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121results about How to "Low dielectric loss tangent" patented technology

Method for producing curing agent having acidic substituent and unsaturated maleimide group, thermosetting resin composition, prepreg, and laminate

Disclosed is a method for producing a curing agent having an acidic substituent and an unsaturated maleimide group, wherein a maleimide compound (a) having at least two N-substituted maleimide groups in a molecule and an amine compound (b) having an acidic substituent represented by the general formula (I) below are reacted in an organic solvent. Also disclosed is a thermosetting resin composition containing a curing agent (A) obtained by the above-described method, and a compound (B) which is cured with the curing agent. A cured product of such a thermosetting resin composition has a glass transition temperature of not less than 200 DEG C. Further disclosed are a prepreg using such a thermosetting resin composition, and a laminate. The curing agent produced by this method enables to obtain a thermosetting resin composition having good solubility in an organic solvent, while being excellent in adhesion to metal foils, heat resistance, moisture resistance, flame retardance, copper cladding heat resistance, low dielectric characteristics and low dielectric loss tangent property. Consequently, the curing agent enables to obtain a prepreg or a laminate having excellent properties useful for printed wiring boards for electronic devices.
Owner:HITACHI CHEM CO LTD

Diphenyl sulfone-containing aminosilane coupling agent and preparing method thereof

The present invention relates to a coupling agent containing diphenylsulfone amino-silane and the related preparation method, which is technically characterized in that 4,4-diphenylsulfone and gamma-chloropropthyl type silane are taken as raw materials and dimethyl formamide is used as the solvent. Preparation steps are as follows: the solvent dimethyl formamide and the raw materials 4,4-diphenylsulfone are sequentially added to three flasks to be stirred until dissolved, then nitrogen gas is input to the flasks; when the flasks are slowly heated to 100 or 150 DEG C, a certain amount of gamma-chloropropthyl type silane are dropped into the flasks, after that, the liquid in the flasks is reflowed to 5 - 15 h at the right temperature; then, the coupling agent can be produced after decompression distillation and the removal of the solvent. The introduction of diphenylsulfone reduces the polarity of active amido, so that the coupling agent is provided with a low dielectric loss angle tangent value. When the coupling agent is used for glass fiber-reinforced epoxy resin or cyanate ester resin and other thermosetting resin composite materials, the dielectric performance of such composite materials can be increased, therefore, the coupling agent is widely applied to wave-transparent composite material field, such as antennas and radomes.
Owner:NORTHWESTERN POLYTECHNICAL UNIV

Method for producing curing agent having acidic substituent and unsaturated maleimide group, thermosetting resin composition, prepreg, and laminate

ActiveUS20100173163A1Improve solubilityExcellent adhesion-to-metal foil property and heat resistance and moisture resistanceOrganic chemistrySynthetic resin layered productsSolubilityMetal foil
The invention provides a method for producing a curing agent having an acidic substituent and an unsaturated maleimido group, including reacting, in an organic solvent, a maleimide compound (a) having at least two N-substituted maleimido groups in a molecule thereof with an amine compound (b) having an acidic substituent (represented by formula (I)); a thermosetting resin composition containing the curing agent (A) produced through the method and a compound (B) which is cured with the curing agent, wherein a cured product of the composition has a glass transition temperature of 200° C. or higher; and a prepreg and a laminated sheet produced therefrom. The curing agent produced through the method of the present invention has good solubility in an organic solvent and can provide a thermosetting resin composition exhibiting excellent adhesion-to-metal foil property, heat resistance, moisture resistance, flame retardancy, and copper cladding heat resistance, and low dielectric properties and low dielectric loss tangent. Therefore, the thermosetting resin composition can produce a prepreg or laminated sheet exhibiting excellent performance suitable for a printed wiring board for electronic devices and similar devices.
Owner:RESONAC CORP
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