Aluminum-doped spinel manganese-based material and preparation method thereof
A spar manganese-based, aluminum-doped technology, applied in the direction of electrical components, battery electrodes, circuits, etc., can solve the problems of uneven precipitation, inability to achieve uniform mixing of doping elements, etc., and achieve good repeatability and excellent electrochemical performance , Improve the effect of uniformity
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[0029] Example 1
[0030] MnSO 4 ·H 2 O is dissolved in deionized water to form a 2mol / L solution. Anhydrous Na 2 CO 3 As a precipitant, it is dissolved in deionized water to form a 2mol / L solution. Use a peristaltic pump to separate MnSO 4 Solution and Na 2 CO 3 The solution was pumped into the reactor at a flow rate of 0.5 mol / L. Weigh a certain amount of aluminum isopropoxide in proportion, dissolve aluminum isopropoxide and acetylacetone in ethanol at a molar ratio of 1:1, with a concentration of 0.8 mol / L, and use the above aluminum isopropoxide solution to a certain amount Add dropwise to the reactor at a rate of. The pH of the control system is ≈8, the temperature of the system is 50℃, the stirring speed is 600r / min, and the (Mn 0.925 Al 0.075 )CO 3 precipitation. The precipitate is filtered and dried and calcined at 850℃ for 5h to obtain M 2 O 3 (M=Mn, Al) oxide. After fully mixing the oxide with 1.05 times the stoichiometric amount of lithium carbonate, keep it at 90...
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[0034] Example 2
[0035] Weigh 0.1 mol nickel sulfate and 0.3 mol manganese sulfate in a molar ratio of 1:3, and dissolve them in deionized water to prepare a 2 mol / L mixed solution. Weigh 0.4mol sodium carbonate and prepare a 2mol / L solution as a precipitant. A peristaltic pump was used to drive the manganese sulfate solution, nickel sulfate solution and sodium carbonate solution into the reactor at a flow rate of 0.5 mol / L. Weigh a certain amount of aluminum isopropoxide, dissolve aluminum isopropoxide and acetylacetone in ethanol at a molar ratio of 1:1, with a concentration of 0.8 mol / L, and drop the aluminum salt solution at a certain speed. Add to the reactor. The pH value is 8.3, the temperature is 50°C, the stirring speed is 400r / min, the reaction time is 20h, and the carbonate precipitate is obtained after multiple filtration and washing, and drying. The precipitate was heat-treated at 600° C. for 5 hours to obtain oxides. The oxide and the stoichiometric ratio of 1...
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[0037] Example 3
[0038] Dissolve manganese sulfate in deionized water to form a 1mol / L solution. Use ammonium bicarbonate as precipitant and dissolve in deionized water to make a 1mol / L solution. A peristaltic pump was used to separately drive the manganese sulfate solution and the ammonium bicarbonate solution into the reactor at a flow rate of 0.5 mol / L. Weigh a certain amount of aluminum isopropoxide in proportion, dissolve aluminum isopropoxide and acetylacetone in ethanol at a molar ratio of 1:1, with a concentration of 0.8 mol / L, and drop the aluminum salt solution at a certain speed Add to the reactor. The pH of the control system is about 7.5, the temperature of the system is 50°C, the stirring speed is 600r / min, and the (Mn 0.925 Al 0.075 )CO 3 precipitation. The precipitate was filtered and dried and calcined at 800℃ for 5h to obtain M 2 O 3 (M=Mn, Al) oxide. After fully mixing the oxide with 1.01 times the stoichiometric amount of lithium carbonate, keep it at 80...
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