Semi-continuous casting process of VW64M high-strength heat-resistant magnesium alloy big ingot blank

A 1. VW64M, casting process technology, applied in the field of magnesium alloy casting, Mg-Gd-Y-Ag-Zn-Zr-Ca series magnesium alloy semi-continuous casting, can solve the problem of reducing the fluidity of the melt, increasing the difficulty of forming, Increase the difficulty of casting and other issues to achieve the effect of accelerating the diffusion of solute atoms, eliminating the segregation of solute atoms, and reducing oxide slag inclusions

Active Publication Date: 2017-08-11
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the process of preparing large magnesium alloy ingots by conventional semi-continuous casting, the melt is easily burned, resulting in a large number of defects such as inclusions, pores, porosity, and central cracks inside the ingot, which reduces the quality of the ingot and directly affects the subsequent deformation process and structure. normal use of the
In the casting process of the rare earth magnesium alloy billet, due to the large amount of rare earth added, the density of the melt is increased, the fluidity of the melt is reduced, and the surface of the ingot is severely cold-shocked; the addition of rare earth causes a large amount of metal shrinkage, and the casting thermal stress increases sharply , making various casting defects more likely to appear, especially the penetrating cracks running through the billet, which significantly increases the difficulty of forming
Especially the addition of Zn element increases the tendency of edge cracking and hot cracking, which increases the difficulty of casting

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] In a smelting furnace with a capacity of 1 ton, melt high-purity magnesium ingots, control the temperature of the melt at 690-700℃ during melting, and add Mg-Ca master alloy and 6# flux after the magnesium ingots are completely melted. Ca element accounts for the mass percentage of the alloy. 0.01%. Remove scum on the surface of the melt, in SF 6 With CO 2 Under the protection of the mixed gas, the temperature is increased to 750-780℃, and Mg-Gd master alloy, high-purity zinc, Mg-Y master alloy, Mg-Zr master alloy, and high-purity silver are sequentially added, and 6# flux is added. After the raw materials are completely melted, remove the scum on the surface of the molten liquid, and pass in argon gas to stir and degas for 10 minutes. After capping and sealing the melt in SF 6 With CO 2 Adjust the melt temperature to 760-770°C under the protection of, and keep it for 20min. Turn off the resistance furnace, keep the melt temperature at 680-690℃, and let it stand for 1.5...

Embodiment 2

[0017] In a smelting furnace with a capacity of 1 ton, melt high-purity magnesium ingots, control the melt temperature at 680-690°C during melting, and add Mg-Ca master alloy and 6# flux after the magnesium ingots are melted. Ca element accounts for 0.02 of the alloy mass percentage. %. Remove scum on the surface of the melt, in SF 6 With CO 2 Increase the temperature to 760-790°C under the protection of the mixed gas, and add Mg-Gd master alloy, high-purity zinc, Mg-Y master alloy, Mg-Zr master alloy, high-purity silver, and add 6# flux. After all the raw materials are melted, the scum on the surface of the melt is removed, and argon gas is introduced to stir and degas for 15 minutes. After capping and sealing the melt in SF 6 With CO 2 Adjust the melt temperature to 760-770°C under the protection of, and keep it for 25min. Turn off the resistance furnace, keep the melt temperature at 680-690℃, and let it stand for 2.5h. After that, it is cast, the current is 100mA, the freq...

Embodiment 3

[0019] In a smelting furnace with a capacity of 1 ton, melt high-purity magnesium ingots, control the temperature of the melt to 670-680°C during melting, and add Mg-Ca master alloy and 6# flux after the magnesium ingots are melted. Ca element accounts for 0.05 of the alloy mass percentage %. Remove the scum on the surface of the melt and pass into SF 6 With CO 2 Mg-Gd master alloy, high-purity zinc, Mg-Y master alloy, Mg-Zr master alloy, high-purity silver are added in sequence, and 6# flux is added. After all the raw materials are melted, the scum on the surface of the melt is removed, and argon gas is introduced to stir and degas for 20 minutes. After capping and sealing the melt in SF 6 With CO 2 Adjust the melt temperature to 770-780°C under the protection of, and keep it for 30min. Turn off the resistance furnace, keep the melt temperature at 680-690℃, and let it stand for 3h. After casting, the current is 80mA, the frequency is 18Hz, and the cooling water flow is 35m. ...

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Abstract

The invention discloses a semi-continuous casting process of a VW64M high-strength heat-resistant magnesium alloy big ingot blank. An alloy contains, by weight, 5.0-7.0% of Gd, 2.5-4.0% of Y, 0.1-0.3% of Ag, 0.15-1.0% of Zn, 0.25-0.65% of Zr, 0.002-0.050% of Ca and the balance Mg. The process mainly includes the following steps that a magnesium ingot is molten at the temperature ranging from 670 DEG C to 720 DEG C; a Mg-Ca intermediate alloy and a fluxing agent are added; alloy elements are added at the temperature of 750 DEG C to 800 DEG C; refining and slagging-off are performed; gas feeding and stirring are performed; the temperature is adjusted to reach 680 DEG C to 700 DEG C and maintained for still standing for 1.5-3.5 hours; and low-temperature low-speed electromagnetic casting is performed. By coordinating the process parameters of all the steps, the magnesium alloy ingot blank being free of cracks, smooth in surface, small in grain size, uniform in structure and free of solute segregation and having the diameter phi of 300-630 mm and the length of at least 1000 mm is obtained.

Description

Technical field [0001] The invention relates to the field of magnesium alloy casting, in particular to the field of semi-continuous casting of Mg-Gd-Y-Ag-Zn-Zr-Ca series magnesium alloys with a diameter of Ф300-630mm. Background technique [0002] In recent years, magnesium and magnesium alloys, as important structural materials, have the advantages of low density, high specific strength, high damping performance, and good cutting performance. In automobiles, information electronics and aerospace, materials that require light weight and high strength Large-size magnesium alloy structural parts have broad application prospects. Adding rare earths to magnesium greatly improves the strength and heat resistance of the alloy, but the plasticity is low. The study found that Mg-Gd-Y-Ag-Zn-Zr-Ca series magnesium alloy has high strength, good heat resistance, strong plastic deformation ability and high ductility. After plastic deformation, room temperature elongation δ≥10%, tensile stre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C23/06C22C1/03C22C1/06B22D11/115
CPCB22D11/001B22D11/115C22C1/03C22C1/06C22C23/06
Inventor 高永浩王俊凯刘楚明蒋树农王必正余世伦
Owner CENT SOUTH UNIV
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