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Waterborne two-component varnish and preparation method thereof

A water-based two-component, varnish technology, applied in coatings, polyurea/polyurethane coatings, etc., can solve problems such as unbalanced acid and alkali resistance, easy water loss, increased steps, etc., to improve hot-stick defects, cold and brittle, Good moisturizing performance and the effect of improving film-forming performance

Inactive Publication Date: 2018-05-18
GUANGDONG YATU CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Because topcoat and varnish are roughly the same in terms of composition and function, the biggest difference is that the topcoat contains color paste, so the problems of varnish can be obtained by analyzing the defects of existing topcoat, such as patent CN105482588A "An Environmentally Friendly Nano-Metal Auto Finish" discloses an automotive finish. This patent combines the treated nano-metal powder with other substances to finally obtain a top coat with excellent performance. It is based on conventional resin components. Adding metal powder in the process increases the steps, increases the cost, and has certain requirements for the metal powder; the patent CN106800874A "A water-based two-component polyurethane topcoat and its preparation method" discloses that it is mainly composed of hydroxyacrylate and isocyanate curing agent As the main component, but the curing agent contains both hydrophilic and hydrophobic polyisocyanate curing agents, and the content of water-based hydroxyl acrylic dispersion in component A is high, and the acid and alkali resistance of the product is unbalanced
[0006] As a two-component acrylic varnish, traditional water-based acrylic resin coatings have defects such as easy water loss, high light absorption, hot stickiness, cold brittleness, and environmental sensitivity. As far as varnishes are concerned, there are still gaps in the fullness, gloss, leveling, and workability of the paint film.

Method used

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  • Waterborne two-component varnish and preparation method thereof
  • Waterborne two-component varnish and preparation method thereof
  • Waterborne two-component varnish and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Preparation of waterborne two-component varnish

[0051] The formula of waterborne two-component varnish is as shown in table 1, and its preparation process is as follows:

[0052] (1) Put the formulated amount of water-based acrylic resin and water-based polyester resin into the container in sequence and mix them evenly, then slowly add carboxymethyl chitosan, substrate wetting agent, leveling agent, defoamer, and ultraviolet absorber , bactericide and co-solvent, then add thickener, stir evenly, filter and discharge to obtain component A;

[0053] (2) Add a formula amount to the container to mix the isocyanate curing agent, adhesion promoter and cosolvent, and filter the discharge to obtain component B;

[0054] (3) Mix according to the mixing ratio of A and B as 3:1 to obtain a water-based two-component varnish.

[0055] Table 1 Waterborne two-component varnishes of different formulations

[0056]

[0057] Water-based two-component varnish performance testing d...

Embodiment 2

[0066] Table 4 shows the feeding formula of Example 2 when the types of substances in the formula are kept unchanged, and the content of each substance is changed. The water-based two-component varnish is prepared according to the process of Example 1.

[0067] The properties of the obtained water-based two-component varnishes prepared by formulas 6 to 9 are shown in Table 5. Compared with the properties of Table 2, it can be seen that when the weight parts of the various substances of the A and B components exceed the range disclosed in the table of Example 1, The performance of the obtained water-based two-component varnish is drastically reduced in all aspects.

[0068] Table 4 Waterborne two-component varnishes of different formulations

[0069]

[0070] Water-based two-component varnish performance testing data of different formulations in table 5

[0071]

[0072]

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PUM

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Abstract

The invention discloses waterborne two-component varnish and a preparation method thereof. The waterborne two-component varnish is formed by mixing a component A and a component B in the mass ratio of(2.5-3.5):1, wherein the component A comprises, by weight, 25-40 parts of waterborne acrylic resin, 25-40 parts of waterborne polyester resin, 0.1-1 part of base material wetting agent, 0.1-1 part offlatting agent, 0.1-1 part of defoaming agent, 0.1-1 part of ultraviolet absorbent, 0.1-1 part of bactericide, 5-10 parts of cosolvent, 0.1-1 part of thickening agent and 2-5 parts of carboxymethyl chitosan; the component B comprises, by weight, 40-60 parts of isocyanate curing agent, 0.1-1 part of adhesion promoter and 40-60 parts of cosolvent. The fullness, glossiness, flatting property, construction performance and mechanical properties of the varnish can reach the standards of high-performance oily varnish and are higher than those of existing waterborne varnish, and the varnish has the advantage of being low in content of VOCs.

Description

technical field [0001] The invention belongs to the field of paint preparation, in particular to a water-based two-component varnish for vehicles. Background technique [0002] Coating refers to a substance that can be applied to the surface of an object, firmly bonded to the surface, and forms a solid film with a certain strength. [0003] Varnish, also known as varnish, is a coating composed of resin as the main film-forming substance plus a solvent. Since the coating and the coating film are transparent, it is also called transparent coating. Must have several functions: 1. Good appearance: including high fullness, high gloss, good leveling, no shrinkage cavity, no prickly heat, etc.; 2. Excellent protection performance: including good hardness, good flexibility, weather resistance Good, good water resistance, good salt spray resistance, etc.; 3. Excellent construction: including good wettability, not easy to sag; 4. Wide construction window: including good adaptability ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D7/65C09D7/43C09D7/47C08G18/68C08G18/62
CPCC08G18/6229C08G18/68C08L2205/035C09D175/14C08L75/04C08L1/286C08L33/02C08L5/08
Inventor 冯兆均张育波刘冬立秦中海周其运
Owner GUANGDONG YATU CHEM
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