Ultrahigh molecular weight polyethylene and preparation method thereof as well as high-temperature-resistant sand grain wax
A technology of ultra-high molecular weight and polyethylene, applied in the direction of coating, etc., can solve the problems affecting the addition and use of sand texture agent, low molecular weight of PE additives, shortening the gelation time of powder, etc., to achieve good shape, low addition amount, clear texture effect
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Embodiment 1
[0021] A kind of high temperature resistant sand pattern wax, melting point is 200 ℃, and its preparation comprises the following steps:
[0022] The ultra-high molecular weight polyethylene is pre-crushed into a first powder with a particle size of 10 mesh, and then the first powder is frozen and crushed at a temperature of -180°C into a second powder with a particle size of 200 mesh. The second powder and dispersant are evenly mixed to obtain high temperature resistant sand pattern wax;
[0023] Among them, the preparation method of ultra-high molecular weight polyethylene is: add 0.1 parts by weight of aluminum alkoxide and 1 part by weight of catalyst to the stirred tank slurry reactor in an inert atmosphere, and when the temperature rises to 52 ° C, open the ethylene feed valve, Feed ethylene, control the reaction temperature to 55°C, and the reaction pressure to 0.5MPa, continuously feed ethylene, polymerize for 2 hours, and react to obtain ultra-high molecular weight po...
Embodiment 2
[0026] A kind of high temperature resistant sand pattern wax, melting point is 210 ℃, and its preparation comprises the following steps:
[0027] The ultra-high molecular weight polyethylene is pre-crushed into a first powder with a particle size of 15 mesh, and then the first powder is frozen and crushed at a temperature of -170°C into a second powder with a particle size of 250 mesh. The second powder and dispersant are evenly mixed to obtain high temperature resistant sand pattern wax;
[0028] Among them, the preparation method of ultra-high molecular weight polyethylene is: add 0.5 parts by weight of aluminum alkoxide and 1 part by weight of catalyst to the stirred tank slurry reactor in an inert atmosphere, and when the temperature rises to 52 ° C, open the ethylene feed valve, Feed ethylene, control the reaction temperature to 58°C, and the reaction pressure to 0.6 MPa, continuously feed ethylene, polymerize for 2.2 hours, and react to obtain ultra-high molecular weight...
Embodiment 3
[0031] A kind of high temperature resistant sand pattern wax, melting point is 230 ℃, and its preparation comprises the following steps:
[0032] The ultra-high molecular weight polyethylene is pre-crushed into a first powder with a particle size of 20 mesh, and then the first powder is frozen and crushed at a temperature of -165°C into a second powder with a particle size of 300 mesh. The second powder and dispersant are evenly mixed to obtain high temperature resistant sand pattern wax;
[0033] Among them, the preparation method of ultra-high molecular weight polyethylene is: add 0.11 parts by weight of aluminum alkoxide and 1 part by weight of catalyst to the stirred tank slurry reactor in an inert atmosphere, and when the temperature rises to 52 ° C, open the ethylene feed valve, Feed ethylene, control the reaction temperature to 63°C, and the reaction pressure to 0.7MPa, continuously feed ethylene, polymerize for 2.5 hours, and react to obtain ultra-high molecular weight...
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Abstract
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