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Method for manufacturing sheet-like product

A manufacturing method and sheet-like technology, applied in textiles, papermaking, fiber processing, etc., can solve problems such as unresolved, water-dispersed polyurethane hardening, etc., and achieve the effects of excellent moisture and heat resistance, good surface appearance and hand feeling

Active Publication Date: 2017-08-18
TORAY IND INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, the hand of water-dispersed polyurethane tends to harden due to the reaction with the cross-linking agent, and no technology has been proposed to maintain the hand at the same level as before cross-linking.

Method used

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  • Method for manufacturing sheet-like product

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0142] As the sea component, polyethylene terephthalate copolymerized with 8 mol% of sodium isophthalate-5-sulfonate was used, and as the island component, polyethylene terephthalate was used, and With a composite mass ratio of 20% by mass of the sea component and 80% by mass of the island component, a sea-island type composite fiber with an island number of 16 islands per filament and an average fiber diameter of 20 μm was obtained. The obtained island-in-the-sea composite fibers were cut into fiber lengths of 51 mm to form staple fibers, and a fiber web was formed by a card and a crosslapper, and a nonwoven fabric was formed by needle punching.

[0143] The nonwoven fabric thus obtained was immersed in hot water at a temperature of 97° C. for 5 minutes to shrink it, and dried at a temperature of 100° C. for 10 minutes. Next, an aqueous solution adjusted to 10% by mass (in terms of solid content) of PVA [NM-14 manufactured by Nippon Synthetic Chemicals Co., Ltd.] with a degre...

Embodiment 2

[0148] The crosslinking agent to be given was changed to a blocked isocyanate series ["ELASTRON" (registered trademark) BN-69 manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd.], except that, it was performed in the same manner as in Example 1 to obtain a weight per unit area of 258g / m 2 artificial leather. The obtained artificial leather had good abrasion resistance and appearance, and had good hand feeling. In addition, the stress retention rate at 10% elongation of the fabric before dyeing when wet was 74%. The results are shown in Table 1.

Embodiment 3

[0150] As the sea component, polyethylene terephthalate copolymerized with 8 mol% of isophthalic acid-5-sulfonate sodium was used, and as the island component, polyethylene terephthalate was used. With a compounding ratio of 20% by mass and an island component of 80% by mass, an island-in-sea type composite fiber with an island number of 16 islands / filament and an average fiber diameter of 20 μm was obtained. The obtained island-in-the-sea composite fiber was cut into a fiber length of 51 mm to make short fibers, and a fiber web was formed by a carding machine and a cross-lapper, and a non-woven fabric was made by needle punching.

[0151] The nonwoven fabric thus obtained was immersed in hot water at a temperature of 97° C. for 2 minutes to shrink it, and dried at a temperature of 100° C. for 5 minutes. Next, the obtained nonwoven fabric was impregnated with a dispersion liquid (the dispersion liquid was added in an amount of 4% by mass relative to the polyurethane solid cont...

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Abstract

The present invention provides a method for manufacturing a sheet-like product having good surface quality and texture and, in particular, excellent moist heat resistance, by means of an environmentally-friendly manufacturing step in which, regardless of the polyurethane hardening method, a reaction with a crosslinking agent is performed and the texture of the product is maintained so as to be similar to the texture before crosslinking. This method for manufacturing a sheet-like product is characterized in that a liquid solution, in which a crosslinking agent is dissolved or dispersed, is applied to a sheet obtained by impregnating a fibrous base material with a water-dispersed polyurethane as a binder and hardening the impregnated material, and then the sheet is heated to 100DEG C-200DEG C.

Description

technical field [0001] The present invention relates to a method for manufacturing an environmentally friendly sheet without using an organic solvent in the manufacturing process, and in particular to a method for manufacturing a sheet with excellent heat and humidity resistance, good surface appearance and hand feel. Background technique [0002] A sheet mainly composed of a fibrous base material (which is formed of fabric such as nonwoven fabric) and polyurethane has excellent characteristics that natural leather does not have, and has been widely used in various applications such as artificial leather. In particular, sheets using fibrous substrates made of polyester fibers are increasingly used in clothing, seat surface processing materials, and automotive interior materials because of their excellent light resistance. . [0003] When producing such a sheet, a combination of the following steps is generally employed: impregnating the fibrous base material with an organic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06N3/14D06M13/322D06M15/564
CPCD06N3/14D06N3/0004D06N3/0011D06N3/147D06N2211/28D06M13/322D06M15/564C08J9/0085C08J2375/04D06N3/0036D06N3/005D06N2205/243
Inventor 村原寿中井俊一郎石金正幸
Owner TORAY IND INC