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Composite piezoelectric material for cable external pressure detection and manufacturing method thereof

A piezoelectric material, external pressure technology, applied in the material selection of piezoelectric devices or electrostrictive devices, the manufacture/assembly of piezoelectric/electrostrictive devices, insulated cables, etc. It is not easy to solve problems such as high brittleness, etc., and achieves the effect of low Curie temperature, superior piezoelectric performance and good bonding force.

Active Publication Date: 2020-12-15
ANHUI HUALING CABLE GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

2. The bending radius exceeds the recommended value: When the cable is bent and its bending radius is much smaller than the bending radius recommended by the manufacturer, the internal components of the cable are prone to mechanical damage
3. Kinks: Kinks are initially caused by knot loops, most often when the cable is "pulled" from a fixed reel, and cannot be easily undone
Kinking can cause permanent "weakness"
[0004] In fact, we can find that these three failure principles can be prevented by setting a long-distance linear pressure detection device on the surface of the cable or finding the failure point after failure. The limitation of temperature and almost all sensitive piezoelectric materials are crystals, which are brittle and have a small expansion coefficient, which makes it completely unmatched to the environment in which cables are used.
The surface of the cable is always exposed to the outside world, and is subject to many and irregular mechanical forces such as wind. Therefore, conventional piezoelectric materials that cannot cope with acid, alkali, salt spray, atmospheric corrosion, low strength, and impact resistance in the prior art cannot be realized at all. Real-time monitoring of cable surface force

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A composite piezoelectric material for cable external pressure detection, made of the following raw materials in parts by weight: polyvinylidene fluoride solution containing solute 30, anti-vibration PbTiO modified by Ca and Co 3 Crystal 5 parts, Pb(Zr 0.3 Ti 0.7 )O 3 3 parts, 5 parts of graphene, 1 part of sulfonamide adhesion promoter, Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 10 parts, 15 parts of aluminum-chromium master alloy ingot.

[0032] The manufacturing method of the composite piezoelectric material comprises the following steps:

[0033] 1) Preparation before production

[0034] ① Graphene, modified PbTiO 3 , Pb(Zr 0.3 Ti 0.7 )O 3 Grinding to a powder with a particle size of 10 μm, and mixing evenly to obtain a mixed powder;

[0035] ② Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 Make a crystal belt with a thickness of 0.1mm and a width of 1.2mm;

[0036] ③ mixing the sulfonylami...

Embodiment 2

[0054] The whole is consistent with Example 1, the difference is:

[0055] A composite piezoelectric material for cable external pressure detection, made of the following raw materials in parts by weight: polyvinylidene fluoride solution containing 35 parts of solute, anti-vibration PbTiO modified by Ca and Co 3 Crystal 5 parts, Pb(Zr 0.3 Ti 0.7 )O 3 2 parts, 3 parts of graphene, 0.5 parts of sulfonamide adhesion promoter, Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 8 parts, 10 parts of aluminum-chromium master alloy ingot.

[0056] The manufacturing method of the composite piezoelectric material comprises the following steps:

[0057] 1) Preparation before production

[0058] ① Graphene, modified PbTiO 3 , Pb(Zr 0.3 Ti 0.7 )O 3 Grinding to a powder with a particle size of 20 μm, and mixing evenly to obtain a mixed powder;

[0059] ② Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 Make a crystal belt wi...

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Abstract

The invention relates to a composite piezoelectric material for cable external pressure detection and a manufacturing method thereof. The composite piezoelectric material is made of the following raw materials in parts by weight: polyvinylidene fluoride solution containing 30-35 parts of solute, (modified PbTiO 3 )3-5 parts, [Pb(Zr0.3Ti0.7)O 3 ] 2 parts-3 parts, 3 parts-5 parts of graphene, 0.5 part-1 part of sulfonylamino adhesion promoter, {Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3}8-10 parts, 10-15 parts of aluminum-chromium master alloy ingot. The composite piezoelectric material for cable external pressure detection of the present invention is resistant to acid, alkali, salt spray, atmospheric corrosion, high temperature resistance, good mechanical properties and strong impact resistance.

Description

technical field [0001] The invention relates to the field of electrical materials, in particular to a composite piezoelectric material for cable external pressure detection and a manufacturing method thereof. Background technique [0002] Cables are used to transmit electric (magnetic) energy, information and wire products that realize electromagnetic energy conversion. They play an extremely important role in modern industry and people's daily life. Therefore, the frequent failure of cables will also bring great negative effects. impact, and as modern cables are more widely used, failure cases abound. [0003] Although it seems that there are many reasons for cable failure, in fact, more than 95% of cables fail due to the following three reasons: 1. Mechanical damage: the outer sheath of the cable is often torn or crushed, and there is no cracked sheath. There are burrs or abrasion marks on the surface of the sheath; there are no signs of damage on the outside of the sheat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L41/18H01L41/187H01L41/193H01L41/337H01L41/37H01B7/18H01B7/28H01B7/29H01B7/32H01B7/42H10N30/85H10N30/086H10N30/092H10N30/853H10N30/857
CPCH01B7/18H01B7/28H01B7/2806H01B7/29H01B7/326H01B7/428H10N30/852H10N30/8554H10N30/857H10N30/086H10N30/092
Inventor 姜源聂祝婷黄辉张敬敏
Owner ANHUI HUALING CABLE GRP
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