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Ultrahigh molecular weight polyethylene and preparation method thereof as well as high-temperature-resistant sand grain wax

A technology of ultra-high molecular weight and polyethylene, applied in the direction of coating, etc., can solve the problems affecting the addition and use of sand texture agent, low molecular weight of PE additives, shortening the gelation time of powder, etc., to achieve good shape, low addition amount, clear texture effect

Inactive Publication Date: 2018-07-13
公安县瑞凯高分子材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the early preparation of sand-textured powder coatings, a large amount of fillers were often added, or the gelation time of the powder was shortened, or the combination of the two. The disadvantages are self-evident, which not only affects the performance, but also brings difficulties to the powder processing.
Now people can obtain different texture effects by adding polyethylene (PE) polymers, but the molecular weight of conventional PE additives is usually low, which seriously affects the addition and use of sanding agents

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A kind of high temperature resistant sand pattern wax, melting point is 200 ℃, and its preparation comprises the following steps:

[0022] The ultra-high molecular weight polyethylene is pre-crushed into a first powder with a particle size of 10 mesh, and then the first powder is frozen and crushed at a temperature of -180°C into a second powder with a particle size of 200 mesh. The second powder and dispersant are evenly mixed to obtain high temperature resistant sand pattern wax;

[0023] Among them, the preparation method of ultra-high molecular weight polyethylene is: add 0.1 parts by weight of aluminum alkoxide and 1 part by weight of catalyst to the stirred tank slurry reactor in an inert atmosphere, and when the temperature rises to 52 ° C, open the ethylene feed valve, Feed ethylene, control the reaction temperature to 55°C, and the reaction pressure to 0.5MPa, continuously feed ethylene, polymerize for 2 hours, and react to obtain ultra-high molecular weight po...

Embodiment 2

[0026] A kind of high temperature resistant sand pattern wax, melting point is 210 ℃, and its preparation comprises the following steps:

[0027] The ultra-high molecular weight polyethylene is pre-crushed into a first powder with a particle size of 15 mesh, and then the first powder is frozen and crushed at a temperature of -170°C into a second powder with a particle size of 250 mesh. The second powder and dispersant are evenly mixed to obtain high temperature resistant sand pattern wax;

[0028] Among them, the preparation method of ultra-high molecular weight polyethylene is: add 0.5 parts by weight of aluminum alkoxide and 1 part by weight of catalyst to the stirred tank slurry reactor in an inert atmosphere, and when the temperature rises to 52 ° C, open the ethylene feed valve, Feed ethylene, control the reaction temperature to 58°C, and the reaction pressure to 0.6 MPa, continuously feed ethylene, polymerize for 2.2 hours, and react to obtain ultra-high molecular weight...

Embodiment 3

[0031] A kind of high temperature resistant sand pattern wax, melting point is 230 ℃, and its preparation comprises the following steps:

[0032] The ultra-high molecular weight polyethylene is pre-crushed into a first powder with a particle size of 20 mesh, and then the first powder is frozen and crushed at a temperature of -165°C into a second powder with a particle size of 300 mesh. The second powder and dispersant are evenly mixed to obtain high temperature resistant sand pattern wax;

[0033] Among them, the preparation method of ultra-high molecular weight polyethylene is: add 0.11 parts by weight of aluminum alkoxide and 1 part by weight of catalyst to the stirred tank slurry reactor in an inert atmosphere, and when the temperature rises to 52 ° C, open the ethylene feed valve, Feed ethylene, control the reaction temperature to 63°C, and the reaction pressure to 0.7MPa, continuously feed ethylene, polymerize for 2.5 hours, and react to obtain ultra-high molecular weight...

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Abstract

The invention relates to ultrahigh molecular weight polyethylene and a preparation method thereof as well as high-temperature-resistant sand grain wax. The preparation method of the ultrahigh molecular weight polyethylene comprises the following steps: sequentially adding alkoxy aluminum and a catalyst into a reaction kettle type slurry-phase reactor in an inert atmosphere, opening an ethylene feed valve when heating up to 52 DEG C, introducing ethylene, controlling the reaction temperature to be 55-63 DEG C and the reaction pressure to be 0.5-0.7MPa, continuously introducing ethylene, and carrying out a polymerization reaction for 2-2.5h to obtain the ultrahigh molecular weight polyethylene, wherein the ratio of parts by weight of the catalyst to the alkoxy aluminum is equal to 1 to (0.1-0.11). The ultrahigh molecular weight polyethylene powder provided by the invention has a better form and a larger molecular weight; when only 1-3wt% of the ultrahigh molecular weight polyethylene isadded into a coating, a better texture effect can be achieved, and the grains are clear; contrast experiments show that the sand grain wax provided by the invention is lower in adding amount under theconditions of being same in film thickness and obtaining the same texture.

Description

technical field [0001] The invention relates to the technical field of sand grain wax, in particular to an ultra-high molecular weight polyethylene, a preparation method thereof, and a high temperature resistant sand grain wax. Background technique [0002] A texture agent is an additive that can provide a uniform surface texture and a uniform gloss and color to the paint surface. When used, some insoluble or incompatible additives are often added to control the particle size, melt viscosity, and surface tension of the molten surface of the powder, so that the desired texture effect can be achieved. [0003] Textured powder coating is a general term and has different varieties, such as sand grain type, wrinkle type, water grain type and so on. [0004] In the early preparation of sand-textured powder coatings, a large amount of fillers were often added, or the gelation time of the powder was shortened, or the combination of the two. The disadvantages are self-evident, which...

Claims

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Application Information

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IPC IPC(8): C08F110/02C08F4/646C09D5/28C08J3/12
CPCC08F110/02C08J3/12C08J2323/06C09D5/28C08F4/6465C08F2500/01
Inventor 蔡建光
Owner 公安县瑞凯高分子材料股份有限公司