Composite anode material, preparation method and application thereof
A negative electrode material and raw material technology, applied in the field of composite negative electrode materials and its preparation, can solve the problems of expensive graphite and graphene, poor effect of graphite tailings in batteries, and low cost of graphite tailings, and achieve low cost and excellent battery life. Chemical properties, the effect of improving the reversible specific capacity
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Embodiment 1
[0021] In the embodiment of the present invention, a composite negative electrode material includes the following raw materials: 31 kg of graphite tailings, 3 kg of yttrium nitrate, 13 kg of chloroplatinic acid, 5 kg of epoxy resin E51, 3 kg of diethylenetriamine, and 10 kg of graphite.
[0022] Mix chloroplatinic acid with 7.5 times its mass of deionized water to prepare a chloroplatinic acid solution; mix diethylenetriamine with 4.5 times its mass of deionized water to prepare a diethylenetriamine solution. Mix and grind graphite tailings and yttrium nitrate, pass through a 100-mesh sieve, then mix with chloroplatinic acid solution, heat up to 58°C and stir at this temperature for 50 minutes, then heat up to 120°C and seal and stir at this temperature for 25 minutes ; The stirring speed after mixing with the chloroplatinic acid solution is 250r / min. Then add diethylenetriamine solution, and stir at 80°C for 1.5h, then filter, wash and dry to obtain mixture A; after adding di...
Embodiment 2
[0024] In the embodiment of the present invention, a composite negative electrode material includes the following raw materials: 39kg of graphite tailings, 7kg of yttrium nitrate, 21kg of chloroplatinic acid, 12kg of epoxy resin E51, 7kg of diethylenetriamine, and 20kg of graphite.
[0025] Mix chloroplatinic acid with 8 times its mass of deionized water to prepare a chloroplatinic acid solution; mix diethylenetriamine with 5 times its mass of deionized water to prepare a diethylenetriamine solution. Mix and grind graphite tailings and yttrium nitrate, pass through a 150-mesh sieve, then mix with chloroplatinic acid solution, heat up to 60°C and stir at this temperature for 60 minutes, then heat up to 125°C and seal and stir at this temperature for 30 minutes ; The stirring speed after mixing with the chloroplatinic acid solution is 300r / min. Then add diethylenetriamine solution, and stir at 82°C for 1.8h, then filter, wash, and dry to obtain mixture A; after adding diethylene...
Embodiment 3
[0027] In the embodiment of the present invention, a composite negative electrode material includes the following raw materials: 33kg of graphite tailings, 4kg of yttrium nitrate, 15kg of chloroplatinic acid, 7kg of epoxy resin E51, 4kg of diethylenetriamine, and 12kg of graphite.
[0028] Mix chloroplatinic acid with 8 times its mass of deionized water to prepare a chloroplatinic acid solution; mix diethylenetriamine with 5 times its mass of deionized water to prepare a diethylenetriamine solution. Mix and grind graphite tailings and yttrium nitrate, pass through a 120-mesh sieve, then mix with chloroplatinic acid solution, heat up to 59°C and stir at this temperature for 55 minutes, then heat up to 122°C and seal and stir at this temperature for 30 minutes ; Wherein the stirring speed after mixing with the chloroplatinic acid solution is 280r / min. Then add diethylenetriamine solution, and stir at 81°C for 1.8h, then filter, wash, and dry to obtain mixture A; after adding die...
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