Preparation method of ultralight and high-strength GMT (glass mat reinforced thermoplastic) composite board

A composite sheet, high-strength technology, applied in the field of preparation of ultra-light and high-strength GMT composite sheet, can solve the problems of uneven distribution of microspheres, unfavorable continuous production, increased cost, etc. The effect of improving mechanical properties

Inactive Publication Date: 2018-05-25
浙江华江科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (3) Since the connection between the glass fiber and the hot-melt fiber is a point connection; in order to improve the mechanical properties of the board, the amount of resin is relatively high, so the cost increases, and it is difficult to further reduce the weight of the material
It effectively solves the problems of traditional lightweight GMT, such as the difficulty of further ultra-lightweight, insufficient air infiltration, product design freedom and NVH performance lag far behind foreign imported products, etc.
However, the introduction of microsphere foaming agent through the impregnation process makes it difficult to dry the felt net in the subsequent process and consumes a lot of energy, which is not conducive to continuous production
Moreover, the introduction of foamed microspheres into the felt net through the impregnation process will easily lead to uneven distribution of microspheres, thereby affecting its mechanical properties.
[0009] Patent 200680020471.2 disperses reinforcing fiber, thermoplastic resin powder and microsphere foaming agent in the bubble liquid added with surfactant, and makes a network by papermaking method (also known as papermaking method), but this manufacturing method requires complex structure The device, operation and process are also very complicated, and at the same time, it will cause great pollution to the environment
The cost is relatively high due to the use of surfactants to make the expensive foam solution prepared by reinforcing fibers, thermoplastic resin powder and microsphere foaming agent

Method used

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  • Preparation method of ultralight and high-strength GMT (glass mat reinforced thermoplastic) composite board
  • Preparation method of ultralight and high-strength GMT (glass mat reinforced thermoplastic) composite board
  • Preparation method of ultralight and high-strength GMT (glass mat reinforced thermoplastic) composite board

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] An ultra-light and high-strength GMT composite sheet for preparing automobile bottom guards, which uses polypropylene fiber 1 as a bonding matrix, glass fiber 2 as a reinforcement, and microspheres that have the effect of changing the connection mode of glass fiber spacing points to adjust the expansion ratio of the sheet Blowing agent 3 composition. Its specific preparation method comprises the following steps:

[0031] (1) The polypropylene fiber 1 and the glass fiber 2 are uniformly mixed at a ratio of 60wt%:40wt%, and a uniform single fiber web is obtained through a non-woven process through opening, mixing and carding.

[0032] (2) Uniformly disperse the microsphere foaming agent on the surface of the carded single fiber web by dusting process, wherein the content of the microsphere foaming agent is 5wt% of the mass of the single fiber web.

[0033] (3) The single fiber web containing the microsphere foaming agent is cross-laid and needle-punched to obtain a blended...

Embodiment 1

[0064] Example 1 introduces a microsphere foaming agent 3 into the felt net of the existing lightweight GMT composite board, and the introduction of the microsphere foaming agent 3 makes the connection modes between the glass fibers 2 more diverse. In addition to the traditional point connection, the microsphere blowing agent 3 binds the glass fibers 2 around it as a bridge, and the microsphere blowing agent 3 is connected to each other, as figure 1 As shown, these diverse connection methods have fundamentally changed the internal felt network structure of composite panels. figure 2 Comparing the results inside the felt net in Example 1 and Comparative Example 1, it was found that the glass fibers 2 inside the felt net in Example 1 were connected to each other, while the glass fibers 2 in Comparative Example 2 were simply point-connected. Compared with the bottom guard plate at the same density, the mechanical properties of Example 1 are significantly improved compared with C...

Embodiment 2

[0066] An ultra-light and high-strength GMT composite sheet for the preparation of automobile roofs, consisting of ES fiber as a bonding matrix, hemp fiber as a reinforcement, and a microsphere foaming agent 3 that has the effect of changing the connection mode of the reinforcing fiber spacing points to adjust the expansion ratio of the sheet . Its specific preparation method comprises the following steps:

[0067] (1) The ES fiber and the hemp fiber are mixed uniformly at a ratio of 55wt%:45wt%, and a uniform single fiber web is obtained through a non-woven process through opening, mixing and carding.

[0068] (2) Uniformly disperse the microsphere foaming agent on the surface of the carded single fiber web by dusting process, wherein the content of the microsphere foaming agent is 10wt% of the mass of the single fiber web.

[0069] (3) The single fiber web containing the microsphere foaming agent is cross-laid and needle-punched to obtain a blended composite fiber mat unifo...

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Abstract

The invention discloses a preparation method of an ultralight and high-strength GMT composite board. According to the preparation method of the ultralight and high-strength GMT composite board, microballoon foaming agent is introduced into a blend fiber composite mat made of thermoplastic compound fiber and reinforcing fiber through a dusting process and then hot-pressed through continuous compounding equipment into the ultralight and high-strength GMT composite board for automobile interior and exterior trimming, in which the reinforcing fiber serves as a reinforcing body, the thermoplastic compound fiber serves as a bonding matrix, and the microballoon foaming agent serves as filling modifier; the microballoon foaming agent is uniformly dispersed inside the blend fiber composite mat through the dusting process, which is simple, flexible in operation, applicable to continuous production and meanwhile has the advantage of low cost, so that the manufacturing cost can be reduced, preparation of high-price foaming solution can be saved and small environmental pollution can be achieved.

Description

technical field [0001] The invention belongs to the technical field of thermoplastic composite materials for interior and exterior decoration of automobiles, and in particular relates to a preparation method of an ultra-light and high-strength GMT composite plate used for interior and exterior decoration of automobiles. Background technique [0002] Lightweight glass fiber mat reinforced thermoplastic composite sheet (referred to as lightweight GMT sheet), is a new type of composite material composed of continuous glass fiber mat and thermoplastic resin. It has light weight, environmental protection, sound absorption and heat insulation, high strength and toughness, excellent With the characteristics of chemical corrosion resistance and environmental adaptability, it is widely used in the fields of transportation, construction and aviation. The modern automobile industry takes the reduction of body weight as the main development direction of energy saving and consumption red...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/32B32B27/02B32B27/12B32B17/02B32B17/10B32B17/12B32B27/06B32B37/10B32B37/06
CPCB32B5/02B32B5/20B32B5/26B32B37/06B32B37/10B32B2262/0253B32B2262/101B32B2262/14B32B2307/50B32B2307/718B32B2605/003B32B2605/08
Inventor 郑爱爱马国维方晶梅金波周立丁文鹏韩黎刚
Owner 浙江华江科技股份有限公司
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