A kind of insulating stretch-resistant heat-conducting coating and its preparation method and application
A heat-conducting coating and anti-stretching technology, which is applied in fireproof coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problem of elongation, temperature resistance, insulation and high thermal conductivity of capacitor aluminum shell coatings, paint coatings, etc. The temperature resistance of the film has high requirements and affects the appearance quality of the circuit board, etc., so as to achieve the effects of easy promotion and use, good elongation and simple preparation method
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Embodiment 1
[0029] The following proportions (by mass parts) were used to prepare insulating and stretch-resistant thermally conductive coatings: 25 parts of polyurethane polyol A, 25 parts of polyurethane polyol B, 26.85 parts of mixed solvent, 1 part of polyester hyperdispersant, and 1.2 parts of silane coupling agent part, 15 parts of aluminum oxide, 5 parts of boron nitride, 1 part of graphene, 0.3 part of organosilicon, 0.15 part of polyether modified organosilicon, 0.5 part of polysiloxane, and its specific steps are:
[0030] 1) Put polyurethane polyol resin A, polyurethane polyol resin B, and mixed solvent into a mixer and stir until they are uniformly dispersed to obtain a mixture.
[0031] 2) Mix silane coupling agent, polyester hyperdispersant, aluminum oxide, boron nitride, graphene, silicone, polyether modified silicone and polysiloxane with the mixture obtained in step 1) Uniformly, to obtain mixed raw materials.
[0032] 3) Grind the mixed raw material obtained in step 2) ...
Embodiment 2 4
[0034] Compared with Embodiment 1, Embodiments 2 to 4 differ only in the ratio of raw materials (by mass parts), see Table 1 for details.
[0035] Table 1 The proportioning table of raw material parts by mass in Examples 2 to 4
[0036] Embodiment two Embodiment Three Embodiment four Polyurethane polyol A 30 29 28 Polyurethane polyol B 14.2 15 20 mixed solvent 22.45 22.65 25.85 Polyester Hyperdispersant 1 1 1 A silane coupling agent 1.4 1.4 1.2 Aluminum oxide 20 10 5 boron nitride 10 10 1 Graphene 1 10 18 Silicone 0.3 0.25 0.3 Polyether modified silicone 0.15 0.2 0.15 polysiloxane 0.5 0.5 0.5
Embodiment 5
[0038] The aluminum plate with a thickness of 0.2-0.5 mm is subjected to pretreatments such as degreasing and chromizing, and the insulating and stretch-resistant thermally conductive coatings prepared in each embodiment and the existing commercially available coatings of the same type are respectively coated on the above-mentioned cleaning surface with a wire bar coater. Bake the clean aluminum plate at 245°C for 60-80s, the curing temperature is 210-232°C, and the dry film thickness is controlled at 10-16μm. Then check its performance, see Table 2 for details.
[0039] Table 2 Performance comparison table of insulating and tensile-resistant thermally conductive coatings
[0040] Example insulation Stretch resistance High temperature resistance printability aspect ratio Thermal conductivity (W / m.K) Embodiment one OK OK OK OK 3:1 3.12 Embodiment two OK OK OK OK 2:1 5.08 Embodiment Three OK OK OK OK 2:1 17.42 ...
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