Method for catalyzing biological leaching of copper cobalt ore through silver ions
A technology of bioleaching and copper sulfide, which is applied in the direction of improving process efficiency, can solve the problems of rare reports on the impact of cobalt-containing minerals on bioleaching, and achieve good application prospects, low production costs, and low environmental pollution.
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Embodiment 1
[0018] Inoculate the bacterium liquid containing acidic Thiobacillus ferrooxidans into the 9K medium to prepare the bacterium-containing culture medium, and the inoculum volume ratio of the bacterium liquid to the 9K medium is 1:5. Use a sulfuric acid solution with a concentration of 2N to adjust the pH value of the culture solution to 1.8, then place it in a constant temperature shaking box, and cultivate it at a temperature of 30-40°C and a rotation speed of 160rpm until the potential of the bacterial solution is 580-650mV , to obtain culture broth.
[0019] In the sulfur-copper-cobalt ore powder, the part with a particle size of ≤75 μm accounts for 80% of the total weight of the ore powder, and the mass percentage of cobalt in the ore powder is 0.1%. The sulfur copper cobalt ore powder is added into the culture liquid to make a pulp, and the mass concentration of the pulp is 5%. Then add silver nitrate solution, the amount added is Ag + The concentration of ions in the pu...
Embodiment 2
[0022] Inoculate the bacterium solution containing acidic Thiobacillus ferrooxidans into the 9K medium to prepare the bacterium-containing culture solution, and the inoculum volume ratio of the bacteria solution to the 9K medium is 1:10. Use a sulfuric acid solution with a concentration of 2N to adjust the pH value of the culture solution to 1.6, then place it in a constant temperature shaking box, and cultivate it at a temperature of 30-40°C and a rotation speed of 200rpm until the potential of the bacterial solution is 580-650mV , to obtain culture broth.
[0023] In the sulfur-copper-cobalt ore powder, the part with a particle size of ≤75 μm accounts for 90% of the total weight of the ore powder, and the mass percentage of cobalt in the ore powder is 1%. The sulfur copper cobalt ore powder is added into the culture liquid to make a pulp, and the mass concentration of the pulp is 10%. Then add silver nitrate solution, the amount added is Ag + The concentration of ions in t...
Embodiment 3
[0026] Inoculate the bacterium solution containing acidic Thiobacillus ferrooxidans into the 9K medium to prepare the bacterium-containing culture solution, and the inoculum volume ratio of the bacteria solution to the 9K medium is 1:8. Use a sulfuric acid solution with a concentration of 3N to adjust the pH value of the culture solution to 1.2, then place it in a constant temperature shaking box, and cultivate it at a temperature of 30-40°C and a rotation speed of 180rpm until the potential of the bacterial solution is 580-650mV , to obtain culture broth.
[0027] In the sulfur-copper-cobalt ore powder, the part with a particle size less than or equal to 75 μm accounts for 70% of the total weight of the ore powder, and the mass percentage of cobalt in the ore powder is 0.5%. The sulfur copper cobalt ore powder is added into the culture liquid to make a pulp, and the mass concentration of the pulp is 15%. Then add silver nitrate solution, the amount added is Ag + The concent...
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