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Method for preparing chemical sand solidification agent

A sand-fixing agent and chemical technology, which is applied in the field of preparation of chemical sand-fixing agents, can solve the problems of poor water retention and sand-fixing ability, and achieve the effect of strong water retention and enhanced sand-fixing effect

Inactive Publication Date: 2017-09-08
闫博文
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem mainly solved by the present invention: Aiming at the problems of poor water retention and sand-fixing ability of existing sand-fixing agents, a preparation method of chemical sand-fixing agents is provided

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0024] Weigh 40g itaconic acid, 15g acrylic acid and 200mL absolute ethanol into the flask, place the flask in a water bath, control the temperature of the water bath to 60°C, then add 0.1g ammonium persulfate to the flask, keep stirring for 2h, After the reaction is completed, the material in the flask is placed in a rotary evaporator, and the concentrated solution is concentrated by rotary evaporation for 30min to obtain a concentrated solution containing itaconic acid acrylic acid copolymer, and the concentrated solution containing itaconic acid acrylic acid copolymer is placed in the flask, Then 200 mL of thionyl chloride was added to the flask, and the flask was moved into a constant temperature digital display magnetic stirrer, and the reaction was stirred for 1 h at a temperature of 80 °C and a rotation speed of 300 r / min. After the reaction was completed, the product was placed in a rotating In an evaporator, rotary evaporation is concentrated to dryness to obtain a dry...

example 2

[0026]Weigh 50g of itaconic acid, 20g of acrylic acid and 300mL of absolute ethanol into the flask, place the flask in a water bath, control the temperature of the water bath to be 70°C, then add 0.3g of dicumyl peroxide to the flask, keep stirring Reaction for 3h, after the reaction is completed, the material in the flask is placed in a rotary evaporator, and concentrated by rotary evaporation for 40min to obtain a concentrated solution containing itaconic acid acrylic acid copolymer, and the concentrated solution containing itaconic acid acrylic acid copolymer is placed in In the flask, add 300 mL of thionyl chloride to the flask, move the flask into a constant temperature digital display magnetic stirrer, and stir the reaction for 2 hours at a temperature of 90 ° C and a rotation speed of 400 r / min. Placed in a rotary evaporator, and concentrated to dryness by rotary evaporation to obtain a dried product containing itaconic chloride acryloyl chloride copolymer, and 300 mL of...

example 3

[0028] Weigh 45g of itaconic acid, 18g of acrylic acid and 250mL of absolute ethanol into the flask, place the flask in a water bath, control the temperature of the water bath to be 65°C, then add 0.2g of benzoyl peroxide to the flask, keep stirring for the reaction 2.5h, after the reaction is over, place the material in the flask in a rotary evaporator, and rotate and concentrate for 35min to obtain a concentrated solution containing itaconic acid-acrylic acid copolymer, and the concentrated solution containing itaconic acid-acrylic acid copolymer is placed in In the flask, add 250 mL of thionyl chloride to the flask, move the flask into a constant temperature digital display magnetic stirrer, and stir the reaction for 1.5 h at a temperature of 85 °C and a rotation speed of 350 r / min. The product was placed in a rotary evaporator, and concentrated to dryness by rotary evaporation to obtain a dried product containing itaconic acid chloride acryloyl chloride copolymer, and 250 m...

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Abstract

The invention discloses a preparation method of a chemical sand-fixing agent, which belongs to the technical field of environmental treatment. The present invention uses carboxyl-containing itaconic acid and acrylic acid as monomers to polymerize to obtain a polymer containing multiple carboxyl groups. The carboxyl group in itaconic acid-acrylic acid copolymer is a hydrophilic group, which can make the polymer water-retaining properties, and then use thionyl chloride to react with some carboxyl groups to generate acid chloride groups, and the acid chloride groups react with the amino groups of aminoguanidine to obtain polymers containing amino groups and carboxyl groups, thereby introducing more hydrophilic groups and making polymers It has stronger water retention, and the hydrophilic groups in the polymer can interact with Si‑OH, Ca2+, etc. on the surface of sand particles through physical and chemical interactions such as crosslinking and adsorption to make adjacent loose fine sand particles interact with each other through polymer chains. Linking, and then achieving the effect of sand fixation, the alumina in kaolin can form a gel-like polymer through cross-linking with Si-OH on the surface of sand grains under the action of calcium oxide, and can form a solidified layer on the surface of sand grains, thereby achieving The purpose of sand fixation.

Description

technical field [0001] The invention discloses a preparation method of a chemical sand-fixing agent, and belongs to the technical field of environmental treatment. Background technique [0002] There are three methods of sand fixation, namely mechanical sand fixation, plant sand fixation and chemical sand fixation. Mechanical sand fixation, such as setting up sand barriers, grass squares, etc., is effective, but the investment is large, and it is not suitable for large-scale use; Plant sand fixation: It is mainly to plant shelter forests on the edge or hinterland of the desert or to carry out plant crusting on the sand surface to reduce The wind speed in the desert can prevent sand from rising in the desert, and then achieve the purpose of sand fixation, but it is time-consuming and labor-intensive; chemical sand fixation is the most effective and convenient method among the three. film, and then play the role of sand surface fixation. [0003] At present, the commonly use...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/40C08F222/02C08F220/06C08F8/32C08F8/18
CPCC09K17/40C08F8/18C08F8/32C08F222/02C09K2105/00
Inventor 闫博文王维
Owner 闫博文
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