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A method for treating foam gas production wastewater and a foam gas production wastewater treatment device

A technology of gas extraction wastewater and its treatment method, which is applied in the foam gas extraction wastewater treatment device and the field of foam gas extraction wastewater treatment, and can solve the problems of inability to recover surfactants, etc.

Active Publication Date: 2021-05-14
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] The purpose of the present invention is to overcome the technical problem that the existing foam gas extraction wastewater treatment method needs to be operated in an acidic environment, and the surfactant cannot be recovered, and provides a treatment method for foam gas extraction wastewater. Operating in an acidic environment reduces the corrosion of equipment, improves operational safety, and enables the recovery and reuse of surfactants

Method used

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  • A method for treating foam gas production wastewater and a foam gas production wastewater treatment device
  • A method for treating foam gas production wastewater and a foam gas production wastewater treatment device
  • A method for treating foam gas production wastewater and a foam gas production wastewater treatment device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0088] use figure 1 The shown device treats foam gas extraction wastewater, and the specific process is as follows.

[0089] (1) Send the foam gas extraction wastewater (its property parameters are listed in Table 1) into the precipitation unit, add sodium hydroxide to the foam gas extraction wastewater, adjust the pH value of the foam gas extraction wastewater to 10, and quickly A large amount of yellow-white precipitate was produced. The liquid-solid mixture obtained by the precipitation reaction is filtered with filter paper (purchased from Hangzhou Wohua Filter Paper Co., Ltd., the same below) to obtain a clear liquid phase, and the removal rates of suspended solids, condensate oil and COD (the three are respectively used for gas extraction with foam) Suspended solids, condensate oil and COD values ​​​​in wastewater are listed in Table 2.

[0090] (2) The liquid phase output from the sedimentation unit is sent to the air flotation unit for air flotation. The air flotati...

Embodiment 2

[0103] Adopt the method identical with embodiment 1 to process foam gas extraction waste water, difference is, in step (2), adopt following method to carry out air flotation:

[0104] Inject air into the air flotation tank containing the liquid phase output from the sedimentation unit through the microporous gas distributor (pore diameter of 80-100 μm), the air-water volume ratio is 10:1, the foam overflows from the top of the air flotation tank, and lasts Air is supplied for 5 minutes until the height of the foam layer no longer rises. Remove the remaining foam on the top layer to obtain the recovered surfactant (the liquid carrying capacity is 860mL / L foam), and obtain the air flotation water.

[0105] The experimental results are listed in Table 2.

Embodiment 3

[0107] The same method as in Example 1 is used to treat the foam gas extraction waste water. The difference is that in step (2), the dissolved air pressure is 0.2MPa, and the foam layer is removed to reclaim the surfactant (the liquid carrying capacity is 148mL / L foam ).

[0108] The experimental results are listed in Table 2.

[0109] Table 1

[0110]

[0111] Table 2

[0112]

[0113] 1 : The removal rates of suspended solids, condensate and COD are based on the values ​​of suspended solids, condensate and COD in foam gas recovery wastewater, the same below;

[0114] 2: The removal rate of COD is based on the COD value of the liquid phase sent to the air flotation unit, the same below; the change rate of foaming ability is based on the foaming ability of the air flotation inlet water, the same below;

[0115] 3 : The COD removal rate is based on the COD value of the air flotation water, the same below; the foaming ability change rate is based on the foaming abili...

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Abstract

The invention discloses a method for treating foam gas extraction wastewater and a treatment device for foam gas extraction wastewater. The treatment method includes adjusting the pH value of foam gas extraction wastewater to be above 8.5, performing a precipitation reaction, and dissolving the The mixture is subjected to solid-liquid separation; the obtained liquid phase is subjected to air flotation; the pH value of the air flotation water is adjusted to be neutral and then adsorbed with an adsorbent; the adsorbed water is evaporated to obtain clear water. The treatment method of the present invention makes full use of the characteristics of foam gas extraction wastewater itself, greatly reduces the types and dosage of chemicals used, realizes operation in neutral and alkaline environments, reduces equipment investment costs, and reduces the cost of equipment and operation. Many hidden dangers have been brought, and the safety of operation has been improved. Moreover, the treatment method of the present invention can obtain a good treatment effect, effectively reduce the COD value and salinity of the foam gas extraction wastewater, and can recover the surfactant in the wastewater.

Description

technical field [0001] The invention relates to the field of industrial wastewater treatment, in particular, the invention relates to a method for treating foam gas extraction wastewater and a foam gas extraction wastewater treatment device. Background technique [0002] Foam drainage and gas recovery technology is a technology developed by utilizing the foaming properties of surfactants. By introducing surfactants and polymers into the mineralized water at the bottom of wells, natural gas is used to form foam to achieve the purpose of drainage and gas recovery. For gas-water wells with low formation pressure, it is currently widely used in the field of gas production in oil and gas fields. In the process of foam gas recovery, a large amount of wastewater will be discharged with the bubbles, also known as bubble drainage. This type of wastewater is seriously polluted and has the characteristics of oil content, high chemical oxygen demand (COD), and high salt content. Due to...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/10C02F103/10
CPCC02F1/048C02F1/24C02F1/281C02F1/283C02F1/285C02F1/5236C02F1/66C02F9/00C02F2103/10
Inventor 赵锐杨宇宁
Owner CHINA PETROLEUM & CHEM CORP