Composite piezoelectric material for cable external pressure detection and manufacturing method thereof
A piezoelectric material, external pressure technology, applied in the material selection of piezoelectric devices or electrostrictive devices, the manufacture/assembly of piezoelectric/electrostrictive devices, insulated cables, etc. It is not easy to solve problems such as high brittleness, etc., and achieves the effect of low Curie temperature, superior piezoelectric performance and good bonding force.
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Embodiment 1
[0031] A composite piezoelectric material for cable external pressure detection, made of the following raw materials in parts by weight: polyvinylidene fluoride solution containing solute 30, anti-vibration PbTiO modified by Ca and Co 3 Crystal 5 parts, Pb(Zr 0.3 Ti 0.7 )O 3 3 parts, 5 parts of graphene, 1 part of sulfonamide adhesion promoter, Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 10 parts, 15 parts of aluminum-chromium master alloy ingot.
[0032] The manufacturing method of the composite piezoelectric material comprises the following steps:
[0033] 1) Preparation before production
[0034] ① Graphene, modified PbTiO 3 , Pb(Zr 0.3 Ti 0.7 )O 3 Grinding to a powder with a particle size of 10 μm, and mixing evenly to obtain a mixed powder;
[0035] ② Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 Make a crystal belt with a thickness of 0.1mm and a width of 1.2mm;
[0036] ③ mixing the sulfonylami...
Embodiment 2
[0054] The whole is consistent with Example 1, the difference is:
[0055] A composite piezoelectric material for cable external pressure detection, made of the following raw materials in parts by weight: polyvinylidene fluoride solution containing 35 parts of solute, anti-vibration PbTiO modified by Ca and Co 3 Crystal 5 parts, Pb(Zr 0.3 Ti 0.7 )O 3 2 parts, 3 parts of graphene, 0.5 parts of sulfonamide adhesion promoter, Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 8 parts, 10 parts of aluminum-chromium master alloy ingot.
[0056] The manufacturing method of the composite piezoelectric material comprises the following steps:
[0057] 1) Preparation before production
[0058] ① Graphene, modified PbTiO 3 , Pb(Zr 0.3 Ti 0.7 )O 3 Grinding to a powder with a particle size of 20 μm, and mixing evenly to obtain a mixed powder;
[0059] ② Pb 0.95 Cr 0.02 Ca 0.03 [(Ni 1 / 3 Nb 2 / 3 ) 0.5 · Zr 0.2 · Ti 0.3 ]O 3 Make a crystal belt wi...
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