Ferric-oxide nano material and application thereof used as tumor-drug targeting carriers
A technology of iron oxide nanometer and ferric chloride, which is applied in the field of biomaterials, can solve the problem that drugs cannot be delivered specifically to tumor cells, and achieve high safety effects
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Embodiment 1
[0020] Example 1 Preparation of Iron Oxide Nanomaterials
[0021] Prepared by the following method:
[0022] First dissolve ferric chloride hexahydrate, polyvinylpyrrolidone and bis-(3-methyl-1-imidazole) butylene bisulphate in distilled water, then transfer to a reactor with a polytetrafluoroethylene liner for hydrothermal Reaction, the reaction temperature is 200°C, the reaction time is 20h, and finally centrifuged, washed, dried, calcined, and ground; wherein, the molar concentration of ferric chloride hexahydrate is 0.035mol / L, and the concentration of polyvinylpyrrolidone is 10g / L. The molar concentration of bis-(3-methyl-1-imidazole) butylene bissulfate is 0.015mol / L.
[0023] Among them, washing with ethanol and deionized water alternately 4 times, each washing volume is 10 times the weight of the precipitate; the temperature during drying is 70°C, and the drying time is 10h; the calcination temperature is 500°C, and the calcination time is 4h.
[0024] figure 1 It i...
Embodiment 2
[0025] Example 2 Preparation of Iron Oxide Nanomaterials
[0026] Prepared by the following method:
[0027] First dissolve ferric chloride hexahydrate, polyvinylpyrrolidone and bis-(3-methyl-1-imidazole) butylene bisulphate in distilled water, then transfer to a reactor with a polytetrafluoroethylene liner for hydrothermal Reaction, the reaction temperature is 180°C, the reaction time is 22h, and finally centrifuged, washed, dried, calcined, and ground; wherein, the molar concentration of ferric chloride hexahydrate is 0.03mol / L, and the concentration of polyvinylpyrrolidone is 8g / L. The molar concentration of bis-(3-methyl-1-imidazole) butylene bisulphate is 0.01 mol / L.
[0028] Among them, washing with ethanol and deionized water alternately for 3 times, each washing volume is 15 times the weight of the precipitate; the temperature during drying is 60°C, and the drying time is 12h; the calcination temperature is 450°C, and the calcination time is 5h.
[0029] The TEM tran...
Embodiment 3
[0030] Example 3 Preparation of Iron Oxide Nanomaterials
[0031] Prepared by the following method:
[0032] First dissolve ferric chloride hexahydrate, polyvinylpyrrolidone and bis-(3-methyl-1-imidazole) butylene bisulphate in distilled water, then transfer to a reactor with a polytetrafluoroethylene liner for hydrothermal Reaction, the reaction temperature is 220°C, the reaction time is 18h, and finally centrifuged, washed, dried, calcined, and ground; wherein, the molar concentration of ferric chloride hexahydrate is 0.04mol / L, and the concentration of polyvinylpyrrolidone is 12g / L. The molar concentration of bis-(3-methyl-1-imidazole) butylene bissulfate is 0.02 mol / L.
[0033] Among them, washing with ethanol and deionized water alternately 5 times, each washing volume is 5 times the weight of the precipitate; the temperature during drying is 80°C, and the drying time is 8h; the calcination temperature is 550°C, and the calcination time is 3h.
[0034] The TEM transmiss...
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