The present invention relates to a coupling agent containing diphenylsulfone amino-silane and the related preparation method, which is technically characterized in that 4,4-diphenylsulfone and gamma-chloropropthyl type silane are taken as raw materials and dimethyl formamide is used as the solvent. Preparation steps are as follows: the solvent dimethyl formamide and the raw materials 4,4-diphenylsulfone are sequentially added to three flasks to be stirred until dissolved, then nitrogen gas is input to the flasks; when the flasks are slowly heated to 100 or 150 DEG C, a certain amount of gamma-chloropropthyl type silane are dropped into the flasks, after that, the liquid in the flasks is reflowed to 5 - 15 h at the right temperature; then, the coupling agent can be produced after decompression distillation and the removal of the solvent. The introduction of diphenylsulfone reduces the polarity of active amido, so that the coupling agent is provided with a low dielectric loss angle tangent value. When the coupling agent is used for glass fiber-reinforced epoxy resin or cyanate ester resin and other thermosetting resin composite materials, the dielectric performance of such composite materials can be increased, therefore, the coupling agent is widely applied to wave-transparent composite material field, such as antennas and radomes.