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Dual-phase Mg-Li-Zn-Y magnesium-lithium alloy enhanced by effectively utilizing rare earth element Y and preparation method

A rare earth element, magnesium-lithium alloy technology, applied in the field of magnesium-lithium alloys, can solve the problems of low absolute strength, large quasi-crystalline phase volume fraction, low-density strength and other problems of magnesium-lithium alloys, and achieve low cost, good plasticity, and stress concentration elimination Effect

Inactive Publication Date: 2018-01-05
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The object of the present invention is to provide a kind of effectively utilizing rare earth element Y to strengthen two-phase Mg-Li-Zn-Y magnesium-lithium alloy and preparation method, under the premise of certain Y content, by reasonable selection Zn / Y ratio in the alloy, make the introduction When the volume fraction of the quasicrystalline phase reaches the maximum in the magnesium-lithium alloy matrix, a quasicrystal-strengthened dual-phase Mg-Li-Zn-Y magnesium-lithium alloy with ultra-low density, high strength, and good plasticity is prepared to solve the absolute problem of magnesium-lithium alloys. Problems such as low strength

Method used

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  • Dual-phase Mg-Li-Zn-Y magnesium-lithium alloy enhanced by effectively utilizing rare earth element Y and preparation method
  • Dual-phase Mg-Li-Zn-Y magnesium-lithium alloy enhanced by effectively utilizing rare earth element Y and preparation method
  • Dual-phase Mg-Li-Zn-Y magnesium-lithium alloy enhanced by effectively utilizing rare earth element Y and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Ⅰ), the composition of the magnesium-lithium alloy used

[0025] Use quasi-crystal strengthened dual-phase Mg-Li-Zn-Y alloy, its chemical composition (weight percentage composition) is: lithium content is 8%; Zinc content is 3%; Yttrium content is 0.5%; Magnesium balance; Alloy The Zn / Y ratio is 6.

[0026] Ⅱ), alloy smelting

[0027] The alloy is smelted in a vacuum smelting furnace under the protection of argon, and after being kept at 770°C for 4 hours, it is cast in the furnace.

[0028] Ⅲ), homogenization treatment

[0029] The as-cast quasicrystalline strengthened dual-phase Mg-Li-Zn-Y alloy was kept at 400°C for 8 hours, and tightly wrapped with aluminum foil to prevent the alloy from burning due to high temperature oxidation.

[0030] Ⅳ), plastic deformation

[0031] The homogenized alloy was hot-extruded at 350°C with an extrusion ratio of 10.

[0032] Ⅴ) Microstructure characterization

[0033] The preparation process of the sample for tissue observation...

Embodiment 2

[0037] Ⅰ), the composition of the magnesium-lithium alloy used

[0038] Use quasi-crystal strengthened dual-phase Mg-Li-Zn-Y alloy, its chemical composition (weight percentage composition) is: lithium content is 8%; Zinc content is 6%; Yttrium content is 1%; Magnesium balance; Alloy The Zn / Y ratio is 6.

[0039] Ⅱ), alloy smelting

[0040] Same as Example 1.

[0041] Ⅲ), homogenization treatment

[0042] Same as Example 1.

[0043] Ⅳ), plastic deformation

[0044] Same as Example 1.

[0045] Ⅴ) Microstructure characterization

[0046] The tissue observation method is the same as in Example 1. Optical observation results show that the volume fraction of the quasi-crystalline phase formed in the sample of Example 2 is 8.3%, and the corresponding photo is shown in Figure 1(b).

[0047] Ⅵ), mechanical performance test

[0048] Tensile sample processing and tensile performance testing methods are the same as in Example 1. The measured yield and tensile strengths of the al...

Embodiment 3

[0050] Ⅰ), the composition of the magnesium-lithium alloy used

[0051] Use quasi-crystal strengthened dual-phase Mg-Li-Zn-Y alloy, its chemical composition (weight percentage composition) is: lithium content is 8%; Zinc content is 8%; Yttrium content is 1%; Magnesium balance; Alloy The Zn / Y ratio was 8.

[0052] Ⅱ), alloy smelting

[0053] Same as Example 1.

[0054] Ⅲ), homogenization treatment

[0055]Same as Example 1.

[0056] Ⅳ), plastic deformation

[0057] Same as Example 1.

[0058] Ⅴ) Microstructure characterization

[0059] The tissue observation method is the same as in Example 1. Optical observation results show that the volume fraction of the quasi-crystalline phase formed in the sample of Example 3 is 12.5%, and the corresponding photo is shown in Figure 1(c).

[0060] Ⅵ), mechanical performance test

[0061] Tensile sample processing and tensile performance testing methods are the same as in Example 1. The measured yield and tensile strengths of the a...

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Abstract

The invention relates to the field of magnesium-lithium alloys, in particular to a dual-phase Mg-Li-Zn-Y magnesium-lithium alloy enhanced by effectively utilizing a rare earth element Y and a preparation method. The problem that the absolute strength of the magnesium-lithium alloy is low is solved. Under the premise that the Y content is certain, the ratio (Zn / Y = 5-10) of zinc to yttrium in the alloy is reasonably selected, so that volume fraction of a quasicrystalline phase brought into a magnesium-lithium alloy base body reaches the maximum, and the dual-phase Mg-Li-Zn-Y alloy with the ultra-low density, high strength and good plasticity is prepared. The components of the magnesium alloy material comprise 5-20% of Li, 3-20% of Zn, 0.5-5% of Y and the balance Mg, and all the percentagesare percentages by weight. The dual-phase Mg-Li-Zn-Y magnesium-lithium alloy is made into a product through alloy smelting and subsequent hot extrusion and machining deformation, and the machining technology of the dual-phase Mg-Li-Zn-Y magnesium-lithium alloy is easy and convenient to operate. According to the dual-phase Mg-Li-Zn-Y magnesium-lithium alloy enhanced by effectively utilizing the rare earth element Y and the preparation method, the tensile strength of the material is sigma b=200-350 MPa, the yield strength is sigma 0.2=140-220 MPa, the ductility is delta=10-40%, and the density is 1.58-1.85 g / cm<3>.

Description

technical field [0001] The invention relates to the field of magnesium-lithium alloys, in particular to a dual-phase Mg-Li-Zn-Y magnesium-lithium alloy strengthened by effectively utilizing rare earth element Y and a preparation method thereof. Background technique [0002] So far, magnesium-lithium alloy is the lightest metal structure material in engineering applications, with a density of 1.35-1.65g / cm 3 Among them, it has low density, high specific strength and specific stiffness, strong cold and hot deformation ability, no obvious anisotropy and low temperature performance, strong resistance to high-energy particle penetration, good electromagnetic shielding performance, good damping performance, and machinability. Excellent and other advantages make magnesium-lithium alloys have potential application prospects in high-tech fields such as aerospace and automobiles. However, compared with traditional magnesium alloys, the absolute strength of magnesium-lithium alloys is...

Claims

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Application Information

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IPC IPC(8): C22C23/04C22C23/00C22C1/02C22F1/06
Inventor 许道奎韩恩厚
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI