Preparation method of anti-reflection film

A technology of anti-reflection film and mixed liquid, applied in the direction of coating, etc., can solve the problem that the refractive index of the anti-reflection film cannot be lowered too low, and it can only be reduced to about 2% to 4%, and the film cannot be used normally. and other problems, to achieve the effect of fast corrosion rate, low cost and no pollution discharge.

Active Publication Date: 2018-04-13
FUYAO GLASS IND GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, it has been proved by practice that the distribution of hollow silica particles in the film layer is not easy to control. The effect of reducing the reflectivity is not ideal if the amount of hollow silica particles is added, and the haze of the film layer will be increased if the particles are added or the distribution is uneven, and the transparency will be reduced. The problem of mutual restriction between the salt spray resistance and weather resistance of the existing anti-reflection coating and the anti-reflection performance is that the reason is that in order to reduce the refractive index of the anti-reflection coating, the coating must have

Method used

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Examples

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Embodiment 1

[0038] (1) Weigh anhydrous ethanol, tetraethyl orthosilicate, and KH560 with a molar ratio of 1:10.6:3.7 and mix and stir evenly under the action of a magnetic stirrer to obtain a mixed solution A; weigh a mass with a molar ratio of 0.002:11 Mix nitric acid and deionized water with a fraction of 10% under the action of a magnetic stirrer to obtain a mixed solution B; slowly drop the mixed solution B into the mixed solution A with a dropper, and continuously stir the mixed solution A during the dropping process , until the two are completely mixed, and continue to stir for 5 hours, and let stand for 1 day to obtain a silica sol.

[0039] (2) Weigh 3.6g of polyacrylic acid with a molecular weight of 2000 and dissolve it in 20mL of ammonia water. After the polyacrylic acid is completely dissolved, a mixed solution C is obtained. Add all the mixed solution C to 300mL of absolute ethanol and mix evenly with magnetic stirring After that, add 0.2mL tetraethyl orthosilicate dropwise w...

Embodiment 2

[0045] (1) Weigh tetraethyl orthosilicate, absolute ethanol, and KH570 with a molar ratio of 1:12:2.3, and mix and stir evenly under the action of a magnetic stirrer to obtain a mixed solution A; weigh a molar ratio of 0.004:15 Mix hydrochloric acid and deionized water with a mass fraction of 30% under the action of a magnetic stirrer to obtain a mixed solution B; slowly drop the mixed solution B into the mixed solution A with a dropper, and continuously stir the mixed solution during the dropping process A, until the two are completely mixed, and continue to stir for 5 hours, and let stand for 1 day to obtain silica sol.

[0046] (2) Weigh 3.6g of polyacrylic acid with a molecular weight of 2000 and dissolve it in 20mL of ammonia water. After the polyacrylic acid is completely dissolved, a mixed solution C is obtained. Add all the mixed solution C to 300mL of absolute ethanol and mix evenly with magnetic stirring After that, add 0.2mL tetraethyl orthosilicate dropwise with a ...

Embodiment 3

[0052] (1) Weigh tetraethyl orthosilicate, absolute ethanol, and KH550 with a molar ratio of 1:9.4:5 and mix and stir evenly under the action of a magnetic stirrer to obtain a mixed solution A; weigh the acid with a molar ratio of 0.01:20 Catalyst (1 / 3 mass fraction is 30% hydrochloric acid and 2 / 3 mass fraction is 10% nitric acid mixing) and deionized water, mix and stir under the effect of magnetic stirrer, obtain mixed solution B; Mixed solution B is used The dropper was slowly added dropwise to the mixed solution A, and the mixed solution A was continuously stirred during the dropping process until the two were completely mixed, and the stirring was continued for 5 hours, and the silica sol was obtained by standing still for 1 day.

[0053] (2) Weigh 3.6g of polyacrylic acid with a molecular weight of 2000 and dissolve it in 20mL of ammonia water. After the polyacrylic acid is completely dissolved, a mixed solution C is obtained. Add all the mixed solution C to 300mL of abs...

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Abstract

The invention discloses a preparation method of an anti-reflection film. The preparation method comprises the following steps: A, taking silicon alkoxide, an alcohols solvent and a silane coupling agent to be mixed and stirred to obtain a mixed solution A; B, taking an acid catalyst and deionized water to be mixed and stirred to obtain a mixed solution B; C, slowly dropwise adding the mixed solution B into the mixed solution A to obtain silica sol; D, taking the silica sol, hollow silicon dioxide particles and a dispersing agent to be mixed and stirred to prepare and obtain a coating film solution; E, selecting a glass substrate to be polished, washed and dried; F, coating the coating film solution on the glass substrate, leveling, drying and curing to obtain a film layer; and G, putting the glass substrate in an alkaline solution for corrosion, forming concave-convex fabric surface on the surface of the corroded film layer, and then washing and drying to obtain coated glass. The interior of the anti-reflection film prepared and obtained by using the preparation method is of a hollow pore structure, and the concave-convex fabric surface is on the surface of the anti-reflection film, so that the average reflectivity can be reduced by 2% or lower.

Description

Technical field: [0001] The invention belongs to anti-reflection coating technology, and in particular relates to a method for anti-reflection and anti-reflection coatings. Background technique: [0002] With the widespread use of glass, there is an increasing demand for reducing the reflectivity of the glass surface. For ordinary glass, the reflectivity is generally 8% to 10%, which will cause the reflection of objects on the side of the observer to appear on the glass surface, affecting the observer's observation of objects on the other side of the glass. These problems are applied and displayed in the exhibition hall counter glass. It is especially prominent in application scenarios such as the application of screen glass and the reflection of objects inside the car on the front windshield of the car at night, which is easy to cause visual fatigue. In order to reduce visual fatigue and overcome glare, anti-reflection glass that can reduce the reflectivity of light has be...

Claims

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Application Information

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IPC IPC(8): C03C17/00
CPCC03C17/009C03C2217/29C03C2217/73C03C2218/118C03C2218/33
Inventor 康煌柯城贾迎辉邬亚斌李弥滋
Owner FUYAO GLASS IND GROUP CO LTD
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