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Method for extracting and separating organic matters in carbon-containing residues of coal

A technology for organic matter and residues, which is applied in the field of extraction and separation of coal carbon residues, can solve the problems of long extraction time, high energy consumption, and low extraction efficiency, and achieve the effects of improved extraction efficiency, simple process flow, and low boiling point

Inactive Publication Date: 2018-03-30
TAIYUAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a method for extracting and separating organic matter in coal carbonaceous residues, which solves the technical problems of low extraction efficiency, high energy consumption and long extraction time in the prior art

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The ethyl acetate and the coal tar residue produced in the coking plant were mixed in an extraction device at a ratio of 1:10kg / L to obtain a mixture; the resulting mixture was subjected to ultrasonic, microwave, and ultraviolet light synergistic extraction, with an ultrasonic power of 600W and a microwave power of 100W, UV intensity 100µW·cm -2 , the extraction time is 2min. After the extraction is completed, the mixture is quickly separated by centrifugal equipment to obtain raffinate and extract; the extract obtained after separation is distilled in a distillation device to obtain the extractant and coal carbon-containing residue organic matter, and the obtained extractant can be repeated The yield of the obtained extract can reach 19.82%.

Embodiment 2

[0024] Put ethyl acetate and Shenhua coal direct liquefaction residue in an extraction device at a ratio of 1:5 kg / L for mixing to obtain a mixture; the resulting mixture is subjected to ultrasonic microwave ultraviolet light co-extraction, the ultrasonic power is 500W, and the microwave power is 300W , UV intensity 500 µW·cm -2 , the extraction time is 5min. After the extraction is completed, the mixture is quickly separated by centrifugal equipment to obtain raffinate and extract; the extract obtained after separation is distilled in a distillation device to obtain the extractant and coal carbon-containing residue organic matter, and the obtained extractant can be repeated The yield of the obtained extract can reach 11.24%.

Embodiment 3

[0026] The ethyl acetate and the coal tar residue produced by the coking plant were mixed in an extraction device at a ratio of 1:5 kg / L to obtain a mixture; the obtained mixture was subjected to ultrasonic microwave ultraviolet light synergistic extraction, the ultrasonic power was 500W, and the microwave power 200W, UV light intensity 1000µW·cm -2 , the extraction time is 2min. After the extraction is completed, the mixture is quickly separated by centrifugal equipment to obtain raffinate and extract; the extract obtained after separation is distilled in a distillation device to obtain the extractant and coal carbon-containing residue organic matter, and the obtained extractant can be repeated The yield of the obtained extract can reach 19.10%.

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PUM

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Abstract

The invention relates to a method for extracting and separating organic matters in carbon-containing residues of coal and aims at solving the technical problem of low extracting efficiency in the existing method for extracting and separating the organic matters in the carbon-containing residues of the coal by a solvent. The invention is characterized in that the method comprises the following steps of selecting an organic solvent with microwave absorption and the boiling point being lower than 100 DEG C as an extracting agent, and under the synergistic and auxiliary action of ultrasonic, microwave and ultraviolet radiation, separating the organic matters and the residues in the carbon-containing residues of the coal. The method has the advantages that by utilization of the principle of thesynergistic action of the ultrasonic, the microwave and the ultraviolet radiation, the whole time of the extraction process is greatly shortened and the extraction efficiency is also improved to a great extent.

Description

technical field [0001] The invention relates to a method for extracting and separating coal carbon-containing residues, in particular to a method for extracting and separating organic compounds in coal carbon-containing residues under the synergistic auxiliary conditions of ultrasonic, microwave, and ultraviolet light. Background technique [0002] There are many coal chemical enterprises in my country, which provide indispensable products such as coke, tar and synthesis gas for the development of other industries. However, when these enterprises are producing products, due to problems such as imperfect technology and management, they will inevitably produce a large amount of waste residue. For example, in coal gasification, coal coking and direct coal liquefaction, a large amount of coal carbon residues such as coal tar residue and coal direct liquefaction residue will be produced. These waste residues contain more organic matter mainly aromatic hydrocarbons, if these wast...

Claims

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Application Information

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IPC IPC(8): B01D11/02B01J19/12C10C1/18
CPCB01D11/0265B01J19/123B01J19/126C10C1/18
Inventor 王玉高申峻和明豪刘刚牛艳霞盛清涛
Owner TAIYUAN UNIV OF TECH