Nanometer spectral long-acting catalyst capable of highly-efficiently decomposing organic pollutants under dark light and light-free conditions
An organic pollutant and nano-technology, applied in the field of nano-spectrum long-acting media, can solve the problems of ineffective sealing agent, wear of furniture, and difficulty in eliminating reaction completely, and achieve good catalytic effect.
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Embodiment 1
[0042] Preparation of bismuth vanadate
[0043] Dissolve 0.0015 mol of sodium vanadate and 0.00 mol of bismuth nitrate in deionized water, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it in a constant temperature drying box After reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01 mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.
[0044] Preparation of nano-modified niobium oxide:
[0045] At room temperature, 8 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 15 parts by weight of bismuth vanadate, 0.08 parts by weight of sulfurous acid Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pentachloride, and the mi...
Embodiment 2
[0048] Preparation of bismuth vanadate
[0049] Dissolve 0.0015mol of sodium vanadate and 0.00mol of 1 bismuth nitrate in deionized water respectively, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it into a constant temperature drying In the box, after reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.
[0050] Preparation of nano-modified niobium oxide:
[0051] At room temperature, 5 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 10 parts by weight of bismuth vanadate, 0.05 parts by weight of sulfurous acid Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pen...
Embodiment 3
[0054] Preparation of bismuth vanadate
[0055] Dissolve 0.0015mol of sodium vanadate and 0.00mol of 1 bismuth nitrate in deionized water respectively, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it into a constant temperature drying In the box, after reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.
[0056] Preparation of nano-modified niobium oxide:
[0057] At room temperature, 4 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 14 parts by weight of bismuth vanadate, 0.05 parts by weight of Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pentachloride, and...
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