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Composite anode material, preparation method and application thereof

A negative electrode material and raw material technology, applied in the field of composite negative electrode materials and its preparation, can solve the problems of expensive graphite and graphene, poor effect of graphite tailings in batteries, and low cost of graphite tailings, and achieve low cost and excellent battery life. Chemical properties, the effect of improving the reversible specific capacity

Active Publication Date: 2018-03-30
吉林聚能新型炭材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Graphene is also getting more and more attention, but graphite and graphene are expensive and their applications are limited
Graphite tailings are low in cost, occupy a large amount of ground, damage the land, and are prone to landslides and mudslides. However, the effect of graphite tailings in batteries is too poor to be used directly, and they need to be treated.

Method used

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  • Composite anode material, preparation method and application thereof
  • Composite anode material, preparation method and application thereof

Examples

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Embodiment 1

[0021] In the embodiment of the present invention, a composite negative electrode material includes the following raw materials: 31 kg of graphite tailings, 3 kg of yttrium nitrate, 13 kg of chloroplatinic acid, 5 kg of epoxy resin E51, 3 kg of diethylenetriamine, and 10 kg of graphite.

[0022] Mix chloroplatinic acid with 7.5 times its mass of deionized water to prepare a chloroplatinic acid solution; mix diethylenetriamine with 4.5 times its mass of deionized water to prepare a diethylenetriamine solution. Mix and grind graphite tailings and yttrium nitrate, pass through a 100-mesh sieve, then mix with chloroplatinic acid solution, heat up to 58°C and stir at this temperature for 50 minutes, then heat up to 120°C and seal and stir at this temperature for 25 minutes ; The stirring speed after mixing with the chloroplatinic acid solution is 250r / min. Then add diethylenetriamine solution, and stir at 80°C for 1.5h, then filter, wash and dry to obtain mixture A; after adding di...

Embodiment 2

[0024] In the embodiment of the present invention, a composite negative electrode material includes the following raw materials: 39kg of graphite tailings, 7kg of yttrium nitrate, 21kg of chloroplatinic acid, 12kg of epoxy resin E51, 7kg of diethylenetriamine, and 20kg of graphite.

[0025] Mix chloroplatinic acid with 8 times its mass of deionized water to prepare a chloroplatinic acid solution; mix diethylenetriamine with 5 times its mass of deionized water to prepare a diethylenetriamine solution. Mix and grind graphite tailings and yttrium nitrate, pass through a 150-mesh sieve, then mix with chloroplatinic acid solution, heat up to 60°C and stir at this temperature for 60 minutes, then heat up to 125°C and seal and stir at this temperature for 30 minutes ; The stirring speed after mixing with the chloroplatinic acid solution is 300r / min. Then add diethylenetriamine solution, and stir at 82°C for 1.8h, then filter, wash, and dry to obtain mixture A; after adding diethylene...

Embodiment 3

[0027] In the embodiment of the present invention, a composite negative electrode material includes the following raw materials: 33kg of graphite tailings, 4kg of yttrium nitrate, 15kg of chloroplatinic acid, 7kg of epoxy resin E51, 4kg of diethylenetriamine, and 12kg of graphite.

[0028] Mix chloroplatinic acid with 8 times its mass of deionized water to prepare a chloroplatinic acid solution; mix diethylenetriamine with 5 times its mass of deionized water to prepare a diethylenetriamine solution. Mix and grind graphite tailings and yttrium nitrate, pass through a 120-mesh sieve, then mix with chloroplatinic acid solution, heat up to 59°C and stir at this temperature for 55 minutes, then heat up to 122°C and seal and stir at this temperature for 30 minutes ; Wherein the stirring speed after mixing with the chloroplatinic acid solution is 280r / min. Then add diethylenetriamine solution, and stir at 81°C for 1.8h, then filter, wash, and dry to obtain mixture A; after adding die...

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Abstract

The invention discloses a composite anode material, a preparation method and application thereof. The composite anode material comprises the following raw materials by weight: 31-39 parts of graphitetailings, 3-7 parts of yttrium nitrate, 13-21 parts of chloroplatinic acid, 5-12 parts of epoxy resin E51, 3-7 parts of diethylenetriamine, and 10-20 parts of graphite. The preparation method includes: mixing graphite tailings with yttrium nitrate and performing grinding, then mixing the product with a chloroplatinic acid solution and conducting heating stirring; then adding a diethylenetriamine solution, performing heating stirring, then conducting pumping filtration, washing and drying, then mixing the product with graphite evenly and conducting crushing, then performing mixing with epoxy resin E51, and carrying out calcination. The anode material prepared by the method provided by the invention has good electrochemical performance, can improve the reversible specific capacity, charge and discharge efficiency, cycle performance stability and rate capability of lithium ion batteries, also can achieve recycling of graphite tailings, and has remarkable effect. The preparation process issimple and is suitable for large-scale industrial production.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a composite negative electrode material and a preparation method and application thereof. Background technique [0002] Compared with traditional lead-acid and nickel-cadmium secondary batteries, lithium-ion batteries have the advantages of high operating voltage, high specific energy, wide operating temperature range, stable discharge, long cycle life, and no memory effect. Energy storage power supplies are widely used in communication equipment, electric tools, aerospace and other fields. [0003] With the continuous advancement of technology, people have put forward higher requirements for lithium-ion batteries. Lithium-ion batteries with high energy density, high rate performance, long cycle life, and high safety factor have gradually become a research hotspot. Graphite is currently the main commercial carbon anode material for lithium-ion batteries. Graphene is also gett...

Claims

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Application Information

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IPC IPC(8): H01M4/58H01M4/583H01M10/0525
CPCH01M4/5825H01M4/583H01M10/0525Y02E60/10
Inventor 姚尧陈海田魏张军
Owner 吉林聚能新型炭材料股份有限公司
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