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Preparation of calcium-base polysulfide repairing agent and application of calcium-base polysulfide repairing agent to polluted environment repairing

A polysulfide, polluting environment technology, applied in the restoration of polluted soil, polluted groundwater/leachate treatment, water pollutants, etc., to achieve the effect of increasing stability, easy availability of raw materials, and less consumption

Inactive Publication Date: 2017-07-28
QINGDAO UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] By consulting relevant literature and patents related to the preparation and use of calcium-based polysulfides at home and abroad, the results show that before the present invention, the preparation method and method of calcium-based polysulfides that have not been used for repairing hexavalent chromium in polluted environments Report on how to apply

Method used

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  • Preparation of calcium-base polysulfide repairing agent and application of calcium-base polysulfide repairing agent to polluted environment repairing
  • Preparation of calcium-base polysulfide repairing agent and application of calcium-base polysulfide repairing agent to polluted environment repairing
  • Preparation of calcium-base polysulfide repairing agent and application of calcium-base polysulfide repairing agent to polluted environment repairing

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preparation example Construction

[0042] In the embodiment of the preparation method of a calcium-based polysulfide restoration agent of the present invention, quicklime and elemental sulfur are first prepared into suspension solutions, and then the sulfur solution is slowly added to lime water, and the reaction is carried out under stirring conditions to obtain calcium-based polysulfide repair agent. Sulfide repair agent. Concrete preparation method comprises the following steps:

[0043] (1) Prepare quicklime, elemental sulfur, and water as raw materials in a certain proportion;

[0044] (2) Use a small amount of hot water to adjust the elemental sulfur into a paste-like sulfur slurry, and stir evenly;

[0045] (3) Put quicklime in a beaker, dissolve it with a small amount of water, make a paste, add enough water, and heat on an electric furnace;

[0046] (4) Slowly pour the pre-adjusted sulfur slurry into the lime water from the side of the beaker, stir while pouring, and record the water level;

[0047]...

Embodiment 1

[0054] Formula and material selection: Prepared according to the ratio of quicklime, sulfur powder and water at 1:2:10 (mass: mass: volume), the quicklime is made of calcium oxide reagent, the elemental sulfur is sulfur powder, and the water is deionized water.

[0055] The preparation steps are:

[0056] (1) Mix the sulfur powder with a small amount of water (hot water) to make a paste-like sulfur slurry, and the more uniform the stirring, the better;

[0057] (2) Put the quicklime into the beaker, dissolve it with a small amount of water (the lime dissolves more slowly when the water is too much over the lime), make a paste, pour it into the beaker and add enough water (wash and dissolve the quicklime beaker), and then heated on an electric stove;

[0058] (3) When the milk of lime is close to boiling, slowly pour the sulfur slurry adjusted in advance from the edge of the beaker into it (rinse the beaker), stir while pouring, and record the water level. Prevent the splashe...

Embodiment 2

[0063] Formula and material selection: Prepared according to the ratio of quicklime, sulfur powder and water at 1:2:10 (mass: mass: volume), the quicklime is made of calcium oxide reagent, the elemental sulfur is sulfur powder, and the water is deionized water.

[0064] The preparation steps are:

[0065] (1) Mix the sulfur powder with a small amount of water (hot water) to make a paste-like sulfur slurry, and the more uniform the stirring, the better;

[0066] (2) Put the quicklime into the beaker, dissolve it with a small amount of water (the lime dissolves more slowly when the water is too much over the lime), make a paste, pour it into the beaker and add enough water (wash and dissolve the quicklime beaker), and then heated on an electric stove;

[0067] (3) When the milk of lime is close to boiling, slowly pour the sulfur slurry adjusted in advance from the edge of the beaker into it (rinse the beaker), stir while pouring, and record the water level. Prevent the splashe...

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Abstract

The invention provides preparation of a calcium-base polysulfide repairing agent and application of the calcium-base polysulfide repairing agent to polluted environment repairing. The preparation and application are mainly used for repairing of hexavalent chromium polluted water and soil. The repairing agent is formed by preparing raw materials including unslaked lime, elemental sulfur and water according to the proportion, lime water is heated firstly, then elemental sulfur powder is dissolved through hot water, and when the lime water is about to boil, a sulfur solution is poured, high-temperature heating is continuously conducted for 60 min, then cooling and filtering are conducted, and the red brown and transparent repairing agent is obtained. According to an application method, a proper number of repairing agents are added in the hexavalent chromium polluted water and soil, sufficient stirring is conducted, a certain reaction time is given, hexavalent chromium in the water and soil is reduced into trivalent chromium, and repairing is finished. According to the preparation of the calcium-base polysulfide repairing agent and the application of the calcium-base polysulfide repairing agent to polluted environment repairing, when the polluted water is repaired, the hexavalent chromium can be reduced into the trivalent chromium, sediment is generated, and the repairing effect is good; when the polluted soil is repaired, the trivalent chromium obtained through reducing can be fixed into the soil, stability of 60d or above is kept, stability is high, secondary pollution is avoided, cost is low, and the calcium-base polysulfide repairing agent and the application of the calcium-base polysulfide repairing agent to polluted environment repairing are suitable for in-situ repairing of the hexavalent chromium polluted soil.

Description

technical field [0001] The invention relates to the field of environmental protection, in particular to the preparation of a calcium-based polysulfide remediation agent and its application in the remediation of polluted environments. Background technique [0002] As an important industrial raw material, chromium salts and chromium play an important role in my country's national economy, and are widely used in industries such as tanning, dyestuffs, metal pickling, metallurgy, and electroplating. However, the " Improper disposal of the "three wastes" will cause serious environmental pollution. In the early production process of chromium salt, the technology was relatively backward, and the residual concentration of hexavalent chromium in chromium slag was relatively high, about 1.5%-2.5%. Infiltration measures have resulted in the dissolution of a large amount of soluble hexavalent chromium, causing serious soil pollution. Hexavalent chromium is a carcinogenic and teratogenic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B09C1/08B09C1/00C02F1/00C02F101/22C02F103/06
CPCC02F1/00B09C1/002B09C1/08C02F2101/22C02F2103/06
Inventor 孙玉焕杨志海宋淑敏关峰孙延慧
Owner QINGDAO UNIV OF SCI & TECH