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Preparation method of anti-static high-tenacity PP/PA6 composite

A composite material and high toughness technology, which is used in the preparation of methods, synergistically compatibilized and toughened PP/PA6 composite materials, can solve problems such as poor compatibility, and achieve high fluidity, high ionic conductivity, and good antistatic properties. Effect

Active Publication Date: 2017-09-08
HENAN INST OF ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem to be solved by the present invention is to provide a preparation method of antistatic high toughness PP / PA6 composite material for the simple blend of PP and PA6, which has poor compatibility. Adding Synergistic Compatibility and Toughening Agent Ionic Liquid and Fumed Nano Silica to Obtain an Antistatic High Toughness PP / PA6 Composite

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] The preparation method of the antistatic and high-toughness PP / PA6 composite material of this embodiment includes the following steps:

[0017] Synergistic compatibilizing and toughening agent is added to PP and PA6 composite material, and PP / PA6 composite is obtained by melt blending injection molding. The total mass fraction of PP and PA6 in the mixed system is 95%, and the quality of the synergistic compatibilizing and toughening agent The fraction is 5%, the weight ratio of PA6 to PP is 1:3, the synergistic compatibilizing and toughening agent is ionic liquid and fumed nano silica, and the ionic liquid is 1-allyl-3-methyl chloride The mass fraction of base imidazole is 4.9%, and the mass fraction of fumed nano-silica is 0.1%. The melt blending injection molding process conditions are as follows: the screw speed is 25 r / min, and the feed zone temperature is set to 170 o C, the temperature of the plasticizing section is 210 o C, the melting section temperature is 220 o C,...

Embodiment 2

[0020] The preparation method of the antistatic and high-toughness PP / PA6 composite material of this embodiment includes the following steps:

[0021] Synergistic compatibilizing and toughening agent is added to PP and PA6 composite material, and PP / PA6 composite is obtained by melt blending injection molding. The total mass fraction of PP and PA6 in the mixed system is 85%. The quality of the synergistic compatibilizing and toughening agent The fraction is 15%, the weight ratio of PA6 to PP is 1:9, the synergistic compatibilizing and toughening agent is ionic liquid and fumed nano silica, and the ionic liquid is 1-butyl-3-methyl chloride The mass fraction of imidazole is 10%, and the mass fraction of fumed nano-silica is 5%; the melt blending injection molding process conditions are as follows: the screw speed is 25 r / min, and the feed zone temperature is set to 165 o C, the temperature of the plasticizing section is 200 o C, the melting section temperature is 210 o C, and then u...

Embodiment 3

[0024] The preparation method of the antistatic and high-toughness PP / PA6 composite material of this embodiment includes the following steps:

[0025] Synergistic compatibilizing and toughening agent is added to PP and PA6 composites, and PP / PA6 composites are obtained by melt blending injection molding. The total mass fraction of PP and PA6 in the mixed system is 80%. The quality of the synergistic compatibilizing and toughening agent The fraction is 20%, the weight ratio of PA6 to PP is 2:3, the synergistic compatibilizing and toughening agent is ionic liquid and fumed nano silica, and the ionic liquid is 1-dodecyl-3-chloride The mass fraction of methylimidazole is 15%, and the mass fraction of fumed nano-silica is 5%; the melt blending injection molding process conditions are as follows: the screw speed is 25 r / min, and the feed zone temperature is set to 160 o C, the temperature of the plasticizing section is 190 o C, the melting section temperature is 200 o C, then use a micr...

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Abstract

The invention discloses an anti-static high-tenacity PP / PA6 composite. A preparation method of the anti-static high-tenacity PP / PA6 composite comprises the steps that a synergic compatibilization and toughening agent is added into a PP and PA6 composite, melt blending injection molding is adopted for obtaining the PP / PA6 composite, wherein in the mixed system, the total mass percentage of PP and PA6 is 80-95%, the mass percentage of the synergic compatibilization and toughening agent is 5-20%, the weight ratio of PA6 to PP is 1:9-2:3, the synergic compatibilization and toughening agent is prepared from 4.9-15% of ionic liquid and 0.1-5% of fumed nano-silica, positive ions in the ionic liquid are imidazoles or pyridines, and the negative ions are chloride ions. The elongation at break of the anti-static high-tenacity PP / PA6 composite prepared through the method is 250-800%, and the surface resistance of the anti-static high-tenacity PP / PA6 composite is 105-108 omega.

Description

Technical field [0001] The invention belongs to the field of polymer materials, and specifically relates to a preparation method of a method for synergistic compatibilization and toughening PP / PA6 composite material. Background technique [0002] Blending modification is a simple and effective modification method. Blending PP with other plastics can prepare polymer alloys with the properties of these polymers. However, PA6 is a strongly polar polymer, and PP is a weakly polar polymer. The solubility parameters of the two are quite different and they are not thermodynamically compatible. Therefore, a simple blend of PP and PA6 exists. This is the disadvantage of poor compatibility. [0003] At present, the commonly used compatibilizers are divided into three main categories according to the main chain structure: the first category is the graft copolymer of rubber (such as ethylene propylene rubber) and polar monomer (such as maleic anhydride); the second is Graft copolymers of PP ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L77/02C08K3/36C08K5/3445C08K5/3432
CPCC08K2201/011C08L23/12C08L2201/04C08L77/02C08K3/36C08K5/3445C08K5/3432
Inventor 田银彩于翔王明迟长龙张浩鹏李根宇
Owner HENAN INST OF ENG
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