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Nylon material and its preparation method and application

A technology of nylon and long-chain nylon, applied in the field of nylon materials and its preparation, can solve the problems of reducing the impact strength of materials, affecting the appearance of parts, affecting the assembly of parts, etc., achieving low melting point temperature, convenient for industrial application, rigidity and toughness well balanced effect

Active Publication Date: 2020-08-18
GUANGZHOU SUPER DRAGON ENG PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional polyolefin elastomer toughened glass fiber reinforced nylon 6 and nylon 66 materials are prone to weld lines during multi-gate injection molding, which affects the appearance of the parts.
[0005] Moreover, general polyolefin elastomer toughened glass fiber reinforced PA6 and PA66 materials are prone to warping and deformation during injection molding, especially when injecting long and thin-walled parts such as automotive door and window frame surround trim strips.
The warping deformation will obviously seriously affect the later assembly of the parts.
Although the addition of mineral fillers such as mica, talc, wollastonite and glass fiber can improve the warpage of glass fiber reinforced PA6 and PA66, but the impact strength of the material is greatly reduced

Method used

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  • Nylon material and its preparation method and application
  • Nylon material and its preparation method and application
  • Nylon material and its preparation method and application

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Embodiment Construction

[0039] The nylon material of the present invention and its preparation method and application will be further described in detail below in conjunction with specific examples.

[0040] The raw materials used in Examples 1-6 and Comparative Examples 1-11 of the present invention are as follows:

[0041] The nylon 6 copolymer is a nylon 6 / 610 copolymer (PA6 / 610, nylon 6 accounts for 85% by mass, and nylon 610 accounts for 15% by mass), relative viscosity: 2.6, melting point: 188°C.

[0042] The manufacturing method of the nylon 6 / 610 copolymer is as follows:

[0043] Put 85kg of caprolactam and 2500mL of water into a 400L autoclave, fill it with nitrogen to eliminate oxygen and seal it. The reaction kettle was heated to 150°C, and then 37.5kg of hexamethylene sebacamide aqueous solution with a mass concentration of 40% was added to the reaction kettle through a metering pump. The temperature in the reaction kettle was at 150°C, the internal pressure was 2.5kg, and the reaction kettle was...

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Abstract

The invention relates to a nylon material. The nylon material is prepared from, by weight, 50-80% of nylon 6 copolymer, 10-30% of glass fiber, 3-20% of flexibilizer, 0.1-1% of heat stabilizer, 0.1-1% of processing agents, 0.1-1% of nucleating agent and 0.5-3% of plastic coloring agent, wherein the nylon 6 copolymer is a nylon 6 and long-chain nylon copolymer; the long-chain nylon is formed by condensation polymerization of hexamethylenediamine and dicarboxylic acid; the molecular formula of the dicarboxylic acid is HOOC-(CH2)R-COOH, wherein R=7-12. The nylon material adopts the reasonably-set component ratio, the nylon 6 and long-chain nylon copolymer is adopted as a resin matrix, by means of glass fiber reinforcement, the obtained nylon material has the good injection molding surface, no weld mark is formed on the surface, buckling deformation is low, the rigidity and toughness are balanced well, and the nylon material is quite suitable for automobile component manufacturing.

Description

Technical field [0001] The present invention relates to a polymer material, in particular to a nylon material and its preparation method and application. Background technique [0002] Glass fiber reinforced nylon materials are widely used in automobile interior and exterior parts due to their excellent comprehensive properties such as good rigidity, heat resistance and dimensional stability. [0003] The car door and window frame surrounds the decorative strip, which is used to protect the car door and window frame from being damaged by external forces such as vibration, scratching, collision, etc., to ensure the safety of the car door and window. Therefore, the nylon material used for the car door and window frame to surround the decorative strip needs to have a good balance of rigidity and toughness, that is, the material needs higher impact strength, bending strength, tensile strength and other mechanical properties. However, the traditional glass fiber reinforced nylon 6 and n...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/02C08L51/06C08L23/06C08K13/04C08K7/14C08K3/04C08K3/34B29C48/92
CPCB29C48/92B29C2948/9258B29C2948/92704C08K2201/003C08K2201/004C08L77/00C08L2205/025C08L2205/035C08L2205/24C08L51/06C08L23/06C08K13/04C08K7/14C08K3/04C08K3/34
Inventor 郝建鑫陈维维李齐添严松阳郝源增陈瑜李桂波
Owner GUANGZHOU SUPER DRAGON ENG PLASTICS