of 1,6-hexanediol diglycidyl ether, diethylene 19 parts of triamine, 2 parts of triethylenetetramine, 5 parts of N-(ß-aminoethyl)piperazine, 2 parts of isophorone diamine, 41 parts of benzyl alcohol, the molecular weight is 1400~3000 g / mol 5 parts of carboxyl hyperbranched polyether, the above components are under stirring conditions, the epoxy compound is dissolved in benzyl alcohol, and added dropwise to the mixture of organic amines for...

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Abstract

The invention provides nonylphenol-free epoxy paste paint, and solves the problems that epoxy paste paint used for a fishing rod or other sports goods contains harmful chemical substances such as nonylphenol and the color of the epoxy paste paint is easy to darken. Compared with the epoxy paste paint in the prior art, the nonylphenol-free epoxy paste paint provided by the invention does not contain a compound with a phenol structure, so that an obtained epoxy curing agent and a curing coating layer are relatively high in color stability and difficult to discolor; moreover, harms of nonylphenol to a human body and an environment are eliminated from the source; the nonylphenol-free epoxy paste paint meets the national environmental protection requirement and the environmental protection requirement for exporting the products to all districts in foreign countries, and is more ecological and environmentally-friendly.

Description

technical field [0001] The invention relates to an epoxy impregnated paint, which does not contain harmful compounds such as nonylphenol, and satisfies domestic and export requirements to countries and regions such as the United States and Europe. Background technique [0002] Epoxy thick paint is used for the coating, protection and decoration of fishing rod guide ring winding, fishing rod stickers and other places in the fishing gear industry. In current use, it is required that the thick epoxy paint after compounding has stable color, fast hardening at room temperature, high surface gloss, high flexibility and good chemical resistance. [0003] Existing thick epoxy paints meet the requirements of fast hardening and bright coating surface at room temperature, but as time goes by, photochemical reactions tend to generate colored groups, resulting in discoloration and affecting the appearance, especially for decorative purposes. The stickers are beautiful. [0004] In addi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/00C08G59/68
CPCC08G59/68C08L2205/03C09D163/00C08L83/04C08L33/04
Inventor 郑耀臣
Owner YANTAI UNIV
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